A Study on $SO_2$Removal in Flue Gas by Semidry Flue Gas Desulfurization Method

반건식 배연탈황법에 의한 연소 페가스 중 $SO_2$제거에 관한 연구

  • Published : 1998.08.01

Abstract

The investigation on the removal of 502 gas fro.In flue gas which causes serious air pollution was made by using a semi dry flue gas desulfurization method. Experiments were carried out as a function of process variables which would affect SO2 removal efficiency. Process variables inclilded SO2 inlet concentration, inlet temperature of simulated flue gas, sorbent weight fraction, and volume flow rate of sorbent slurry. In this study, used sorbent was Ca(OH), and simulated flue gas was prepared by mixing pure SO2 gas with air. Experimental conditions were varied at 140~18$0^{\circ}C$ of inlet temperature of the simulated flue gas, 500~2000ppm of inlet SO2 concentration, 0.4~1.0% of sorbent concentration, and 10~25 mL/min of flow rate of sorbent slurry. Among process variables, inlet concentration of SO2 was found to be the most significant factor to affect SO2 removal efficiency. The concentration of Ca(OH2) had a lower effect on SO2 removal than SO2 inlet concentration removal amount was 0.108, 0.141, 0.153 g SO2/g Ca(OH)2 respectively- As 200 mmol of HNO3 was added into slurry to improve removal efficiency, initial pH was maintained and solubility of slurry increased, so that removal efficiency elevated. Adding over 200 mmol of HNO3 into slurry caused removal efficiency lower. Therefore it could be concluded the optimum was 200 mmol of HNO3 input.

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References

  1. G7과제 보고서 산업용 배연탈황공정 개발을 위한 단위장치 개발 나진균
  2. 환경백서 환경처
  3. EPA/EPRI First Combined FGD and Dry control Symp FGD research and development status in US Delleney, R.D.
  4. Chemical Engineering Science v.46 no.4 The kinetics of the absorption of sulfur dioxide in calcium hydroxide suspension Ruhland, F.;Kind, R.
  5. J. Air Waste Mangement Association v.42 no.1 Current Status of the ADVA-CATE Process for Flue Gas Desulfurization Halt, B.W.;Sedman, C.B.
  6. J. Air Waste Management Association v.40 no.7 A simple model for $SO_2$ Removal in the Duct Injection Process Harriot, P.
  7. Method of air sampling and analysis ($3^{rd}$ ed.) James, P. Lodge
  8. Heated fly ash/hydrated lime slurry for $SO_2$ removal in spray absorbers v.34 John, F. Sanders
  9. Environmental Science and Technology v.28 no.2 Effect of salts on preparation and use of calcium silicates for flue gas desulfurization Kurt, K. Kind
  10. J. Air Waste Management Association v.40 no.7 A combined $Ca(OH)_2$/$NH_3$ Flue Gas Desulfurization Prcess for High sulfur coal Pakrasi, A.;Davis, W. T.;Reed, G. D.
  11. Chemical engineer's Handbook Perry, R. H.
  12. EPA/EPRI First Combined FGD and Dry $SO_2$ control Sym. An overview of EPA's program for retrofit sorbent injection technologies Stern, R.D.
  13. First Combined FGD and dry $SO_2$ control symp. EPRT Perspective on $SO_2$ control technologies Torrens, I. M.