Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Ettect of Sodium Gluconate on the Hydration of 3CaO.$Al_2O_3$(I)-Adsorption Behavior-

3CaO.$Al_2O_3$의 수화반응에 미치는 글루콘산나트륨읨 영향(I) -흡착거동-

  • 김창은 (연세대학교 공과대학 요업공학과) ;
  • 이승헌 (연세대학교 공과대학 요업공학과) ;
  • 유종석 (연세대학교 공과대학 요업공학) ;
  • 최진호 (서울대학교 자연대학 화학과)
  • Published : 1986.02.01
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Abstract

The adsorption behavior of 3CaO.$Al_2O_3$-sodium gluconate-$H_2O$ system by measuring adsorp-tion isotherm DTA and IR sepctra. The adsorbed amount of sodium gluconate on 3CaO.$Al_2O_3$ is exceedingly larger than 3CaO.$SiO_2$ and portland cement. From the DAT experiment the formation of complex is observed by the characteristic exothermic peak of the complex at 45$0^{\circ}C$ It is now strong deduced that the chemical bonding between gluconate anion and 3CaO.$Al_2O_3$ should be coordinative due to the complex formation on the surface 3CaO.$Al_2O_3$ from the IR spectra of sod-ium gluconate only and 3CaO.$Al_2O_3$ -sodium gluconate-$H_2O$.

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References

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