Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Monitoring of Bisphenol A and Nonylphenol in Waterworks System of Seoul, Korea

상수도 계통에서 비스페놀 A와 노닐페놀의 실태조사

  • Ham, Young-Kook (Department of Water Quality Research, Waterworks Research Institute of Seoul Metropolitan Government) ;
  • Oh, Sea-Jong (Department of Water Quality Research, Waterworks Research Institute of Seoul Metropolitan Government) ;
  • Kim, Sung-Whan (Division of Life Science, Kangwon National University)
  • 함영국 (서울특별시 상수도연구소 수질연구부) ;
  • 오세종 (서울특별시 상수도연구소 수질연구부) ;
  • 김성완 (강원대학교 생명과학부)
  • Received : 2004.07.08
  • Accepted : 2004.07.30
  • Published : 2004.10.25
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Abstract

This study was examined occurrence of bisphenol A (BPA) and nonylphenol (NP) in waterworks system of Seoul, Korea from September 2002 to December 2003. The levels of BPA and NP in Han-river and its tributaries were as followed: Paldang-dam, ND(not detected)${\sim}0.033{\mu}g/L$ and $ND{\sim}0.823{\mu}g/L$; Kyungahn-creek, $ND{\sim}0.659{\mu}g/L$ and $ND{\sim}3.827{\mu}g/L$; Whangsuk-creek, $ND{\sim}0.528{\mu}g/L$ and $ND{\sim}12.724{\mu}g/L$, respectively. In water of 6 intake-station, the contents of NP and BPA were detected $0.122{\sim}2.724{\mu}g/L$, and $ND{\sim}0.260{\mu}g/L$, respectively. In the finished- and tap-water of three drinking water treatment plants (DWTPs) around Whangsuk-creek, BPA was not detected in all samples, while NP was in ppt levels in whole. Through the process of DWTP, also, the removal ratio of NP was above 80% in all this. Therefore, this result was suggested that levels of BPA and NP in waterworks system depended on non-point contaminants and swage treatment plants in the Han-river shed.

본 연구는 서울시 상수도 계통에서 내분비계장애물질인 BPA 및 NP의 실태조사를 위해 2002년 9월부터 2003년 12월까지 수행되었다. 상수원 유역의 한강 및 지류천중의 BPA 및 NP의 수준은 다음과 같았다: 팔당댐, $ND{\sim}0.033{\mu}g/L$ 및 $ND{\sim}0.823{\mu}g/L$ ; 경안천, $ND{\sim}0.659{\mu}g/L$ 및 N$D{\sim}3.827{\mu}g/L$ ; 왕숙천, $ND{\sim}0.528{\mu}g/L$ 및 $ND{\sim}12.724{\mu}g/L$. 서울시 6개 취수장 원수중의 BPA 수준은 $ND{\sim}0.260{\mu}g/L$, NP의 농도는 $0.122{\sim}2.724{\mu}g/L$의 범위에 있었다. 그리고 왕숙천 수역을 중심으로 한 3개 정수장의 여과수와 그 수돗물에서 BPA는 모두 불검출된 반면에, NP는 전지점에서 ppt 수준으로 검출되었다. 또한, 먹는물의 정수처리공정에서 NP의 제거율은 정수장별 차이가 없이 80{\sim}95%로 높게 나타났다. 따라서 본 연구결과는 상수도 계통에서 BPA 및 NP의 농도는 한강유역에 존재하는 점오염원 및 하수처리장 방류량에 의존된다는 것을 시사하고 있다.

