DOI QR코드

DOI QR Code

Comparison of the Cold-Pressed Peel Oil Composition between ]Korean and Japanese Satsuma Mandarin (Citrus unshiu Marcov. forma Miyagawa-wase) by GC, GC-MS and GC-O

  • Published : 2002.03.01

Abstract

The comparison of the volatile flavor components from Korean and Japanese Satsuma mandarin (C. unshiu Marcov. forma Miyagawa-wase) peel oils, isolated by cold-pressing, was performed by gas chromatography, mass-spectrometry and gas chromatography-olfactometry (GC-O). Eighty-five volatile components were identified in each oil by GC and GC-MS. Forty-three components were detected in each oil by GC-O. The total amount of monoterpene hydrocarbons was 95.88% (Korean mandarin) and 95.29% (Japanese mandarin). Limonene, ${\gamma}$-terpinene, myrcene and $\alpha$-pinene were the main components of the cold-pressed oils from the both samples. The volatile composition of the Japanese mandarin was characterized by a higher content of sesquiterpene hydrocarbons, especially bicyclogermacrene, $\alpha$-humullene and valencene. The volatile composition of two samples can easily be distinguished by the percentages of aldehydes, ketones and esters, which were found at higher levels in the Japanese mandarin. The sweet and fruity flavor was stronger in the Korean mandarin oil while herbaceous flavor was stronger in Japanese sample. From GC-O data it is suggested that the sweet and fruity flavor of the Korean mandarin resulted from terpinolene and linalool, and the herbaceous note of the Japanese mandarin from $\alpha$-humullene, nepal, ι-carvone and perill aldehyde.

Keywords

References

  1. Citrus science and technology v.2 Fruit production-with special emphasis on fruit for processing Cooper,W.C.;Chapot,H.;Nagy,S.(ed.);Shaw,P.(ed.);Veldhuis,M.K.(ed.)
  2. Citrus science and technology Nagy,S.;Shaw,P.;Veldhuis,M.K.
  3. Kankitsu no hinshu Shizuoka Prefectural Agricultural Cooperation of Citrus Fruits Iwamasa,M.
  4. J Japan Soc Hort Sci v.41 Evaluation of edible quality of commercial Satsuma mandarin (Citrus unshiu MARC.). Ⅱ. Relationship of palatability with refractive index and pH of commercial Satsuma mandarin Iino,K.;Osodo,K. https://doi.org/10.2503/jjshs.41.398
  5. J Japan Soc Hort Sci v.46 Evaluation of edible quality of commercial Satsuma mandarin (Citrus unshiu MARC.). Statistical analysis of organoleptic evaluation and sampling for the grading Iino,K.;Osodo,K. https://doi.org/10.2503/jjshs.46.548
  6. J Japan Soc Hort Sci v.41 Evaluation of edible quality of commercial Satsuma mandarin (Citrus unshiu MARC.). Ⅰ. Analysis of the characters of commercial Satsuma mandarin based on the principal components Osodo,K.;Iino,K. https://doi.org/10.2503/jjshs.41.83
  7. Sci Rept Fac Agr Kobe Univ v.14 The influence of ethylene, oxygen, and carbon dioxide on the maturation of bananas and Satsuma Mandarin fruits Terai,H.;Mizuno,S.
  8. J Japan Soc Hort Sci v.52 Effects of ethylene on peel puffing of Satsuma mandarin Maotani,T.;Kawase,K.;Kamuro,Y.;Hirai,K. https://doi.org/10.2503/jjshs.52.238
  9. Agr Biol Chem v.5 Composition of peel oil from Citrus unshiu Yamanishi,T.;Kobayashi,A.;Mikumo,Y.;Nakasone,Y.
  10. Agr Biol Chem v.33 Composition of peel oil from Citrus unshiu Kita,Y.;Nakatani,Y.;Kobayashi,A. https://doi.org/10.1271/bbb1961.33.1559
  11. J Japan Sci Hort Sci v.42 Studies on the coloring of Satsuma mandarin (Citrus unshiu Marc.). Ⅲ. The relation of fruit condition and coloring by the treatment of sealing with ethylene for 15 hours Kitagawa,H.;Tarutani,T. https://doi.org/10.2503/jjshs.42.65
  12. Nippon Ngeikagaku Kaishi v.57 Aroma components of Satsuma mandarin oranges grown in vinyl houses and in open fields (Quality of Satsuma mandarin fruits from vinyl houses cultures.) Sawamura,M.;Yanogawa,K.;Hattori,M. https://doi.org/10.1271/nogeikagaku1924.57.863
  13. Recent Res Devel Agricultural & Food Chem v.4 Volatile components of essential oils of Citrus genus Sawamura,M.
  14. J Agric Food Chem v.36 Quantitative determination of volatile constituents in the pummelo (Citrus grandis Os-beck forma Tosabuntan) Sawamura,M.;Kuriyama,T. https://doi.org/10.1021/jf00081a040
  15. Ph D Dissertation. Ehime University Studies on the chemotaxonomy of the Citrus genus Zheng,X.H.
  16. Flavour Fragr J v.11 Volatile leaf oils of some south-western and southern Australian species of the genus Eucalyptus. A. Subgenus Eudesmia: B. Subgenus Symphyomytus: (a) Section Exsertaria; (b) Series Globulares Bignell,C.M.;Dunlop,P.J.;Brophy,J.J.;Jackson,J.F. https://doi.org/10.1002/(SICI)1099-1026(199605)11:3<145::AID-FFJ565>3.0.CO;2-O
  17. Flavour Fragr J v.10 Determination of the enantiomeric composion of α-terpineol in essential oils Ravid,U.;Putievsky,E.;Katzir,I. https://doi.org/10.1002/ffj.2730100409
  18. Perfume and Flavor chemicals Arctander,S.
  19. J Agric Food Chem v.48 Composition of the essential oil of Citrus tamurana Hort. ex Tanaka(Hyuganatsu) Choi,H.S.;Sawamura,M. https://doi.org/10.1021/jf000651e

