Korean Journal of Air-Conditioning and Refrigeration Engineering (설비공학논문집)

The Society of Air-Conditioning and Refrigerating Engineers of Korea (대한설비공학회)
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An Experimental Study on Vapor-Liquid Equilibria of HFC and HC Refrigerant Mixtures

탄화수소 및 불화탄화수소 혼합냉매의 기상-액상 평형에 관한 실험적 연구

  • Published : 2000.11.01
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Abstract

Isothermal vapor-liquid equilibrium(VLE) data have been obtained for the systems of propane(R290)+1,1,1,2-tetrafluoroethane(R134a) and 1,1,1,2-tetrafluoroethane(R134a)+isobutane(R60A) in the temperature range of 253.15 to 323.15K. Experiments were performed in a circulation type apparatus by injecting vapor through liquid pool using a magnetic pump. Both systems form azeotropes in the temperature range of this study. The experimental results were estimated with the Peng-Robinson equation of state. When the temperature-dependent binary interaction parameter was used in the Peng-Robinson equation of state, the absolute average deviation of the measured bubble point pressures from the values correlated by the Peng-Robinson equation was 0.65% and 0.78% for R290+R134a and R134a+600a, respectively. Azeotropic compositions for both systems were presented.

Keywords

References

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