Wear Mechanism of MgO-C Refractory with Thermite Reaction Products of MgO and Al

MgO와 Al의 테르밋 반응생성물이 첨가된 MgO-C계 내화재료의 용손 기구

  • 최태현 (경남대학교 무기재료공학과) ;
  • 전병세 (전남대학교 무기재료공학과)
  • Published : 1996.07.01

Abstract

Thermite reaction products of MgO and Al were added to MgO-C refractory to improve the properties of corrosion against the attack of slag, oxidation and mechanical spalling. Corrosion rate of MgO-C-MgAl2O4 spinel refractory at the ratio of 3.3(CaO/SiO2) slag was smaller than that of MgO-C and MgO-C-Al refractory. The excellent corrosion resistance of the MgO-C-MgAl2O4 spinel refractory against the slag attack was appeared by Al and MgAl2O4 spinel with high melting point and corrosion resistance and the high thermal conductivity and low thermal expansion of AIN. Hot M.O.R at 140$0^{\circ}C$ and the resistance of oxidation weight loss at 90$0^{\circ}C$ were 210kg/cm2 and -12% respectively.

Keywords

References

  1. Refractories, Japan v.41 no.8 Gas Permeability of Low Cement Castables S. Sakaki;H. Hashimoto
  2. Refractories, Japan v.42 no.10 Application of Alumina Spinel Castable to Teeming Ladle N. Hiroki;Y. Sato;H. Joguchi;M. Uchida
  3. Refractories, Japan v.47 no.4 Magnesia-Carbon Bricks Hiroshi Yasui
  4. Refractories, Japan v.46 no.9 Evaluation of Mechanical properties of MgO-C Brick Hiroshi Yasui;Satoshi Hayashi;Kazuo Nonobe;Hirokuni Takahashi;Akira Watanable
  5. 한국요업학회지 v.23 no.1 전로용MgO-C질 내화벽돌의 손상요인 김의훈;오영우;이철수;김종성;김종희
  6. Refractories, Japan v.41 no.10 Thermal and Mechanical Properties of Al₂O₃-MgO-C Brick Akiea Watanabe;Hirokuni Takahashi;Shigeyuki Takanaga;Nobuo Goto;Osamu Matsuura;Syoji Yoshida
  7. Taikabutsu v.35 no.11 Behaviors of SiC and Al added to Carbon Containing Refractories Akira Yamaguchi
  8. Taikabutsu v.36 no.4 Study of Wear Mechanism of Bottom Refractories for Torpedo Ladle Hidetoshi Shibata;Mitsuru Kondo;Shigeki Kashio
  9. Taikabutsu v.38 no.4 Hiroshi Kyoden;Hideaki Nishio;Katsunori Ito;Syuzo Horita
  10. Refractories, Japan v.3 no.11 Effect of Si on Corrosion and Thermal Shock Resistance of Trough Material Hirobumi Ninomiya(et al.)
  11. Refractories, Japan v.38 no.11 Bahavior of Different Metals Added to MgO-C Bricks Akira Watanabe;Hirokuni Takahashi;Shigeyuki Takanaga;Nobuo Goto;Kenji Anan;Mineo Uchida
  12. Refractories, Japan v.46 no.6 Effects of Aluminum on Oxidation of MgO-C Bricks Ichikawa Kenji;Hideaki Nishio;Osamu Nomura;Yasuhiro Hoshiyama
  13. Refractories, Japan v.49 no.9 Effects of Addition of Metal and CB to Magnesia Carbon Brick for Converter Seiji Hanagiri;Toshiya Harada;Seiji Aso;Shigeru Fujihaea;Hieoshi Yasui;Sigeyuki Takanaga;Hirokuni Takahashi;Akira Watanabe
  14. 한국요업학회지 v.33 no.2 SHS법에 의한 Magnesia-Alumina Spinel 제조와 특성 최태현;전병세
  15. J. Am. Ceram. Soc. v.46 no.8 Reactive Magnesia Spinel Preparation and Properties W.T. Bakker;J.G. Lindsay
  16. J. Am. Ceram. Soc. v.44 no.9 Preparation and Properties of Spinel Made by Vaper Transport and Diffusion in the System MgO-Al₂O₃ Louis Navias
  17. Cera. Bull v.57 no.7 S.M. Kim;P.S. Nicholson;W.K. Lu
  18. J. Kor. Ceram. Soc. v.27 no.8 Properties of Castable Refractories Containing Metallic Al Powder H.J. Kim;I.S. Kim;S.W. Lee
  19. Refractories, Japan v.36 no.12 Some Properties of Magnesia-Carbon Bricks Containing Mg and Al Akira Watanate;Hirokuni Takahashi;Toshiyuki Matsuki;Masashige Takahashi