Temperature and Local Wind Flow Influencing Surface Ozone Enhancement in Seoul and Busan, Korea

서울 및 부산지역에서 기온과 국지풍이 지표 고농도 오존 발생에 미치는 영향

Kim, Yoo-Keun;Moon, Yun-Seob;Oh, In-Bo;Hwang, Mi-Kyoung
김유근;문윤섭;오인보;황미경

  • Published : 20020800

Abstract

This paper analysed the effects of surface air temperature and local wind flow on surface ozone enhancement in two major Korean cities (Seoul and Busan). The analysis was based on hourly surface ozone and meterological data during the ozone season from 1998 to 2000. The relationships between the daily maximum temperature and ozone concentrations (1-h and 8-h average) were found to be weak in Seoul and insignificant in Busan. However, the probabilities of ozone exceedences above 8-h 60 ppb increased with temperature in both cities and exceeded 60% in Seoul for daily maximum temperature above $30^{\circ}C$. High ozone concentrations in both cities were observed under the low wind speed (< 3 $ms^{-1}$) during the morning and were related to the wind direction during the afternoon: westerly winds in Seoul and southerly winds in Busan (3-5 $ms^{-1}$). Furthermore, horizontal distributions of ozone exceedences and daily maximum 8-h ozone concentrations for a given wind speed in the daytime (1400-1600 LST) during episode days showed that high ozone concentrations were elevated around down town areas and were distributed more widely under low wind speed. On days with moderate wind, relatively high ozone concentrations occurred slightly downwind in the urban plume. In particular, the elevated ozone concentrations in Busan was observed along the coastal area under all given wind speed. As a result, ozone episodes in Seoul originated not only mainly in the photochemical activity due to the high surface air temperature but also partly in the weaken local advection from the western region, and that in Busan occurred in both the partly photochemical reaction along high air temperature of the coastal region and the strong transport of the rich air of ozone and its precursors gases due to the see-breeze of the southerly winds.

