Journal of the Korean Society of Food Science and Nutrition (한국식품영양과학회지)

The Korean Society of Food Science and Nutrition (한국식품영양과학회)
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Volatile Components of Chestnut (Castanea crenata Sieb. et Zucc.) Flower

밤꽃의 휘발성 화합물 특성

  • Published : 2003.08.01
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Abstract

Volatile flavor components in chestnut (Castanea crenate Sieb. et Zucc.) flower were collected by SDE method using the mixture of n-pentane and diethylether as an extract solvent and were identified by GC-FID and GC/MS. A total of 122 components including 35 alcohols,5 hydrocarbons,20 terpene and derivatives,7 ketones, 24 aldehydes, 12 esters, 4 acids, 3 furans, and 2 miscellaneous were identified from total volatile extract of chestnut. Alcohols were comprise 36.58% of volatile extract and dominant constituents and the main components of flower volatiles were 1-phenylethanol (18.6%), (E)-geraniol, tricosane, heneicosane, benzyl alcohol, acetophenone and 2-phenylethanol as aromatic alcohols and odd carbon hydrocarbons. Especially 1-phenylethanol and acetophenone would be applicable to the markers to ascertain floral origin of chestnut honey. The powerful animal and floral notes of chestnut flower were characterized by compounds including nonanal.

밤꿀의 밀원이 되는 밤꽃에서 SDE 추출법과 GC-FID 및 GC/MS 분석방법으로 122종의 휘 발성 성분을 분리ㆍ동정하였다. 밤꽃의 휘발성분 조성은 전체 향기성분 중 alcohol류가 36.58%로 가장 높은 함량을 보였으며, 그 다음으로 15종의 hydrocarbon류, 20종의 terpene류와 유도체, 7종의 ketone류,24종의 aldehyde류, 12종의 ester류, 4종의 acid류, 3종의 furan류와 2종의 기타 화합물 순으로 구성되어 있음이 확인되었다. 밤꽃 휘발성분의 주성분은 전 체 peak area의 18.6%을 구성하는 1-phenylethanol과 (E)-geraniol, tricosane, heneicosane, benzyl alcohol, acetophenone, 2-phenylethanol 등으로 방향족 alcohol과 홀수탄소로 구성 된 포화탄화수소들이었다. 밤꽃 추출물의 휘발성분에는 밤꿀의 밀원을 판단할 수 있게끔 하는 marker로써 사용가능성을 지닌 1-phenyl-ethanol과 acetophenone이 주성분으로 구성되어있으며, 밤꽃의 특징적인 강한 동물취와 꽃향이 혼합된 형태의 향 특성은 nonanal 등에 기인한다고 판단되었다.

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