Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Interactions between Polyelectrolyte Based on Crosslinked Chitosan and Amphoteric Surfactant

가교화 키토산을 기저로 한 고분자 전해질과 양쪽성 계면활성제의 상호작용

  • Published : 1999.09.01

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Abstract

The interactions between polyelectrolyte based on cationic chitosan and an amphoteric surfactant, N-dodecyl-N,N-dimethyl-3-ammonia-1-propanesulfonate (DAP), were described. Chitosan films were crosslinked with epichlorohydrin. The binding isotherms were determined potentiometrically and expressed by using the sequence generating function (SGF) method. The degree of binding of the crosslinked chitosan was compared to the degree of binding of chitosan in free solution. A discontinuous volume transition was observed in the crosslinked chitosan gels as the binding with DAP proceeded. And collapse of chitosan gel also occurred. The oleophilic behavior of the chitosan/DAP complex was demonstrated by the affinity of these complexes for oleophilc dyestuff.

Keywords

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