Keywords

References

  1. 기상청, 1998-2000: 기상월보
  2. 김영성, 2000: 우리나라 오존농도 변화 추이와 주요인자, 한국대기환경학회지, 16(6), 607-623
  3. 김영성, 김영진, 윤순창, 1999: 고농도 오존일의 강우와 운량, 한국대기환경학회지, 15(6), 747-755
  4. 오현선, 김영성, 1999: 서울.수도권 지역 고농도 오존 사례의 지상 및 종관기상 특성, 한국대기 환경학회지, 15(4), 441-455
  5. 이화운, 김유근, 정우식, 2000: 복잡한 연안지역에서 해풍시작시 지형의 영향에 대한 수치모의, 한국기상학회지, 36(5), 561-572
  6. 임헌호, 2000: 부산지역에서 해륙풍일의 선정과 기후학적인 특성에 관한 연구, 부산대학교 석사학위논문, 108pp
  7. 정용승, 정재섭, 1991: 서울 수도권 지역의 광화학오존 에 관한 연구, 한국대기보전학회지, 7(3), 169-179
  8. 허정숙, 김태오, 김동술, 1999: 오존 대기 환경기준의 비교 연구, 한국대기환경학회지, 15(2), 159-173
  9. 환경부, 2000: 환경연감 2000, 102pp
  10. 환경부, 2001: 대기환경연보, 35pp
  11. Chan, C.Y. and L.Y. Chan, 2000: The effect of meteorology and air pollution transport on ozone episodes at a subtropical coastal Asian city, Hong Kong, J. Geophys. Res., 105, 20707 -20724 https://doi.org/10.1029/2000JD900140
  12. Chock, D.P., T.Y. Chang, S.L. Winkler, and B.I. Nance, 1999: The impact of an 8h ozone air quality standard on ROG and NOx controls in Southern California, Atmos. Environ., 33, 2471-2485 https://doi.org/10.1016/S1352-2310(98)00381-1
  13. Chung, Y.S., 1977: Ground-level ozone and regional transport of air pollutants, J. Appl. Met., 16, 1127-1136 https://doi.org/10.1175/1520-0450(1977)016<1127:GLOART>2.0.CO;2
  14. Gladstone, K.P., H. Niki, P.B. Shepson, J.W. Bottenheim, H.I. Schiff, and H.S. Sandhu, 1991: Photochemical oxidant concentrations in two Canadian prairie cities: model evaluation, Atmos. Environ., 25B, 243-254 https://doi.org/10.1016/0957-1272(91)90060-R
  15. Ghim, Y.S. and Y.S. Chang, 2000: Characteristics of ground-level ozone distributions in Korea for the period of 1990-1995, J. Geophys. Res., 105, 8877-8890 https://doi.org/10.1029/1999JD901179
  16. Jo, W.K., I.H. Yoon, and C.W. Nam, 2000: Analysis of air pollution in two major Korea cities: trends, seasonal variations, daily 1-hour maximum versus other hour-based concentrations, and standard exceedances, Environmental Pollution, 110, 11-18 https://doi.org/10.1016/S0269-7491(99)00284-5
  17. Kim. J. Y., and Y. S. Ghim, 2002: Effects of the density of meteorological observations on the diagnostic wind fields and the performance of photochemical modeling in the greater Seoul area, Atmos. Environ., 36, 201-212 https://doi.org/10.1016/S1352-2310(01)00443-5
  18. Kim, Y.K., H.W. Lee, J.K. Park, and Y.S. Moon, 2002: The stratosphere-troposphere exchange of ozone and aerosols over Korea, Atmos. Environ., 36(3), 449-463 https://doi.org/10.1016/S1352-2310(01)00370-3
  19. Lu, R. and R.P. Turco, 1994: Air pollutant transport in a coastal environment. PartⅠ: two-dimensional simulations of sea-breeze and mountain effects, j. Atmos. Sci., 15(15), 2285-2308
  20. Lin, C.-Y.C., D.J. Jacob, and A.M. Fiore, 2001: Trend in exceedances of the ozone air quality standard in the continental Unite States, 1980-1998, Atmos. Environ., 35, 3217-3228 https://doi.org/10.1016/S1352-2310(01)00152-2
  21. Liu, C.M., C.Y. Huang, S.L. Shieh, and C.C. Wu, 1994: Important meteorological parameters for ozone episodes experienced in the Taipei basin, Atmos. Environ., 28, 159-173 https://doi.org/10.1016/1352-2310(94)90031-0
  22. MacDonald, C. P., P.P. Roberts, H.H. Main, T.S. Dye, D.L. Coe, and J. Yarbrough, 2001: The 1996 Paso del Narte Ozone Study: analysis of meteorologucal and air quality data that influence local ozone concentrations, Sci. Total Environ., 276, 93-109 https://doi.org/10.1016/S0048-9697(01)00774-4
  23. McElroy, J. L. and T. B. Smith, 1991: Lidar Descriptions of mixing-layer thickness characteristics in a complex terrain/coastal environment.J. Appl. Met., 30, 585-597 https://doi.org/10.1175/1520-0450(1991)030<0585:LDOMLT>2.0.CO;2
  24. McElroy, J. L. and T.B. Smith, 1992: Creation and fate of ozone layers aloft in Southern California, Atmos. Environ., 26, 1917-1929
  25. Mckendry, I. G., 1993: Ground-level ozone in Montreal, Canada, Atmos. Environ., 35, 3217-3228 https://doi.org/10.1016/S1352-2310(01)00152-2
  26. National Research Council, 1991: Rethinking the ozone problem in urban and regional air pollution, National Academy Press, Washington, D.C
  27. Olszyna, K. J., M. Luria, and J.F. Meagher, 1997: The correlation of temperature and rural ozone levels in southeastern U.S.A., Atmos. Environ., 31, 3011-3022 https://doi.org/10.1016/S1352-2310(97)00097-6
  28. Seinfeld, J. H., 1989: Urban air pollution: state of the science, Science, 243, 745-752 https://doi.org/10.1126/science.243.4892.745
  29. Sillman, S. and P.J. Samson, 1995: Impact of temperature on oxidant photochemistry in urban, polluted rural and remote environments, J. Geophys. Res., 100, 11947-11958
  30. Simpson J. E., 1994: Sea breeze and local winds, Cambridge University Press, 85-94
  31. U.S. EPA, 1996: National ambient air quality standards for ozone: Proposed decision. 40 CFR Part 50
  32. Vukovich, F.M., 1994: Boundary layer ozone variations in the eastern United states and their association with meteorological variations: Long term variations, J. Geophys. Res., 99, 16839-16850 https://doi.org/10.1029/93JD02554
  33. Wang, T., Y.Y. Wu, T.F. Cheung, and K.S. Lam, 2001: A study of surface ozone and the relation to complex wind flow in Hong Kong, Atmos. Environ., 35, 3203-3215 https://doi.org/10.1016/S1352-2310(00)00558-6
  34. Wu, H.W.Y. and L.Y. Chan, 2001: Surface ozone trends in Hong Kong in 1985-1995, Environment International, 26, 213-222 https://doi.org/10.1016/S0160-4120(00)00108-2