Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
권호 표지

Carbon Dioxide Ocean Sequestration Using Gas Hydrate

가스 하이드레이트를 이용한 이산화탄소의 심해저장

Lee, Heun;Lee, Cheol Su;Gang, Ju Myeong
이흔;이철수;강주명

  • Published : 20030000
⟨ Previous Next ⟩

Abstract

Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. The hydrate crystal structures were different depending on a kind of guest molecules. Recently, gas hydrates have attracted the attention of many investigators from all areas of natural gas production and environmental science from a fact that this compound could be formed from only host water and guest gas molecules. The most attrative application of hydrates is to dispose of carbon dioxide in the form of solid hydrates in the ocean to reduce atmospheric carbon dioxide concentration and mitigate global warming. Therefore, this paper summarized present research works concerning the carbon dioxide hydrate and suggested the connection between these results and the strategies for carbon dioxide sequestration. In addition, general topics and research trends related to carbon dioxide hydrate are presented with focusing on carbon dioxide ocean sequestration to resolve the global warming problems.

가스 하이드레이트란 고압 저온의 형성 조건에서 저분자량의 가스가 물분자들에 의해 만들어지는 격자 속으로 포집되면서 형성되는 특별한 결정 상태의 화합물을 일컫는 말이다. 가스 하이드레이트에 대한 존재가 알려진 것은 비교적 오래 되었으나, 물과 가스에 의해 형성되어 진다는 점에서 최근 관심이 증가되고 있다. 포집되는 가스의 종류에 따라 다양한 구조의 결정을 형성하는 하이드레이트는 최근 천연가스의 사용과 지구 온난화 가스에 대한 관심이 증가하면서 이들에 대한 활용을 모색하고자 연구가 진행되고 있는 상황이다. 따라서 본고에서는 가스 하이드레이트 활용 분야 중에서 최근 가장 주목받고 있는 분야, 즉 대표적 지구 온난화 가스인 이산화탄소의 심해저장과 관련하여 이산화탄소 하이드레이트에 관한 전반적인 연구 동향을 소개하도록 한다.

