Dependency of SnO2 System Carbon Monoxide Gas Sensor on the Atmospheric Temperature & Humidity

$SnO_2$계 일산화탄소 가스 감지 소자의 주위온도, 습도 의존성에 관한 연구

  • 정형진 (한국과학기술연구원 무기재료연구실) ;
  • 김종만 (한국과학기술연구원 무기재료연구실) ;
  • 이전국 (한국과학기술연구원 무기재료연구실)
  • Published : 1990.08.01

Abstract

SnO2-ThO2-PdCl2-In2O3 gas sensing ceramic systems were studied in order to lowr the operating temperatures and reduce the dependence of ambient temperatures and humidities. Sensing materials were coated by brush on the alumina tube followed by the impregnation of solidfier(ethylsilicate). Coated species were dried and sintered at 75$0^{\circ}C$ for 30min. carbon monoxide gas detecting sensitiviteis were measured in various ambinet temperatures and humidities. In the composition of 94SnO2-5ThO2-PdCl2 system carbon monoxide gas detecting sensors showed the highest detecting sensitivities and the lowest operating temperature(15$0^{\circ}C$). As the ambient temperatures and humidities were increased, sensitivities were decreased. Because the oscillation effects were observed at high humidities, it was suggested that the sensitivities of sensors depend greatly on the humidities.

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References

  1. U.S. Patent No.3695848 N. Taguchi
  2. 電子材料 v.16 no.5 武田義章
  3. Nihon Daigaku Seisankogakubu Hokoku v.10 no.1 SnO₂Gas Sensor Used Thick Film Technology (Ⅰ) Gas Detective Properties T. Nakasaka
  4. IEEE Transactions on Electron Devices v.ED26 no.3 Thick Film CO Gas Sensor M. Nitta
  5. Proceedings of the International Meeting on Chemical Sensor v.17 Development of Tin Oxide Gas Sensor & Monitoring System T. Oyabu
  6. J. Res. Nat. Bur. Stand v.40 Divided flow. Low-Temperature Humidity Test Apparature A. Wexler
  7. Denki Kagaku v.40 no.3 Gas Detection by Activated Semiconductive Sensor T. Seiya
  8. Proceedings of the International Meeting on Chemical Sensor v.17 Methane Sensitive Semiconductor & detector Lipeide
  9. セラミクス評價技術特集 no.1월 セラミクスガスセンサ評價法, ェレクトニク セラミクス 五百歲
  10. Nihon Daigaku Seisankogakubu v.10 no.2 SnO₂-Based Gas Sensors Used Thick Film Technology Dielectric Properties T. Oyabu
  11. ガス選擇特性に 對する Thる ThO₂の影響 v.9 新田正義
  12. J. Appl. Phys. Lett v.39 no.9 Ocsillation Phenomenon in ThO₂-Doped SnO₂Exposed CO Gas M. Nitta
  13. Proc. Intern. Meeting on Chem. Sensors v.17 Ocsillation Phenomenon in a SnO₂-Based Gas Sensor S. Kanefusa
  14. J. Surface Science v.114 no.2;3 Ocsillatory Oxidation of CO Over Pt, Pd & Ir Catalysts ; Theory B.C. Sales
  15. Phys. Chem. Glasses v.2 S.M. Budd
  16. J. Phys. Chem. Solids v.29 HE. Mathews
  17. Introduction to Solid State Physics(5th ed.) C. Kittel