Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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A Study on Natural Dyeing (5) - Adsorption Properties of Berberine for Silk Fabrics -

천연염색에 관한 연구(5) -황벽색소 베르베린의 견에 대한 염착특성 -

  • Published : 2002.04.01
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Abstract

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

Keywords

References

  1. N. Hollen, J. Saddler, A. L. Langford, and S. J. Kadolph, 'Textiles', Macmillan Publishing Co., 62(1988)
  2. M. L. Gulrajani, 'Chemical Processing of Silk', Indian Institute of Technology, 97 (1993)
  3. S. W. Nam, 'Studies on modernization. of dyeing method with traditional natural dyes', Ministry of Science & Technology, 420(1995)
  4. H. 0. So, 'A study of extracting of the coloring matters and standardizing of the dyeing conditions about the vegetable natural dyestuffs', Ministry of Science & Technology, 50(1995)
  5. B. H. Kim and S. S. Cho, Dyeing of silk fabric with Amur cork tree, J. Kor. Soc. of Dyers and Finishers, 8(1), 26-33(1996)
  6. K. S. Kim, Dyeing of silk fabric with Amur cork tree, 建國技術硏究論文志, 24, 215-219 (1999)
  7. K. R. Cho and M. J. Kang, Studies on the natural dyes(12), J. Kor. Soc. of Dyers and Finishers, 12(4), 13-21(2000)
  8. S. M. Park, '천연염색의 색상다양화 및 염색물의 견뢰도 향상 기술의 개발', 산업자원부, 61(2000)
  9. H. I. Kim, S. I. Eom, and S. M. Park, Loess dyeine on cotton fabrics using silane coupling agent, J. Kor. Soc. of Dyers and Finishers, 13(5), 320-345(2001)
  10. E. Haslam, Po1ypheno1-protein interactions, Biochem. J., 139, 285-288(1974)
  11. W. D. Loomis, Plant phenolic compounds and the isolation of plant enzymes, Methods Enzymol, 31, 423-438(1974)
  12. E. Haslam, Plant Phenolics, Phytochem, 11, 3391-3393(1972)
  13. A. E. Hagerman and L. G. Butler, Condensed tannin purification and Charac-tehzation of tannin-associated proteins, J. Asric. Food Chem, 28, 947-952(1980)
  14. H. I. Kim, S. I. Eom, and S. M. Park, A syudy on natural dyeing(3), J. Kor. Soc. of Dyers and Finishers, 13(5), 289-297(2001)
  15. J. P. Kim, '천연염색의 색상다양화 및 염색물의 견뢰도 향상 기술의 개발', 산업자원부, 191(2000)
  16. S. Yoshikawa and E. Doi, Interaction between tannic acid and antimony potassium tartrate, Sen-i Gakkaishi, 31(10), T-191-193 (1975)
  17. J. Shore, Aftertreatment of anionic dyes on nylon fibers, J.S.D.C., January, 3-12(1974)
  18. R. S. Davidson, The photodegradation of some naturally occurring polymers, journal of Photochemistry and Photobiology B ; Biology, 33, 3-25(1996)
  19. G. J. Smith, I. J. Miller, V. Daniels, and A. J. Smith, White wool, the growth of the ancient dye and an expanding color vocabulary. J.S.D.C., 113, 124-126(1997)
  20. S. K. Dho, Thermodynamics of reactive dyes with different functional groups, J. Kor. Soc. of Dyers and Finishers, 10(3), 168-174(1998)
  21. Y. J. Lim, N. S. Yoon, and S. H. Song, The effect of hydrophobic interaction on the binding of methyl orange and its hornologs with nylons, Journal of the Korean Society of Textile Engineers and Chemists, 26(1), 41-47(1989)
  22. J. Chrastil, Adsorption of Direct Dyes on Cotton, Tex. Res. J., 60, 413(1990)
  23. M. Dohmyo, Y. Shimizu, and M. Kimura, Dyeing of silk with a basic dye, J. Seric. sci. Jpn, 60(30), 161-165(1991)
  24. J. Komiyama and T. Iijima, Some aspects of the Light Fastness of Reactive Azo-Dyes on Cellulose under Wet Condition. J.S.D.C., 93, 217(1977)
  25. H. Zollinger, Kinetics of Dyeing from Finite Baths Based on New Information, J.S.D.C., 81, 345(1965)
  26. T. Takagishi, K. Takami, and N. Kuroki, J. Poly. Chem. Ed., 13, 437(1975)
  27. Y. J. Lim, N. S. Yoon, and C. M. Lee, Thermodynamic analysis for the binding of methyl orange with nylons, Journal of the Koreon Society of Textile Engineers and Chemists, 24(4), 318-323(1987)
  28. T. Sone, Y. Nakai, T. Yamazaki, and S. Ooya, Dyeing of silk with cationic dyes. Sen-i Gakkaishi, 41(4), T-164(1985)