Keywords

References

  1. Climate Change 1995: The Science of Climate Change Houghton, J. T.;Meira Fildo, L. G.;Collander, B. A.;Harris, N.;Kattenberg, A.;Maskell, K.
  2. Chem. Eng. Prog. v.97 Kane, R. L.;Klein, D. L.
  3. Carbon Sequestration: State of the Science, A working paper for roadmapping future carbon sequestration R&D U.S. Department of Energy, Office of Science, Office of Fossil Energy
  4. Ocean Storage of CO₂ IEA GHG
  5. 4th International Conference on Greenhouse Gas Control Technologies Ocean Sequestration of CO₂: An Overview Herzog, H.
  6. Clathrate hydrate of natural gases(2nd ed.) Sloan, E. D.
  7. Progress in Inorganic Chemistry v.8 no.8 Jeffrey, G. A.;McMullan, R. K. https://doi.org/10.1002/9780470166093.ch2
  8. The Journal of Chemical Physics v.42 no.8 Polyhedral Clathrate Hydrates. IX. Structure of Ethylene Oxide Hydrate McMullan, R. K.;Jeffery, G. A. https://doi.org/10.1063/1.1703228
  9. The Journal of Chemical Physics v.42 no.8 Polyhedral Clathrate Hydrates. X. Structure of the Double Hydrate of Tetrahydrofuran and Hydrogen Sulfide Mak, T. C. W.;McMullan, R. K. https://doi.org/10.1063/1.1703229
  10. Proceedings of 3rd International Conference on Permafrost v.1 Davison, D. W.;El-Defrawy, M. K.;Fuglem, M. O.;Judge, A. S.
  11. Nature v.325 no.6100 A New Clathrate Hydrate Structure Ripmeester, J. A.;Tse, J. S.;Ratcliffe, C. I.;Powell, B. M. https://doi.org/10.1038/325135a0
  12. Proceedings of 2nd International Conference on Natural Gas Hydrates New Structures of Calthrates hydrates Udachin, K. A.;Lipkowski, J.
  13. Proceedings of 2nd International Conference on Natural Gas Hydrates Structure H Hydrates: the State-of-the-art Mehta, A. P.;Sloan, D. E.
  14. Rev. Chem. Eng. v.5 Phase Behavior in Systems Containing Clathrate Hydrates Holder, G. D.;Zetts, S. P.;Pradham, N.
  15. Adv. Chem. Phys. v.2 Clathrate Solutions van der Waals, J. H.;Platteeuw, J. C.
  16. The Journal of Chemical Physics v.38 no.12 Theory of Dissociation Pressures of Some Gas Hydarates McKoy, V.;Sinanoglu, O. https://doi.org/10.1063/1.1733625
  17. Industrial & Engineering Chemistry Process Design and Development v.11 no.1 Dissociation Pressures of Gas Hydrates Formed by Gas Mixtures Parrish, W. R.;Prausnitz, J. M. https://doi.org/10.1021/i260041a006
  18. Industrial & Engineering Chemistry Fundamentals v.19 no.3 Thermodynamic and Molecular Properties of Gas Hydrates from Mixtures Containing Methane, Argon and Krypton Holder, G. D.;Corbin, G.;Papadopoulos, K. D. https://doi.org/10.1021/i160075a008
  19. Chemical Engineering Science v.27 no.6 Equilibrium Constants from a Modified Redlich-Kwong Equation of State Soave, G. https://doi.org/10.1016/0009-2509(72)80096-4
  20. Fluid Phase Equilibria v.3 no.4 New Mixing Rules in Simple Equations of State for Representing Vapor-Liquid Equilibria of Strongly Non-Ideal Mixtures Huron, M. J.;Vidal, J. https://doi.org/10.1016/0378-3812(79)80001-1
  21. AIChE Journal v.36 no.12 High-Pressure Vapor-Liquid Equilibrium with a UNIFAC-Based Equation of State Dahl, S.;Michelsen, M. L. https://doi.org/10.1002/aic.690361207
  22. AIChE Journal v.48 no.6 Generalized Model for Predicting Phase Behavior of Clathrate Hydrate Yoon, J. H.;Chun, M. K.;Lee, H. https://doi.org/10.1002/aic.690480618
  23. Fluid Phase Equilibria v.175 no.1-2 Measurement and Prediction of Phase Equilibria for Water+CO₂in Hydrate Forming Conditions Yang, S. O.;Yang, I. M.;Kim, Y. S.;Lee, C. S. https://doi.org/10.1016/S0378-3812(00)00467-2
  24. Industrial & Engineering Chemistry Research v.32 no.7 Clathrate Hydrates Englezos, P. https://doi.org/10.1021/ie00019a001
  25. The Canadian Journal of Chemical Engineering v.72 no.5 Phase Eequilibrium Data on Carbon Dioxide Hydrate in the Presence of Electrolytes, Water Soluble Polymers and Montmorillonite Englezos, P.;Hall, S. https://doi.org/10.1002/cjce.5450720516
