An Experimental Study on Thermal Properties of Clathrate for Cold Storage Applications

저온축열용 포접화합물의 열물성에 관한 실험적 연구

  • 한영옥 (조선대학교 대학원) ;
  • 정낙규 (조선대학교 공과대학 기계공학부) ;
  • 김진흥 (조선대학교 공과대학 기계공학부)
  • Published : 2000.08.01

Abstract

The objective of this paper is to investigate the thermal properties of TMA clathrate applicable to cold storage system for building air-conditioning. Especially, the test tube experiments are peformed by comparing and analyzing the temperature of phase change, specific heat and subcooling characteristic according to the variation of concentrations and temperature of heat source in TMA clathrate. The results are summarized as follows; 1) temperature of phase change is dropped as the temperature of heat source is lower, 2) the effect of subcooling suppression with about $9.3^{\circ}C$ is confirmed when the temperature of heat source is $-10^{\circ}C$ in case of 30wt%, while the temperature of subcooling is about $0^{\circ}C$ when the temperature of heat source is $-15^{\circ}C$ in case of 25, 29wt% and 30wt% . Thus, the effect of subcooling suppression is greater as the temperature of heat source is lower. Additionally, the concentrative study is needed on mass concentration causing the phase change without subcooling phenomenon when the temperature of heat source is $-15^{\circ}C$ Thus, it is concluded that TMA clathrate has proper properties as the cold storage medium for building air-conditioning.

Keywords

References

  1. Air-Conditioning and Refrigeration Engineering v.23 no.2 Systematic Effects of Ice Storage System Ice Storage Research Group KAITECH
  2. Development of Ice storage system Technologies for Utilization of Night Electric Power.IT no.1 Yoo, J. I.;Yun, J. H.;Kang, H. G
  3. Thermodynamic properties of gas hydrates Mol. Phys. v.1 Van der Waals;J. H.;Platteeuw, J. C.
  4. Adv. In Chem. Phy. v.2 Clathrate solutions Van der Waals;J. H.;Platteeuw, J. C.
  5. Pure & Appl. Chem. v.64 no.1 Thermody-namic study of ice and clathrate hydrates Hiroshi Suga;Takasuke Metsuo;Osamu Yamamuro
  6. J. Inclusion Phenom. Mol. Recognit. Chem. v.8 Dynamic and Thermodynamic Properties of Clathrate Hydrates Belosludov, V. R.;Lavrentiev, M. YU.;Dyadin, YU
  7. Journal of the American Chemical Society v.72 Some vapor pressures and the critical constants of trimethylamine Day, H. O.;Felsing, W. A.
  8. Preceding of the intersocity energy conversion energy conference v.4 Use of lathrates for "Off-Peak" thermal energy storage McCormack, Richard A.
  9. J. of Japan Ind. & Eng. Chemistry v.46 no.7 Cold Thermal Energy Storage by Crystallization of Gas Hydrates Kawasaki, S.;Akiya, T.
  10. Industry and Energy Development of Clathrate Cool Storage System Yun, J. H.;Yun, C. H.;Yoo, J. I.
  11. JSME, Series B v.59 no.560 Effect of Various Parameters on a Supercooling Phenomenon of Still Bulk Water and Water Solution Hideo INABA;Kengo TAKEYA;shigeru NOZU
  12. JSME, Series B. v.58 no.553 A Study on Latent Heat Storage Using a Supercooling Condition of Hydrate Hideo INABA;Hideo OTAKE;shigeru NOZU;Takeyuki FUKUDA
  13. Ga Na Da Chemical Books Co Chemical Production Dictionary The 2nd volume Moon, S. H.
  14. Chemical Dictionary v.6 Editorial committee of Chemical Dictionary
  15. Hydrocarbons processing Physical Properties of Hydrocarbons Gallant, R. W.
  16. SAREK 95-w-063 A Study on Subcooling Characteristics of Clathrate Cold Storage Medium Ha, S. J.;Lee, C. S.;Kim, J. H.;Kim, S. H.