Journal of Korea Society of Waste Management (한국폐기물자원순환학회지)

Korea Society of Waste Management (한국폐기물자원순환학회)
권호 표지

Reductive Dechlorination of Chlorophenols by Palladized Iron

팔라듐으로 코팅된 영가철을 이용한 염화페놀류의 환원적 분해

Kim, Young-Hun
김영훈

  • Published : 20020000
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Abstract

Palladium coated iron (Pd/Fe), a bimetal, was investigated for its potential to degrade less chlorophenols. Catalytically modified zero valent iron (Pd/Fe) was prepared by reductive adsorption of the secondary metal on iron and tested as reductant. The results showed that Pd/Fe rapidly degraded three monochlorophenols and two dichlorphenols. Phenol and cyclohexane were detected as daughter products. Based on the mass balance, the degradation turned out mainly dechlorination. In the kinetic study, the reaction rate was in order of 4-CP > 3-CP > 2-CP>2,30DCP > 2,4-DCP. The higher degradation rate for less chlorinated phenol agreed with the result of previous studies for chloroethenes. The degradation rate was proportional to the metal surface area. The degradation pathaways were also discussed

Keywords

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