Preparation and Characterization of Acrylic Acid Grafted Polypropylene Nonwoven Fabric

아크릴산 그라프트 폴리프로필렌 부직포의 제조와 특성

  • Kim, Sang-Yool (Dept. of Clothing & Textiles, Mokpo National University) ;
  • Na, Choon-Ki (Dept. of Environmental Eng., Mokpo National University)
  • 김상률 (목포대학교 의류학전공) ;
  • 나춘기 (목포대학교 환경공학전공)
  • Received : 2003.10.29
  • Published : 2004.06.30

Abstract

The purpose of this study is in development of effective filter-type polymer adsorbent for removal of pollutants from wastewater by UV irradiation graft polymerization. Photografting of acrylic acid (AA) on polypropylene (PP) nonwoven fabric using benzophenone (BP) as a photosensitizer was investigated. Inhibition of homopolymerization was achieved by adding various concentrations of $FeSO_4{\cdot}7H_2O$, $CuSO_4{\cdot}5H_2O$ and Mohr's salt. As AA concentration was increased, the degree of grafting was increased as to a specific value and then decreased, and the effect of BP concentration showed the same tendency. It was also found that the degree of grafting increased with reaction time and reaction temperature. Addition of the polyfunctional monomers and $H_2SO_4$ to the grafting system accelerated the photografting. The melting temperature, molecular weight and breaking stress and breaking strain were decreased with the increase in the degree of grafting.

Keywords

References

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