Abstract
In this study we have investigated the sealing characteristics of glasses suitable for producing the magnetic gap of the ferrite head cores which have been widely used for VTR and computer magnetic heads. $PbO-B_2O_3$ g1asses were evaluated by measuring microhardness, thermal expansion coefficient and sliding wear resistance. Concentration distribution of elements at the interface was observed by WDS. wettability was measured by high temperature microscopy. The results were as follows ; 1. In sealing glasses of $PbO-B_2O_3$ system, thermal expansion coefficient and wear volume were increased with increasing PbO content, and were decreased with increasing $B_2O_3$ content. 2. The contact angle of $PbO-B_2O_3$ Systems was mainly influenced by PbO content. 3. The sealing temperature showed a tendency to decrease proportionally with the increase of the coefficient of thermal expansion. 4. The diffusion at the interface between Mn-Zn single crystal ferrite and sealing glasses of $PbO-B_2O_3$ system was dominated by small amount of diffusion of ferrite content into glass part, which was very little affected by sealing heat treatment time.
본 연구는 computerdisk drive와 VTR head에 사용되어 지고 있는 ferrite head cores의 gap 형성에 적합한 유리의 봉착특성에 관하여 고찰하였다. 유리의 특성측정은 열팽창 계수, 미세경도, 내마모성을 측정하였으며 계면에서의 원소 농도분포는 WDS에 의해 관찰하였고 젖음성은 고온 현미경으로 측정하였다. 그 결과는 다음과 같다. 1. $PbO-B_2O_3$계 봉착용 유리에 있어서 PbO의 함량이 증가함에 따라 열팽창계수와 마모량이 증가하였으며 $B_2O_3$함량이 증가함에 따라서는 열팽창계수와 마모량이 감소하였다. 2. $PbO-B_2O_3$계 유리에 있어서 contact angle은 PbO함량에 주로 영향을 받는다. 3. 열팽창계수의 증가에 따라 봉착온도는 비례적으로 낮아지는 경향을 나타내었다. 4. Mn-Zn single crystal ferrite와 $PbO-B_2O_3$계 봉착용유리의 융착 계면에서의 확산은 ferrite성분이 glass측으로 소량확산이 이루어졌으며 봉착 열처리 시간에 따라서는 거의 영향을 받지 않았다.
