Reliability Analysis and Feilure Mechanisms of Coolant Rubber Hose Materials for Automotive Radiator

자동차 냉각기 고무호스용 재질에 대한 신뢰성 평가 및 고장메커니즘규명

  • Kwak Seung-Bum (Department of Mechanical Design and Production Engineering, Hanyang University) ;
  • Choi Nak-Sam (Department of Mechanical Engineering, Hanyang University) ;
  • Kang Bong-Sung (Reliability Assessment Center, Korea Research Institute of Chemical Technology) ;
  • Shin Sei-Moon (Reliability Assessment Center, Korea Research Institute of Chemical Technology)
  • 곽승범 (한양대학교 기계설계학과) ;
  • 최낙삼 (한양대학교 기계정보경영공학부) ;
  • 강봉성 (한국화학연구원 신뢰성평가센터) ;
  • 신세문 (한국화학연구원 신뢰성평가센터)
  • Published : 2005.09.01

Abstract

Coolant rubber hoses for automobile radiators can be degraded and thus failed due to the influence of contacting stresses of air and coolant liquid under the thermal and mechanical loadings. In this study, test analysis was carried out for evaluating the degradation and failure mechanisms of coolant hose materials. Two kinds of EPDM rubber materials applicable to the hoses were adopted: commonly-used ethylene-propylene diene monomer(EPDM) rubbers and EPDM rubbers with high resistance against electro-chemical degradation (ECD). An increase of surface hardness and a large reduction of failure strain were shown due to the formation of oxidation layer for the specimens which had been kept in a high temperature air chamber. Coolant ageing effects took place only by an amount of pure thermal degradation. The specimens degraded by ECD test showed a swelling behavior and a considerable increase in weight on account of the penetration of coolant liquid into the skin and interior of the rubber specimens. The ECD induced material softening as well as drastic reduction in strength and failure strain. However EPDM rubbers designed for high resistance against ECD revealed a large improvement in reduction of failure strain and weight. This study finally established a procedure for reliability analysis and evaluation of the degradation and failure mechanisms of EPDM rubbers used in coolant hoses for automobile radiators.

Keywords

References

  1. K. J. Lee, H. J. Bae, S. T. No and W. T. Kim, 'Studies on the Mechanical Properties of Silane Crosslinked EPDM,' Polymer, Vol.11, No.6, pp.547-556, 1987
  2. Y.-S. Gal, 'EPDM Rubber and Its Applications,' Polymer Science and Technology, Vol.109, No.3, pp.325-333, 1999
  3. J. K. Kim and H. K. Lee, 'Study on Manufacturing and Characteristics of Silicone/EPDM Rubber Blend,' Polymer, Vol.25, No.3, pp.406-413, 2001
  4. 자동차용 냉각기호스 해설서 RS M0004, 산업자원부 기술표준원, 2001
  5. 자동차용 냉각기호스 신뢰성평가기준 RS M0004, 산업자원부 기술표준원, 2001
  6. Test Methods for Evaluating the Electrochemical Resistance of Coolant System Hoses' and Materials, SAE J1684
  7. W. D. Kim, W. S. Kim, C. S. Woo and S. J. Cho, 'Prediction of Useful Life by Heat Aging of Motor Fan Isolating Rubber,' Elastomer, Vol.37, No.2, pp.107-114, 2002
  8. T. L. Anderson, Fracture Mechanics, Fundamentals and Applications, 2nd edition, CRC press, Tokyo, 1995
  9. Rubber and Plastics Hoses and Hose Assemblies - Hydrostatic Testing, International Standard ISO 1402: 1994(E)
  10. Rubber, Vulcanized - Determination of the Effect of Liquids, International Standard ISO 1817: 1999(E)
  11. Rubber - Coolant Hoses and Tubing for Use on Private Cars and Light Commercial Vehicles Specification, International Standard ISO 4081: 1987(E)
  12. Rubber, Vulcanized or Thermoplastic - Accelerated Ageing and Heat Resistance Tests, International Standard ISO 188: 1998(E)
  13. T. Zaharescu, V. Meltzer and R. Vilcu, 'Thermal Properties of EPD/MNR blends,' Polymer Degradation and Stability, Vol.70, pp.341-345, 2000 https://doi.org/10.1016/S0141-3910(00)00115-4
  14. R. A. Assink, K. T. Gillen and B. Sanderson, 'Monitoring the Degradation of a Thermally Aged EPDM Terpolymer by 1H NMR Relaxation Measurements of Solvent 'Swelled Samples,' Polymer, Vol.43, pp.1349-1355, 2002 https://doi.org/10.1016/S0032-3861(01)00661-9
  15. R. S. Rajeev, S. K. De, A. K. Bhowmick, B. John, 'Studies on Thermal Degradation of Short Melamine Fibre Reinforced EPDM, Maleated EPDM and Nitrile Rubber Composites,' Polymer Degradation and Stability, Vol. 79, pp.449-463, 2003 https://doi.org/10.1016/S0141-3910(02)00361-0
  16. R. N. Darie, M. Brebu, C. Vasile and M. Kozlowski, 'On the Compatibility of the IPP/PA6/EPDM Blends with and without Functionalized IPP I. Thermo-oxidative Behaviour,' Polymer Degradation and Stability, Vol.80, pp.551-566, 2003 https://doi.org/10.1016/S0141-3910(03)00052-1
  17. Rubber, Vulcanized or Thermoplastic - Resistance to Ozone Cracking, Part l : Static Strain Test, International Standard ISO 1431-1: 1989(E)