Oxidative Stability and Antioxidant Content Changes in Roasted and Bleached Sesame Oil during Heating

Kim, In-Hwan;Choe, Eun-Ok

  • Published : 20041200

Abstract

Roasted sesame oil bleached with acid-activated clay at 1.0% (w/w) was heated at $180^{\circ}C$ for 40 hr and the degree of oil oxidation and the changes in tocopherol and lignan contents during heating were evaluated. Free fatty acid (FFA) value, conjugated dienoic acid (CDA) content, carbonyl value (CV), refractive index, and viscosity of the roasted and bleached sesame oil increased with longer heating time due to the oil oxidation. Bleaching of the roosted sesame oil slowed down the increase in FFA value, CDA content, CV, and refractive index of the oil during heating. The contents of tocopherols and lignan compounds in the roasted sesame oil decreased during heating. Degradation of tocopherols and lignan compounds during oil heating was slightly slower in the bleached oil than in the unbleached oil. The results strongly suggested that bleaching with acid clay improves the thermooxidative stability of roasted sesame oil, partly due to slower degradation of tocopherols and lignan compounds in the oil.

Keywords

References

  1. Recovery, refining, converting, and stabilizing edible fats and oils;Food Lipids Johnson, L.A.;Akoh, C.C.(ed.);Min, D.B.(ed.)
  2. Food Sci. Biotechnol. v.10 Effect of sesame oil on thermooxidative stability of soybean oil Chung, J.S.;Choe, E.O.
  3. Journal of Food Science v.52 no.3 Effects of fatty acids on the oxidative stability of soybean oil Mistry, B.S.;Min, D.B. https://doi.org/10.1111/j.1365-2621.1987.tb06741.x
  4. Lebensmittel-Wissenschaft und-Technologie v.36 no.1 Reduction of mutagenicity of the fumes from cooking oil by degumming treatment Yen, G.C.;Wu, S.C. https://doi.org/10.1016/S0023-6438(02)00212-8
  5. Nahrung/Food v.46 no.6 Antioxidative effects of alpha-tocopherol and ascorbyl palmitate on thermal oxidation of canola oil Onal, B.;Ergin, G. https://doi.org/10.1002/1521-3803(20021101)46:6<420::AID-FOOD420>3.0.CO;2-G
  6. Food Chemistry v.55 no.1 Chemical and physical characteristics of palm, palm kernel and groundnut oils as affected by degumming Iwuoha, C.I.;Ubbaonu, C.N.;Ugwo, R.C.;Okereke, N.U. https://doi.org/10.1016/0308-8146(95)00067-4
  7. Science of Sesame Seeds Ahn, B.O.;Lee, J.I.
  8. Journal of Food Lipids v.5 no.3 Comparison of the frying performance of refined, bleached and deodorized palm olein and coconut oil Che-Man, Y.B.;Wan-Hussin, W.R. https://doi.org/10.1111/j.1745-4522.1998.tb00120.x
  9. Agric. Biol. Chem. v.50 Chemical aspects of the antioxidative activity of roasted sesame seed oil, and the effect of using the oil for frying Fukuda, Y.;Nagata, M.;Osawa, T.;Namiki, M. https://doi.org/10.1271/bbb1961.50.857
  10. Journal of the Science of Food and Agriculture v.75 no.1 Effects of seed roasting temperature and time on the quality characteristics of sesame (Sesamum indicum) oil Yoshida, H.;Takagi, S. https://doi.org/10.1002/(SICI)1097-0010(199709)75:1<19::AID-JSFA830>3.0.CO;2-C
  11. Food Chemistry v.62 no.3 The use of sesame oil unsaponifiable matter as a natural antioxidant Mohamed, H.M.A.;Awatif, I.I. https://doi.org/10.1016/S0308-8146(97)00193-3
  12. J. Food Sci. v.69 Oxidative stability of soybean and sesame oil mixture during frying of flour dough Chung, J.;Lee, J.;Choe, E. https://doi.org/10.1111/j.1365-2621.2004.tb13652.x
  13. J. Food Sci. v.69 Effects of bleaching on the properties of roasted sesame oil Kim, I.;Choe, E.
  14. J. Jpn. Soc. Food Sci. Technol. v.50 Ultra-weak photon emission from roasted sesame oil at different roasting temperatures and different qualities Hagiwara, S.;Hageshita, S.;Seki, K.;Saito, T;Shiga, T.;Ohtani, T. https://doi.org/10.3136/nskkk.50.303
  15. Journal of the American Oil Chemists��� Society v.63 no.8 Contribution of lignan analogues to antioxidative activity of refined unroasted sesame seed oil Fukuda, Y.;Nagata, M.;Osawea, T.;Namiki, M. https://doi.org/10.1007/BF02673792
  16. Official Methods and Recommended Practices of the AOCS, Cd 3a-63, Ti 1a-64 AOCS
