Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Effect of A-Site Substitution on the Dielectric Properties of PZN Ceramics

A-자리 치환에 따른 PZN 세라믹스의 유전특성

  • 조상희 (경북대학교 무기재료공학과) ;
  • 백종갑 (경북대학교 무기재료공학과) ;
  • 손정호 (경북대학교 무기재료공학과) ;
  • 김정주 (경북대학교 무기재료공학과) ;
  • 김남경 (경북대학교 무기재료공학과)
  • Published : 1995.05.01
Download PDF
⟨ Previous Next ⟩

Abstract

The effects of A-site substitution with alkaline-earth ions (Ca, Sr and Ba) on the perovskite-phase formation and dielectric properties for Pb1-xMx(Zn1/3Nb2/3)O3 (0.0 x 0.5)-based relaxors were studied. Considerable improvements in the sinterability and the extent fo perovskite formation were observed with increasing the A-site substitution (x) and sintering temperature. The maximum dielectric permittivity appeared at x=0.1 for Sr and Ba substitutiion, while the relative dielectric permittivity was almost invariant in the case of Ca ion substitution. Curie temperature decreased with increasing relative amount of Sr and Ba ions but was almost invariant in case of Ca ion substitution. With increasing the amount of x, the diffuseness parameter ($\delta$) increased but the maximum dielectric constant decreased, demonstrating an enhanced diffuse phase transition (DPT) in the presence of alkaline-earth cations.

Keywords

References

  1. J. Phys. Soc. Jpn. v.28 no.5 Ferroelectric Properties of Pb(Zn⅓/Nb⅔)O₃ Y. Yokomizo;T. Takahashi;S. Nomura
  2. J. Phys. Soc. Jpn. v.27 no.262 Ferroelectric Properties in the Pb(Zn⅓/Nb⅔)O₃-PbTiO₃ System S. Nomura;T. Takahashi; Y. Yokomizo
  3. Sov. Phys. Solid State(Engl. Transl.) v.3 no.3 Electrical and Optical Properties of Single Crystals of Ferroelectrics with a Diffused Phase Transition V.A. Bokov;I.E. Myl'nikova
  4. Ferroelectrics v.22 Diffuse Phase Transitions in Lead Zinc Niobate J. Kuwata;K. Uchino;S. Nomura
  5. Mater. Res. Bull. v.14 no.6 Electrostricition in Pb(Zn⅓/Nb⅔)O₃ S. Nomura;J. Kuwata
  6. Jpn. J. Appl. Phys. v.12 no.4 Quadratic Electro-optic Effect in the System Pb(Zn⅓/Nb⅔)O₃ S. Nomura;H. Arima;F. Kojima
  7. J. Am. Ceram. Soc. v.52 no.9 High-Pressure Synthesis of Perovskite-Type Pb(Zn⅓/Nb⅔)O₃ Y. Matsuo;H. Sasaki;S. Hayakawa;F. Kanamaru;M. Koizumi
  8. Jpn. J. Appl. Phys. v.11 no.3 Dielectric and Piezoelectric Properties in the Ternary System of Pb(Zn⅓/Nb⅔)O₃-Ba(Zn⅓/Nb⅔)O₃-PbTiO₃ S. Nomura;H. Arima
  9. Mater. Res. Bull. v.17 Fabricationof Perovskite Lead Magnesium Niobate S.L. Swartz;T.R. Shrout
  10. Am. Ceram. Soc. Bull. v.65 no.12 Preparation of Perovskite PZN-PT Ceramic Powder near the Morphotropic Phase Boundary T.R. Gururaja;A. Safari;A. Hallyal
  11. J. Am. Ceram. Soc. v.75 no.1 Thermodynamic Stability and Mechanisms of Formation and Decomposition of Perovskite Pb(Zn⅓/Nb⅔)O₃Prepared by the PbO Flux Method H.M. Jang;S.H. Oh;J.H. Moon
  12. Mater. Res. Bull. v.4 Pb₂M₂$O_{1-x}$ (M=Ru, Ir, Re)-Preparation and Properties of Oxygen Deficient Pyrochlore J.M. Longo;P.M. Raccah;J.B. Goodenough
  13. J. Mat. Sci. v.23 Curie Point of Perovskite-type Oxides Containing Bivalent Ions of the 4th Period in the B-site K. Igarashi;K. Koumoto;H. Yanagida
  14. Am. Ceram. Soc. Bull. v.66 no.4 Stabilization of Perovskite Phase and Dielectric Properties of Ceramics in the Pb(Zn⅓/Nb⅔)O₃-BaTiO₃ System A. Halliyal;U. Kumar;R.E. Newnham;L.E. Cross
  15. Ⅰ: Matemot. Naturuid. Klasse no.2 V.M. Goldschmidt Skrifter;Norske Videnskaps-Akad Oslo
  16. Am. Ceram. Soc. Bull. v.66 no.4 Preparation of Lead-Based Ferroelectric Relaxors for Capacitors T.R. Shrout;A. Halliyal
  17. The Nature of Chemical Bonds L. Pauling
  18. J. Mat. Sci. v.24 Lead Zinc Niobate Pyrochlore; Structure and Dielectric Properties H.C. Ling;M.F. Yan;W.W. Rhodes
  19. Advanced Ceram Mater. v.3 no.1 M. Halmi;G. Desgardin;B. Raveau
  20. Solid State Commun. v.32 no.989 Ordering and Diffuse Phse Transition in Pb($Sc_0.5 Ta_0.5$)O₃ Ceramics C.G.F. Stenger;F.L. Scholten;A.J. Burggraaf
  21. J. Appl. Phys. v.51 no.2 Electrostrictive Effect in Lead Magnesium Niobate Signle Crystals K. Uchino;S. Nomura;L.E. Cross;S.J. Jang;R.E. Newnhan
  22. J. Am. Ceram. Soc. v.73 no.10 Diffuseness as a Useful Parmeter for Relaxor Ceramics S.M. Pilgrim;A.E. Suterland;S.R. Winzer
  23. Proc. 6th IEEE Int. Symp. Appl. Ferroelectrics v.153 Low Temperature Fired Lead Magnesium Niobate S.L. Swartz;G.O. Dayton;D.K. Laubscher
  24. Phys Rev. Lett. v.33 Angular Forces in Tetrahedral Solids W.A. Harrison;J.C. Phillips
  25. Ceramic Dielectrics abd Capacitors J.M. Herbert