Keywords

References

  1. C. A. Staples, P. B. Dorn, G. M. Klecka, S. T. O_Block, L. R. Harris, J. Chemosphere, 36(10), 2149-2173(1998).
  2. M. K. Holger, B. Karlheinz, Environ. Sci. Technol., 35, 3201-3206(2001).
  3. S. Jobling, T. Reynolds, R. White, M. G. Parker, J. P. Sumpter, Environ. Health Perspect., 103(6), 582-587(1995).
  4. T. Colborn, F. S. vom Saal, A. M. Soto, Environ. Health. Perspect., 101, 378-384(1993).
  5. L. Ren, S. K. Lewis, J. J. Lech, Chem. Biol. Interact. 100(1), 67-76(1996).
  6. T. Colborn, C. Clement, 'Chemically-induced alterations in sexual and functional development', Ed., Preiceton, NJ : Princeton Scientific Publishin. 1992.
  7. K. Kinnberg, B. Korsgaard, P. Bjerregaard, A. Jespersen, J. Exp. Biol., 203(Pt 2), 171-181(2000).
  8. T. Tanaka, H. Kohno, M. Tanino, Y. Yanaida, Ecotoxicol. Environ. Saf., 52(1), 38-45(2002).
  9. R. White, S. Jobling, S. A. Hoare, J. P. Sumpter, M. G. Parker, Endocrinology, 135(1), 175-182(1994).
  10. M. Hesselsoe, D. Jensen, K. Skals, T. Olesen, P. Moldrup, P. Roslev, G. K. Mortensen, K. Henriksen, Environ. Sci. Technol., 35(18), 3695-3700(2001).
  11. C. Lambert, M. Larroque, J. Chromatogr Sci. 35(2), 57-62(1997).
  12. R. L. Gomes and J. N. Jester, 'Endocrine Disrupters in Wastewater and Sludge Treatment Processes: 7. Endocrine Disruptersin Drinking Water and Water Reuse', Ed., 219-266, J. W. Birkett and J. N. Lester, Lewis Publishers. New York. U.S.A., 2003.
  13. J. A. Brotons, M. F. Olea-Serano, M. Villalobos, V. Pedraza, and N. Olea, Environ. Health Persp., 103(6), 608-612(1995).
  14. J. K. Fawell and J. K. Chipman, J. Chart Inst. Water Environ. Mange., 15, 92(2001).
  15. Environmetal Data Services, 'Public exposed to oestrogen risks from food cans', 246, 3. ENDS Rep., 1995.
  16. G. A. Junk, H. J. Svce, R. D. Vick and M. J. Avery, Environ. Sci. Technol., 8(13), 1100-1106(1974).
  17. Watershed Management Bureau(Han-river Basin Environmental Office), 'A study of trace toxic pollutants in Kyungahn Creek', 151~163. Seoul, Korea, 2000.
  18. P. G. Kim, E. A. Kwon, and S. H. Hwang, Kor. J. Evn. Hlth. Soc., 26(1), 107-113(2000).
  19. Waters Co, 'Oasis sample extraction products: Environ-mental and agrochemical applications notebooks' Rev 2, U.S.A., 2001.
  20. P. L. Ferguson, C. R. Iden and B. J. Brownawell, Anal. Chem., 72(18), 4322-4330(2000).
  21. D. Y. Shang, M. G. Ikonomou, J. Chromatogr. A., 849(2), 467-482(1999).
  22. M. Petrovic, A. Diaz, F. Ventura and D. Barcelo, Anal. Chem., 73(24), 5886-5895(2001).
  23. M. Petrovic, A. Diaz, F. Ventura, and D. Barcelo, Environ. Sci. Technol., 37(19), 4442-4448(2003).
  24. US EPA, 'Removal of endocrine disrupting compounds using drinking water treatment processes'. 20. EPA/625/R-00/015, Washington, DC, U.S.A., 2001.
  25. T. Tanizaki, K. Kadokami and R. Shinohara, Contam. Toxicol, 68(5), 732-739(2002).
  26. Y. Ohko, I. Ando, C. Niwa, T. Tatsuma, T. Yamamura, T. Nakashima, Y. Kubota, A. Fujishima, Environ Sci Technol., 35(11), 2365-2368(2001).
  27. Y. I. Yoon, P. Westerhoffa, S. A. Snyderb and M. Esparzaa, Water Res., 37 (14), 3530-3537(2003).
  28. Proposal from the Commission Com. 17 final. 2000/0035(COD), Brussels, 16. 01. 2001.