Study for the Preparation of Deodorizing Fiber( III ) - Preparations of Deodorizing Fibers using $TiO_2$ and Effects of $TiO_2$ sol Concentration on the Deodorant Activity-

소취 섬유의 제조에 관한 연구(III) - 산화티탄(IV)을 이용한 소취 섬유의 제조 및 $TiO_2$ sol 용액의 농도가 소취율에 미치는 영향 -

  • Published : 2002.06.01

Abstract

The preparations of deodorizing fibers using $\textrm{TiO}_2$ have been investigated. $\textrm{TiO}_2$ is known to be an excellent photocatalyst for the degradation of organic and inorganic contaminants in water. $\textrm{TiO}_2$ catalyst have been supported on the glass fiber by a dip-coating procedure. The resulting materials have been characterized by XRD and SEM. The immobilized catalysts were tested in the photocatalytic degradation of $\textrm{NH}_3$, $\textrm{CH}_3\textrm{SH}$ and $\textrm{CH}_3\textrm{CHO}$. The deodorant activity(D.A.) of these deodorizing fibers was measured by chromogenic gas detector tubes. The efficient deodorant activity results have been achieved through the increase of $\textrm{TiO}_2$ sol concentration.

Keywords

References

  1. J. Photochem. Photobiol A:Chem v.87 Photocatalytic degradation of organic contaminants in water with TiO₂supported on polyethylene films K. Tennakone;C. T. K. Tilakaratne;I. R. M. Kottegoda https://doi.org/10.1016/1010-6030(94)03980-9
  2. Desalination v.108 Wastewater detoxification of organic and inorganic toxic compounds with solar collector P. A. S. S. Marques;M. F. Rosa;F. Mendes;M. C. Pereira;J. Blanco https://doi.org/10.1016/S0011-9164(97)00029-5
  3. Solar Energy v.56 no.5 Photocatalytic degradation of industrial residual waters S. M. Rodriguez;C. Richter;J. B. Galvez;M. Vincent https://doi.org/10.1016/0038-092X(96)00023-0
  4. Solar Energy v.56 no.5 Solar photocatalytic processes for the purification of water : State of development and barriers to commercialization Y. Parent;D. Blake;M. B. Kim;C. Lyons;C. Turchi;A. Watt;E. Wolfrum;M. Prairie https://doi.org/10.1016/0038-092X(96)81767-1
  5. Solar Energy v.56 no.5 TiO₂fixed-bed reactor for water decontamination using solar light R. F. P. Nogueira;W. F. Jardim https://doi.org/10.1016/0038-092X(96)00036-9
  6. v.91 On the M. Bideau;B. Claudel;C. Dubien;L. Faure;H. Kazouan
  7. Applied Catalysis B : Environmental v.7 Preparation and characterization of TiO₂ photo catalysts supported on various rigid supports(glass, quartz and stainless steel). Comparative studies of photocatalytic activity in water puification A. Fernandez;G. Lassaletta;V. M. Jimenez;A. Justo;A. R. Gonzalez-Elipe;J. M. Herrmann;H. Tahiri;Y. Ait-Ichou https://doi.org/10.1016/0926-3373(95)00026-7
  8. Applied Catalysis B : Environmental v.13 Characterization and photocatalytic activity in aqueous medium of TiO₂ and Ag-TiO₂ coatings on quartz J. M. Herrmann;H. Tahiri;Y. Ait-Ichou;G. Lassaletta;A. R. Gonzalez-Elipe;A. Fernandez https://doi.org/10.1016/S0926-3373(96)00107-5
  9. Catalysis Today v.39 Supported titanium oxide as photocatalyst in water decomposition : State of the art R. L Pozzo;M. A. Baltanas;A. E. Cassano https://doi.org/10.1016/S0920-5861(97)00103-X
  10. Chem. Rev. v.90 The sol-gel process L. L. Hench;J. K. West https://doi.org/10.1021/cr00099a003
  11. J. Mater. Sci. Lett v.18 Titanium dioxide synthesis by sol gel methods and evaluation of their photocatalytic activity D. Robert;J. V. Weber https://doi.org/10.1023/A:1006645930952
  12. J. Mater. Sci. Lett v.15 Study of the room temperature ageing effect on the structural evloution of gel-derived nanocry stalline titania powders X. Z. Ding;Y. Z.He https://doi.org/10.1007/BF00591650
  13. J. Mater. Sci. Lett v.14 Effect of hydrolysis water on the preparation of nano-crystalline titania powders via a sol-gel peocess X. Z. Ding;Z. Z. Qi;Y. Z. He https://doi.org/10.1007/BF02565273
  14. J. Photochem. Photobiol. A : Chem v.109 Phonol decomposition using Mⁿ / TiO₂ photocatalysts supported by the sol-gel thchnique on glass fibres V. Brezova;A. Blazkova;L. Karpinsky;J. Groskova;B. Havlinova;V. Jorik;M. Ceppan https://doi.org/10.1016/S1010-6030(97)00121-4
  15. Catalysis Today v.54 Photocatalytic deoxification with TiO₂ supported on glass-fibre using artificial and natural light D. Robert;A. Piscopo;O. Heintz;J. V. Weber https://doi.org/10.1016/S0920-5861(99)00190-X
  16. J. Mater. Sci. Lett v.14 Comparison of photocatalytic activity of sol-gel TiO₂ and P25 TiO₂ particles supported on the commercial fibreglass fabric M. Mikula;V. Brezova;M. Ceppan;L. Pach;L. Karpinsky https://doi.org/10.1007/BF00586156
  17. J. Photochem. Photobiol. A : Chem v.139 Comparison between the reactivity of commercial and synthetic TiO₂ photocatalyst A. Piscopo;D. Robert;J. V. Weber https://doi.org/10.1016/S1010-6030(01)00381-1
  18. Solar Energy v.70 Photocatalytic degradation of organic compounds in aqueous solution by a TiO₂-coated rotating-drum using solar light L. Zhang;T. Kanki;N. Sano;A. Toyada https://doi.org/10.1016/S0038-092X(00)00139-0
  19. Bull. Chem. Soc. Jpn v.58 Heterogeneous photocatalytic decomposition of phenol over TiO₂ powder K. Okamoto;Y. Yamanoto;H. Tanaka;M. Tanaka;A. Itaya https://doi.org/10.1246/bcsj.58.2015
  20. Journal of Cleaner Production v.6 Photocatalytic degradation of methylbutandioic acid(MBA) in TiO₂ aqueous suspension : in fluences of MBA adsorption on the solid semiconductor D. Robert;J. V. Weber https://doi.org/10.1016/S0959-6526(98)00016-X
  21. Adsorption v.6 Study of the adsorption of dicarboxylic acids on titanium dioxide in aqueous solution D. Robert;J. V. Weber https://doi.org/10.1023/A:1008973619801
  22. Applied Surface Science v.121;122 The surface structure of tatnium dioxide thin film photocatalyst N. Negishi;K. Takeuchi;T. Ibusuki
  23. Journal of Molecular Catalysis v.88 Removal of low concentration nitrogen oxides through photoassisted heterogeneous catalysis T. Ibusuki;K. Takeuchi https://doi.org/10.1016/0304-5102(93)E0247-E
  24. Chemosphere v.41 Degradation of short-chain alkyl and alkanolamines by TiO₂ and Pt/TiO₂-assisted photocatlysis M. Klare;J. Scheen;K. Vogelsang;H. Jacobs;J. A. C. Broekaert https://doi.org/10.1016/S0045-6535(99)00447-6