Cited by

  1. Volatile Constituents of Mandarin (Citrus reticulataBlanco) Peel Oil from Burundi vol.18, pp.6, 2006, https://doi.org/10.1080/10412905.2006.9699197
  2. Bioactive properties of Citrus unshiu’s essential oil for its application to textiles vol.14, pp.8, 2013, https://doi.org/10.1007/s12221-013-1295-9
  3. Volatile Profile of the Peel Oil of Kiyomi (Citrus unshiuMarcov. xC. sinensisOsbeck), A New Hybrid Sweet Citrus Fruit vol.21, pp.1, 2009, https://doi.org/10.1080/10412905.2009.9700099
  4. Essential oils of KenyanCitrus fruits: volatile components of two varieties of mandarins (Citrus reticulata) and a tangelo (C. paradisi×C. tangerina) vol.20, pp.1, 2005, https://doi.org/10.1002/ffj.1376
  5. Volatile Profiles in Cold-Pressed Peel Oil from Korean and Japanese Shiranui (Citrus unshiuMarcov. ×C. sinensisOsbeck ×C. reticulataBlanco) vol.70, pp.3, 2006, https://doi.org/10.1271/bbb.70.737
  6. Volatile Profile of the Peel Oil of ‘Setoka’ ([‘Kiyomi x Encore No.2’] x ‘Murcott’), A New Hybrid Sweet Citrus Fruit vol.22, pp.4, 2010, https://doi.org/10.1080/10412905.2010.9700342
  7. 노지 및 시설에서 재배된 한라봉의 기기분석 및 관능평가에 의한 향기특성 vol.34, pp.8, 2002, https://doi.org/10.3746/jkfn.2005.34.8.1239
  8. The Volatile Composition of Kiyomi Peel Oil (Citrus unshiu Marcov×C. sinensis Osbeck) Cultivated in Korea vol.13, pp.4, 2002, https://doi.org/10.3746/jfn.2008.13.4.290