  26. Journal of Chemical & Engineering Data v.38 no.4 Equilibrium Conditions for Carbon Dioxide Hydrate Formation in Aqueous Electrolyte Solutions Dholabhai, P. D.;Kalogerakis, N.;Bishnoi, P R. https://doi.org/10.1021/je00012a045
  27. Industrial & Engineering Chemistry Research v.35 no.3 Carbon Dioxide Hydrate Equilibrium Conditions in Aqueous Solutions Containing Electrolyte and Methanol Using a New Apparatus Dholabhai, P. D.;Parent, J. S.;Bishnoi, P. R. https://doi.org/10.1021/ie950136j
  28. Fluid Phase Equilibria v.147 no.1 Phase Equilibria of Methane and Carbon Dioxide Hydrates in the Aqueous MgCl₂Solutions Kang, S. P.;Chun, M. K.;Lee, H. https://doi.org/10.1016/S0378-3812(98)00233-7
  29. Ph. D. Dissertation, Univ. of Michigan Larson, S. D.
  30. The Journal of Physical Chemistry B v.106 no.4 Effects of Pore Sizes on Dissociation Temperatures and Pressures of Methane, Carbon Dioxide, and Propane Hydrates in Porous Media Uchida, T.;Ebinuma, T.;Takeya, S.;Nagao, J.;Narita, H. https://doi.org/10.1021/jp012823w
  31. Langmuir v.18 no.24 Methane and Carbon Dioxide Hydrate Phase Behavior in Small Porous Silica Gels: Three-Phase Equilibrium Determination and Thermodynamic Modeling Seo, Y.;Lee, H.;Uchida, T https://doi.org/10.1021/la0257844
  32. Chemical Engineering Science v.38 no.7 A Kinetic Study of Mehthane Hydrate Formation Vysniauskas, A;Bishinoi, P. R. https://doi.org/10.1016/0009-2509(83)80027-X
  33. Canadian Journal of Chemistry v.46 no.24 Glew, D. N.;Hagget, M. L. https://doi.org/10.1139/v68-639
  34. Cryobiology v.8 no.3 Gas hydrates in aqueous-organic systems. VII. Linear crystallization velocities of the hydrates of ethylene oxide and tetrahydrofuran. Scanlon, W. J.;Fennema, O https://doi.org/10.1016/0011-2240(71)90047-2
  35. Chemical Engineering Science v.42 no.11 Kinetics of Gas Hydrate Formation from Mixtures of Methane and Ethane Englezos, P.;Kalogerakis, N. E.;Dholabhai, P. D.;Bishnoi, P. R. https://doi.org/10.1016/0009-2509(87)87016-1
  36. Chemical Engineering Science v.49 no.8 A Mass Transport Limited Model for the Growth of Methane and Ethane Gas Hydrates Skovborg, P.;Rasmussen, P https://doi.org/10.1016/0009-2509(94)85085-2
  37. Energy Conversion and Management v.34 no.9 Kinetics of Formation of CO₂Hydrate Shindo, Y.;Lund, P. C.;Fujioka, Y.;Komiyama, H. https://doi.org/10.1016/0196-8904(93)90055-F
  38. Chemical Engineering Science v.50 no.4 Hydrate Formation on the Surface of a CO₂Droplet in High-pressure, Low-temperature Water Teng, H.;Kinoshita, M.;Masutani, S. M. https://doi.org/10.1016/0009-2509(94)00438-W
  39. Korean Journal of Chemical Engineering v.13 no.6 Kinetics of Formation of Carbon Dioxide Clathrate Hydrates Chun, M. K.;Lee, H https://doi.org/10.1007/BF02706029
  40. The Journal of Physical Chemistry B v.105 no.19 Structure, Composition, and Thermal Expansion of CO₂Hydrate from Single Crystal X-ray Diffraction Measurements Udachin, K. A.;Ratcliffe, C. I.;Ripmeester, J. A. https://doi.org/10.1021/jp004389o
  41. Annals of the New York Academy of Sciences v.912 In Situ Observation of CO₂Hydrate by X-ray Diffraction Takeya, S.;Hondoh, T.;Uchida, T.
  42. Inclusion Compounds v.3 Davidson, D. W.;Ripmeester, J. A.;Atwood, J. L.(Ed.);Davies, J. E. D.(Ed.);MacNichol, D. D.(Ed.)
  43. Report C1181-895, National Research Council of Canada Solid State NMR Studies of Inclusion Compounds Ripmeester, J. A.;Ratcliffe, C. I.
  44. The Journal of Physical Chemistry v.94 no.25 Xenon-129 NMR Studies of Clathrate Hydrates: New Guests for Structure II and Structure H Ripmeester, J. A.;Ratcliffe, C. I. https://doi.org/10.1021/j100388a006
  45. The Journal of Physical Chemistry v.92 no.2 Low Temperature Cross Polarization/Magic Angle Spinning $^{13}C$ NMR of Solid Methane Hydrates: Structure, Cage Occupancy, and Hydration Number Ripmeester, J. A.;Ratcliffe, C. I. https://doi.org/10.1021/j100313a018