  17. Journal of the American Oil Chemists��� Society v.31 no.3 Estimating carbonyl compounds in rancid fats and foods Henick, A.S.;Benca, M.F.;Mitchell, J.H. Jr. https://doi.org/10.1007/BF02612488
  18. Korean J. Food Sci. Technol. v.32 Studies on the antioxidative compounds of sesame oils with roasting temperature Kim, H.W.
  19. Korean J. Food Sci. Technol. v.29 Effects of oil refining processes on oxidative stability and antioxidative substances of sesame oil Han, J.S.;Moon, S.Y.;Ahn, S.Y.
  20. Introduction to the analysis of variance;An Introduction to Statistical Methods and Data Analysis Ott, L.
  21. J. Korean Soc. Food Nutr. v.23 Relationship between physical and chemical properties of frying vegetable oils Lee, K.T.;Park, S.M.;Hwang, Y.G.;Kang, O.J.
  22. Chemistry of frying oils;Food Lipids Warner, K.;Akoh, C.C.(ed.);Min, D.B.(ed.)
  23. Journal of the American Oil Chemists Society v.77 Odor significance of undesirable degradation compounds in heated triolein and trilinolein Neff, W.E.;Warner, K.;Byrdwell, W.C. https://doi.org/10.1007/s11746-000-0205-3
  24. Journal of Agricultural and Food Chemistry v.49 no.2 Effect of oleic acid and linoleic acids in the production of deep fried odor in heated triolein and trilinolein Warner, K.;Neff, W.E.;Byrdwell, W.C.;Gardner, H.W. https://doi.org/10.1021/jf000822f
  25. Korean J. Food Sci. Technol. v.30 Thermooxidative stability of soybean oil, beef tallow, and palm oil during frying of steamed noodles Choe, E.;Lee, J.
  26. Food Sci. Biotechnol. v.12 Effects of ginseng extract added to dough on the lipid oxidation of frying oil and fried dough during frying and storage Kim, I.;Choe, E.
  27. Korean J. Food Sci. Technol. v.14 Studies on thermal oxidation of soybean oil Shin, A.J.;Kim, D.H.
  28. Korean J. Food Sci. Technol. v.30 Effect of surface area of soybean oil and lard on the thermooxidative stability Kim, I.H.;Kim, Y.S.;Choi, Y.M.
  29. European Journal of Lipid Science and Technology v.102 no.8 Testing and comparing oxidative stability of vegetable oils and fats at frying temperature Gertz, C.;Klostermann, S.;Kochhar, S.P. https://doi.org/10.1002/1438-9312(200009)102:8/9<543::AID-EJLT543>3.0.CO;2-V
  30. Nutritional and physiological effects of used frying fats;Deep Frying Chemistry, Nutrition and Practical Applications Marquez-Ruiz, G.;Dobarganes, M.C.;Perkins, E.G.(ed.);Erickson, M.D.(ed.)
  31. Korean J. Food Sci. Technol. v.31 Physicochemical properties of methyl linoleate oxidized at various temperatures Kim, I.H.;Kim, C.J.;Kim, D.H.
  32. European Food Research and Technology v.218 no.1 Changes in colour and rheological behaviour of sunflower seed oil during frying and after adsorbent treatment of used oil Maskan, M. https://doi.org/10.1007/s00217-003-0807-z
  33. Journal of the American Oil Chemists Society v.75 no.12 Effect of ${\alpha}$- and ${\gamma}$-tocopherols on thermal polymerization of purified high-oleic sunflower triacylglycerols Lampi, A.M.;Kamal-Eldin, A. https://doi.org/10.1007/s11746-998-0319-x
  34. Journal of the Science of Food and Agriculture v.79 no.13 Loss of tocopherols and formation of degradation compounds in triacylglycerol model systems heated at high temperature Barrera-Arellano, D.;Ruiz-Mendez, V.;Ruiz, G.M.;Dobarganes, C. https://doi.org/10.1002/(SICI)1097-0010(199910)79:13<1923::AID-JSFA457>3.0.CO;2-8
  35. European Journal of Lipid Science and Technology v.102 no.10 Effects of tocopherols and their mixtures on the oxidative stability of olive oil and linseed oil under heating Wagner, K.H.;Elmadfa, I. https://doi.org/10.1002/1438-9312(200010)102:10<624::AID-EJLT624>3.0.CO;2-I
  36. Progress in Lipid Research v.39 no.3 Vitamin E: non-antioxidant roles Azzi, A.;Stocker, A. https://doi.org/10.1016/S0163-7827(00)00006-0
  37. Antioxidant mechanisms;Food Lipids Decker, E.A.;Akoh, C.C.(ed.);Min, D.B.(ed.)
  38. European Journal of Lipid Science and Technology v.105 no.9 On-line LC-NMR-MS characterization of sesame oil extracts and assessment of their antioxidant activity Dachtler, M.;Van de Put, F.H.M.;Stijn, F.V.;Beindorff, C.M.;Fritsche, J. https://doi.org/10.1002/ejlt.200300835