Effect of Light Metal Ions and Competition among Heavy Metal Ions during the Adsorption of Heavy Metal Ions by Bark

수피에 의한 중금속 흡착시 경금속의 영향과 중금속간의 흡착 경쟁

  • Published : 1997.06.30

Abstract

When the light metals such as $Ca^{++}$ and $Mg^{++}$ were added to heavy metal solution, the adsorption of heavy metals was increased by 20 to 30% more, but there were no differences between species. $Pb^{++}$ was the most adsorbed metal(99.5%), and the adsorption ratio of $Cd^{++}$ was significantly improved. In addition, when the light metal concentration was increased to 100ppm, the adsoption ratios of all four heavy metals were reached to 92 to 99%, while coniferous barks showed only 85 to 92%. On the mixture of four heavy metals, the adsorbed amount of each metal was significantly reduced, compared with that of one heavy metal, while $Zn^{++}$ showed the adsorption improvement to 95%. On the column experiment, $Pb^{++}$ was almost completely adsorbed in the upper part of column, and the adsorbed amount of $Cu^{++}$ was gradually decreased depending on column depth. However, $Cd^{++}$ and $Zn^{++}$ were not influenced by column height, and constantly adsorbed on various column height. Based on the above results, each heavy metal had different adsorption mechanism.

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