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Study of Ni-germano Silicide Thermal Stability for Nano-scale CMOS Technology

Nano-scale CMOS를 위한 Ni-germano Silicide의 열 안정성 연구

  • Published : 2004.11.01

Abstract

In this paper, novel methods for improvement of thermal stability of Ni-germano Silicide were proposed for nano CMOS applications. It was shown that there happened agglomeration and abnormal oxidation in case of Ni-germano Silicide using Ni only structure. Therefore, 4 kinds of tri-layer structure, such as, Ti/Ni/TiN, Ni/Ti/TiN, Co/Ni/TiN and Ni/Co/TiN were proposed utilizing Co and Ti interlayer to improve thermal stability of Ni-germano Silicide. Ti/Ni/TiN structure showed the best improvement of thermal stability and suppression of abnormal oxidation although all kinds of structures showed improvement of sheet resistance. That is, Ti/Ni/TiN structure showed only 11 ohm/sq. in spite of 600 $^{\circ}C$, 30 min post silicidation annealing while Ni-only structure show 42 ohm/sq. Therefore, Ti/Ni/TiN structure is highly promising for nano-scale CMOS technology.

Keywords

References

  1. R. People, 'Physics and applications of $Ge_xSi_{1-x}$/Si strained-layer heterostructures', IEEE J. Quantum Electron 22, p. 1696, 1986 https://doi.org/10.1109/JQE.1986.1073152
  2. lyer, S. S. Solomon, P. M. Kesan, V. P. Bright, A. A. Freeouf, J. L. Nguyen, T. N. Warren, and A. C. 'A gate-quality di- electric system for SiGe metal-oxide-semi- conductor devices', IEEE Electron Device Lett. 12, p. 246, 1991 https://doi.org/10.1109/55.79571
  3. D. K. Nayak, J. C. S. Woo, J. S. Park, K. Wang, and K. P. MacWilliams, 'Enhancement-mode quantum- well $Ge_xSi_{1-x}$PMOS', IEEE Electron Device Lett. 12, p. 154, 1991 https://doi.org/10.1109/55.75748
  4. U. Konig, J. Boers, F. Schaffler, and E. Kasper, 'Enhancement mode n-channel Si/SiGe MODFET with high intrinsic transconductance', Electron. Lett. 28, p. 160, 1992 https://doi.org/10.1049/el:19920100
  5. D. Nayak, J. Woo, J. Park, K. Wang, and K. MacWilliams, 'High-mobility p-channel metal-oxide-semiconductor field-effect transistor on strained Si', Appl. Phys. Lett. 62, p. 2853, 1993 https://doi.org/10.1063/1.109205
  6. J. Welser, J. L. Hoyt, and J. F. Gibbons, 'Temperature and scaling behavior of strined-Si N-MOSFET'S', IEEE Trans. Electron Devices 40, p. 2101, 1993
  7. O. Thomas, F. M. d'Heurle, and S. Delage, 'Some titanium germanium and silicon compounds: Reaction and properties', J. Mater. Res. 5, p. 1453, 1990 https://doi.org/10.1557/JMR.1990.1453
  8. W. J. Qi, B. Z. Li, W. N. Huang, Z. G. GU, H. Q. Lu, X. J. Zhang, M. Zhang, G. S. Dong, D. C. Miller, and R. G. Aitken, 'Solid state reaction of Co,Ti with epitaxiallygrown $Si_{1-x}Ge_x$ film on Si(100) substrate', J. Appl. Phys. 77, p. 1086, 1995 https://doi.org/10.1063/1.358969
  9. R. A. Donaton, K. Maex, A. Vantomme, G. Langouche, Y. Morciaux, A. St. Amour, and J. C. Sturm, 'Co silicide formation on SiGeC/Si and SiGe/Si layers', Appl. Phys. Lett. 70, p. 1266, 1997 https://doi.org/10.1063/1.118548
  10. T. Jarmar, J. Seger, F. Ericson, D. Mangelinck, U. Smith, and S. L. Zhang, 'Morphological and phase stability of nickel-germanosilicide on $Si_{1-x}Ge_x$ under thermal stress', J. Appl. Phys. 92, p. 7193, 2002 https://doi.org/10.1063/1.1522491
  11. A. Lauwers, A. Steegen, M. de Potter, R. Lindsay, A. Satta, H. Bender, and K. Maex, 'Materials aspects, electrical performance, and scalability of Ni silicide towards sub-0.13 ${\mu}m$ technologies', J. Vac. Sci. Technol. B19(6), p. 2026, 2001
  12. D. X. Xu, S. R. Das, C. J. Peters, and L. E. Erickson, 'Material aspects of nickel silicide for ULSI applications', Thin Solid Films, 326, p. 143, 1998 https://doi.org/10.1016/S0040-6090(98)00547-1
  13. 지희한, 안순의, 배미숙, 이헌진, 오순영, 이희덕, 왕진석, 'CMOS 소자를 위한 NiSi의 Surface Damage 의존성', 한국전기전자재료학회 논문지, 16권, 4호, p. 280, 2003
  14. D. K. Sohn, J. S. Park, B. H. Lee, J. U. Bae, K. S. Oh, S. K. Lee, J. S. Byun, and J. J. Kim, 'High Thermal Stability and Low Junction Leakage Current of Ti Capped Co Salicide and its Feasibility for High Theral Budget CMOS devices', IEEE IDEM, 326, p. 1005, 1998
  15. W. L. Tan, K. L. Pey, Simon Y. M. Chooi, J. H. Ye, and T. Osipowicz, 'Effect of a titanium cap in inducing interfacial oxides in the formation of nickel silicide', J. Appl. Phys. 91, p. 2901, 2002 https://doi.org/10.1063/1.1448672
  16. 오순영, 윤장근, 박영호, 황빈봉, 지희환, 왕진석, 이희덕, 'Cobalt Interlayer와 Tin capping를 갖는 새로운 구조의 Ni-silicide 및 Nano CMOS에의 응용', 대한전자공학회논문지 40권, p. 897, 2003
  17. J. G. Yun, S. Y. Oh, H. H. Ji, B. F. Huang, Y. H. Park, J. S. Wang, and H. D. Lee, 'Novel NiSi Technology Utilizing Ti/Ni/TiN Structure and Fluorine Implantation for Thermal Stability Improvement by Suppression of Abnormal Oxidation', IWJT, p. 131, 2004