Luminescence of $Y_{2-x}Ce_xSiO_5$ Phosphor

  • Han-Soo Kim (Department of Materials Science and Engineering, Korea University) ;
  • Sahn Nahm (Department of Materials Science and Engineering, Korea University) ;
  • Myong-Ho Kim (Department of Materials Science and Engineering, Changwon National University) ;
  • Kyung-Su Suh (Semiconductor Division, ETRI) ;
  • Jae-Dong Byun (Department of Materials Science and Engineering, Korea University)
  • Published : 1997.12.01

Abstract

Photoluminescence (PL) and cathodoluminescence (CL) characteristics of Ce-activated $Y_{2-x}Ce_xSiO_5$ have been investigated as functions of Ce concentration and firing condition. According to the X-ray, PL and CL results, $Y_2SiO_5$ is found to have two phases depending on the firing temperature. For the specimen fired above 127$0^{\circ}C$, the emission band peaked at 395nm with a shoulder at 424 nm under ultraviolet (u.v.) and cathode-ray (c.r.) excitation. However, for the specimen fired below 120$0^{\circ}C$ in air the peak was observed at 424 nm and it shifted to longer wavelength with reduction level. The reduced specimen for x=0.02 showed the brightest emission under u.v. excitation whereas under c.r. excitation the brightest emission was observed for the reduced specimen for x=0.06.

Keywords

References

  1. J. Electrochem. Soc. v.116 The Afterglow of Some Old and New $Ce^{3+}$-Activated phosphors A.H. Gomes de Mesquita;A. Bril
  2. Mat. Res. Bull. v.4 Preparation and Catiodoluminescence of $Ce^{3+}$-Activated Yttrium Silicate and Some Isostructural Compounds A.H. Gomes de Mesquita;A. Bril
  3. Am. Mineral. v.53 JCPDS card (No. 21-1456) Private Communication Ito;Johnson
  4. Am. Mineral. v.53 JCPDS card (No. 21-1458) Private Communication Ito;Johnson
  5. J. Electrochem. Soc. v.135 Single-Crystal Rare-Earth-Doped Yttrium Orthosilicate phosphors J. Shmulovich;G.W. Berkstresser;C.D. Brandle;A. Valentino
  6. Comprehensive Inorganic Chemistry v.4 M. Cannon Sneed;Robert C. Brasted