Korean Journal of Environmental Agriculture (한국환경농학회지)

The Korean Society of Environmental Agriculture (한국환경농학회)
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Methane Fermentation of the Paper Mill Sludge under Anaerobic Condition

제지슬러지의 혐기메탄발효

  • Published : 2004.03.31
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Abstract

The activated paper mill sludge was treated with WF and some additives (sodium sulfide, nickel nitrate, ethyl acetate) for methane fermentation at $35^{\circ}C$. Optmum C/N ratio was 60 out of three conditions (20, 30 and 60). The Period of 40% of methane content possibly ignition, was 2 days shorter than with non-treatment during 10 days. Nevertheless, the total amount of methane production showed the 1/8 level of control far the same period. The yield and content of methane were increased by the addition of sodium Sulfur and ethyl acetate. Sulfur was an essential factor in methane fermentation of paper mill sludge.

제지공장의 슬러지를 활성오니슬러지와 집수조슬러지로 나누어 C/N율, 메탄발효폐액 첨가 그리고 몇몇 첨가제를 처리하고 발생한 혐기발효가스 중 메탄함량을 측정하여 각각의 처리효과를 조사해 보았다. 1. 활성오니 제지슬러지를 이용한 메탄발효의 최적 C/N율은 60으로 이전의 다른 재료들과는 다른 경향이었다. 2. 혐기발효 폐액의 첨가로 메탄함량 40% 도달 시간은 약 2일정도 앞당겼지만, 10일간의 총 메탄발생량은 1/8 수준으로 적었다. 3. 첨가제중 sodium sulfide와 ethylacetate의 처리효과는 발효폐액 첨가구에서 뚜렷하였고, 무첨가구에서도 sodium sulfide는 1.3배의 메탄생성 증가에 기여하였다. 4. 황화수소가 제거된 제지슬러지에서는 메탄이 전혀 생성되지 않았고, sodium sulfide가 첨가된 처리구에서는 메탄생성이 증가되었기에 제지슬러지 메탄발효에서 황은 필수적이라고 할 수 있다.

Keywords

References

  1. Palz, W., Olartier, P. and Hall, D. O. (1980) Energy from biomass, Applied Science, London, p.330-342
  2. Stafford, D. A., Hugdes, D. E. and Wentworth,. R. L. (1981) Anaerobic digestion, Elservier, Oxford, p.22-70
  3. 임재현, 박영대, 주영희 (1986) 농산부산물의 혐기분해에 의한 메탄가스 발생에 관한 연구, 농촌진흥청 농시논문집 28(1), 147-151
  4. Lim, D. K, Park, W. K, Kwon, S. I., Nam, J. J. and Lee, S. B. (2002) Application amount of anaerobic digestion waste water from rrethane fermentation of pig manure on rice, Kor. J. Environ. Agric. 21(4), 248-254 https://doi.org/10.5338/KJEA.2002.21.4.248
  5. Lim, D. K, Park, W. K, Kwon, S. L, Nam, J. J., Park, B. K. and Kim, S. H. (2002) Application level of anaerobic digestion waste water from methane fermentation pig manure on rice, Kor. J. Environ. Agric. 21(4), 255-260 https://doi.org/10.5338/KJEA.2002.21.4.255
  6. Yang, H. M. (1999) Methane fermentation of pit in pond system for ecological treatment and recycling of animal excreta, Kor. J. Environ. Agric. 18(2), 191-195
  7. Yang, H. M (2000) Methane fermentation of facultative pond in pond System for ecological treatment and recycling of livestock waste water, Kor. J. Environ. Agric. 19(2), 171-176
  8. Kim, G. Y, Park, S. L, Song, B. H and Shin, Y K (2002) Emission characteristics of methane and nitrous oxide by management of water and nutrient in a rice paddy soil, Kor. J. Environ. Agric. 21(2), 136-143 https://doi.org/10.5338/KJEA.2002.21.2.136
  9. 김문규 (1989) 산업폐기물 활용에 관한 연구, 과학기술처
  10. 한국제지공업협회(2002) 종이판지통계연보
  11. Lee, K. S., Choi, J. W, Song, J. Y and Kim. M K (1991) Changes of properties in the soil treated with paper mill sludge, Jour. Agri. Sci. Chungnam Nat'l Univ., Korea 18(1), 74-79
  12. Jung, K Y, Joa, Y H and KiIn, J. J. (1989) Studies on behavior cellulolytic and methanogenic bacteria participated in anaerobic decomposition of rice straw and its decomposition products, Kor. J. Soil. Sci. Fert. 22(4), 323-328
  13. Choi, J. W, Jo, J. R, Lee, K S. and KiIn, M K (1992) Effects of paper mill sludge in submerged soil, Jour. Agri. Sci. Chungnam Nat'l Univ., Korea. 19(2), 187-193
  14. Heo, J. S., KiIn, K S. and Ha, H S. (1988) Effects of paper sludge application on the chemical properties of paddy soil and growth of paddy rice, Kor. J. Environ Agric. 7, 26-33
  15. 환경부 (1997) 환경백서, p.79-80
  16. Aspitarte, T. R (1973) Pulp and paper mill sludge disposal and crop production, Tappi., 56(10), 140-144
  17. 농촌진흥청 (2002) 비료공정규격
  18. Hawkes, D., Hortonand, R and Staford, D. S. (1978) The use of anaerobic digestion for the treatment and recycling of organic wastes, Conversion & Recycling 2(2), 181-195 https://doi.org/10.1016/0361-3658(78)90056-5
  19. Khan, A W and Duncan, W (1981) Fermentative conversion of cellulose to acetic acid and cellulolytic enzyme production, Appl. Environ. Mcrobiol. 41(5), 1214-1218
  20. Fujimura, E. (1980) Energy recovery by methane fermentation of pulp mill waste water and sludge, Pulp & Paper Tech. Times, 240(10), 1-11
  21. Jeong, K Y, Shin, J. 5., Park, Y S. and Han, K H (1981) Use of industrial wastes as sources of organic fertilizer, Kor. J. Soil. Sci. Fert. 14, 83-87
  22. 김학성, 강호 (1992) 유기성폐기물의 자원화 기술, 한국과학기술원, I60-II41
  23. Khan, A W and Trottier, T. M (1978) Effect of sulfur-containing compounds on anaerobic degradation of cellulose to methane by mixed cultures obtained from sewage sludge, Appl. Environ. Mcrobiol. 35(6), 1027-1034
  24. Lee, K. S., Gtoi, J. W, Jo, J. R and KiIn, M K (1992) On the hazardous components of paper mill sludge and treated soil, Jour. Agri. Sci. Chungnam Nat'l Univ., Korea 18(2), 194-200
  25. 농촌진흥청 (1980) 토양화학분석법
  26. 환경부 (2000) 폐기물공정시험방법
  27. 上木勝可 (1995) 우사폐수 혐기첨가처리에 의한 산성광산 배수의 정화, 환경산업, 12(61), 38-40