  46. Industrial & Engineering Chemistry Fundamentals v.19 no.4 Experimental Thermodynamics Parameters for the Prediction of Natural Gas Hydrate Dissociation Conditions Dharmawardhana, P. B.;Parrish, W. R.;Sloan, E. D. https://doi.org/10.1021/i160076a015
  47. The Journal of Physical Chemistry v.90 no.24 Xenon-129 NMR and the Thermodynamic Parameters of Xenon Hydrate Davidson, D. W.;Handa, Y. P.;Ripmeester, J. A. https://doi.org/10.1021/j100282a026
  48. Energy & Fuels v.12 no.2 The Diverse Nature of Dodecahedral Cages in Clathrate Hydrates As Revealed by $^{129}Xe\;and\;^{13}C$ NMR Spectroscopy: CO₂as a Small-Cage Guest Ripmeester, J. A.;Ratcliffe, C. I. https://doi.org/10.1021/ef970171y
  49. The Journal of Physical Chemistry B v.101 no.38 Measurement of Clathrate Hydrates via Raman Spectroscopy Sum, A. K.;Buruss, R. C.;Sloan, E. D. https://doi.org/10.1021/jp970768e
  50. The Journal of Physical Chemistry B v.106 no.37 Phase Behavior and Structure Identification of the Mixed Chlorinated Hydrocarbon Clathrate Hydrates Seo, Y.;Lee, H. https://doi.org/10.1021/jp025685z
  51. Energy Conversion and Management v.36 no.6 Raman Spectroscopic Analysis on the Growth Process of CO₂Hydrates Uchida, T.;Takagi, A.;Kawabata, J.;Mae, S.;Hondoh, T. https://doi.org/10.1016/0196-8904(95)00064-K
  52. Journal of Crystal Growth v.234 no.1 Growth Kinetics of CO₂Hydrate just below Melting Point of Ice Kawamura, T.;Komai, T.;Yamamoto, Y.;Nagashima, K.;Ohga, K.;Higuchi, K. https://doi.org/10.1016/S0022-0248(01)01639-6
  53. Industrial & Engineering Chemistry Process Design and Development v.11 no.1 Dissociation Pressure of Gas Hydrates Formed by Gas Mixtures Parrish, W. R.;Prausnitz, J. M. https://doi.org/10.1021/i260041a006
  54. International Journal of Hydrogen Energy v.22 no.2 Solubility of CO₂and Density of CO₂Hydrate at 30 Mpa Aya, I.;Yamane, K.;Nariai, H. https://doi.org/10.1016/S0360-3199(96)00143-7
  55. AIChE Journal v.43 no.7 Clathrate Phase Equilibria for the Water-Phenol-Carbon Dioxide System Yoon, J.-H.;Lee, H. https://doi.org/10.1002/aic.690430723
  56. Environmental Science & Technology v.35 no.16 A New Hydrate-Based Recovery Process for Removing Chlorinated Hydrocarbons from Aqueous Solutions Seo, Y.;Lee, H. https://doi.org/10.1021/es010528j
  57. Environmental Science & Technology v.34 no.20 Recovery of CO2 from Flue Gas Using Gas Hydrates: Thermodynamic Verification through Phase Equlibrium Measurements Kang, S. P.;Lee, H. https://doi.org/10.1021/es001148l
  58. Ann. NY Acad. Sci. v.912 CO₂Hydrate Formation in Various Hydrodynamic Conditions Yamasaki, A.;Teng, H.;Wakatsuki, M.;Yanagisawa, Y.;Yamada, K.
  59. International Journal of Energy Research v.23 no.4 The Fate of CO₂Hydrate Released in the Ocean Teng, H.;Yamasaki, A.;Shindo, Y. https://doi.org/10.1002/(SICI)1099-114X(19990325)23:4<295::AID-ER478>3.0.CO;2-D
  60. Energy Conversion and Management v.36 no.6 Self-trapping Mechanisms of Carbon Dioxide in the Aquifer Disposal Koide, H.;Takahashi, M.;Tsukamoto, H. https://doi.org/10.1016/0196-8904(95)00054-H
  61. Energy v.22 no.2 Hydrate Formation in Sediments in the Sub-seabed Disposal of CO₂ Koide, H.;Takahashi, M.;Shindo, Y.;Tazaki, Y.;Iijima, M.;Ito, K.;Kimura, N.;Omata, K. https://doi.org/10.1016/S0360-5442(96)00122-3
  62. JOURNAL OF CHEMICAL ENGINEERING OF JAPAN v.30 no.3 Decomposition of CO₂, CH₄and CO₂-CH₄Mixed Gas Hydrates Ohgaki, K.;Nakano, S.;Matsubara, T.;Yamanaka, S. https://doi.org/10.1252/jcej.30.310
  63. Ann. NY Acad. Sci. v.912 Dynamics of Reformation and Replacement of CO₂and CH₄Gas Hydrates Komai, T.;Yamamoto, Y.;Ohga, K.
  64. Development of the Fundamental Key Technologies for Large Scale Ocean Sequestration of Carbon Dioxide Lee, H.;Kang, J. M.