Degradation of Carcinogenic Nitrosamine Formation Factor by natural Food Components 2. Nitrite-scavenging Effects of Seaweed Extracts

천연식품성분에 의한 의한 발암성 니트로사민생성인자 분해작용 2. 해조유출물의 아질산염 분해작용

  • KIM Seon-Bong (Department of Food Science and Technology, National Fisheries University of Pusan) ;
  • AHN Bang-Weon (Department of Food Science and Technology, National Fisheries University of Pusan) ;
  • YEUM Dong-Min (Department of Food Science and Technology, National Fisheries University of Pusan) ;
  • LEE Dong-Ho (Department of Food Science and Technology, National Fisheries University of Pusan) ;
  • PARK Yeung-Ho (Department of Food Science and Technology, National Fisheries University of Pusan) ;
  • KIM Dong-Soo (Department of Food Science and Technology, Pusan Sanub University)
  • 김선봉 (부산수산대학 식품공학과) ;
  • 안장원 (부산수산대학 식품공학과) ;
  • 염동민 (부산수산대학 식품공학과) ;
  • 이동호 (부산수산대학 식품공학과) ;
  • 박영호 (부산수산대학 식품공학과) ;
  • 김동수 (부산산업대학교 식품공학과)
  • Published : 1987.09.01

Abstract

The present paper was investigated to elucidate the nitrite-scavenging ability of seaweed extracts. Seaweed extracts possessed the scavenging ability of nitrite. By fractionation of seaweed extracts, nitrite-scavenging ability of laver(Porphyra tenera), sea lettuce(Enteromorpha compresa) extracts were effective in the water-soluble fraction, but sea mustard (Undaria pinnatifida), sea staghorn (Codium fragile) extracts in the methanol-soluble fraction. Nitrite scavenging ability of seaweed extracts was also pH-dependent, highest at pH1.2 and lowest at pH6.0. Particularly, nitrite-scavenging abilities of water-soluble fractions obtained from laver and sea lettuce were similar to that of L-ascorbic acid at pHl.2. After seaweed extracts were treated with sodium borohydride, nitrite-scavenging ability was remarkably decreased at pH1.2. It is assumed that reducing powers of seaweed extracts participated in their nitrite-scavenging abilities.

일상 식생활에서 널리 섭취하고 있는 해조류를 사용하여 니트로사민의 직접적인 생성인자인 아질산염 분해작용에 관하여 검토하였는데, 그 결과를 요약하면 다음과 같다. 1. 본 실험에 사용한 시료들의 아질산염 분해능은 김${\cdot}$파래 등은 수용성획분과 methanol 가용성획분에서, 미역${\cdot}$청각 등은 methanol 가용성획분에서 그 분해능이 높게 나타났다. 2. 반응용액의 pH 변화에 따른 아질산염 분해능은 pH 1.2에서 가장 컸으며, pH가 증가할수록 분해능은 감소하였다. 3. 각 시료를 10mg씩 취하여 얻은 아질산염 분해능은 동량의 L-ascorbic acid와 비교한 경우, 김과 파래는 pH 1.2에서 L-ascorbic acid와 거의 비슷한 분해능을 나타내었다. 4. 각 시료를 $NaBH_4$로 처리하여 환원능을 소실시킨 후에 측정한 아질산염 분해능은 pH 1.2에서 시료 모두 그 값이 현저하게 감소하였다.

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