A Study on the Acid Degradation Properties of Cellulose Fabrics for Costume Heritage Restoration

유물 복원을 위한 천연 셀룰로오스 직물의 산에 의한 열화 특성 연구

  • Jeon Cho-Hyun (Dept. of Textile Engineering, Pusan National University) ;
  • Kwon Young-Suk (Dept. of Clothing & Textiles, Pusan National University) ;
  • Lee Sang-Joon (Dept. of Microbiology, Pusan National University) ;
  • Cho Hyun-Hok (Dept. of Textile Engineering, Pusan National University)
  • 전초현 (부산대학교 섬유신소재공학과) ;
  • 권영숙 (부산대학교 의류학과) ;
  • 이상준 (부산대학교 미생물학과) ;
  • 조현혹 (부산대학교 섬유신소재공학과)
  • Published : 2005.08.01

Abstract

Researches to preserve and restore the excavated cellulose fabrics as costume heritages have been carried out. In this study, in order to artificially restore an excavated cellulose fabrics, acid-treated cellulose fabrics were prepared. Three kinds of cellulose fabrics were used for an experiment. Three kinds of cellulose fabrics were treated by the acid aqueous solution for the various strength retention ($100\%,\;80\%,\;60\%,\;40\%,\;20\%$). The fine structure and physical properties of acid treated cellulose fabrics were investigated with various techniques such as wide-angle X-ray diffraction, tensile test, weight loss, shrinkage, SEM etc. Tensile strength and strain of cellulose fabrics decreased with increasing acid treatment time. However, weight loss and shrinkage increasing slightly. The crystal diffraction intensity was not changed. SEM results of acid-treated cellulose fabrics show that the surface was damaged.

Keywords

References

  1. 최광남, '문화재의 과학적 보존', 대원사, 서울, pp.110-118(1994)
  2. M. N. Micheal, F. M. Tera and E. M. Othman, Degradation Measurements of Linen Fabrics, Polymer-Plastics Technology and Engineering, 43(5), 1377-1386(2004) https://doi.org/10.1081/PPT-200030185
  3. 조환, 조용석, '최신섬유화학', 형설출판사, pp.65-70(1986)
  4. M. S. Lee, M. J. Park, S. H. Bae, and Y. H. Lee, Analysis of Buried-Fabrics from the Tomb-Kim Hum Jo by Physical, Chemical and Biological Methods, J. of the Korean Society of Clothing and Textiles, 23(6), 809-819(1999)
  5. A. T. Balazsy, D. Eastop, 'Chemical principles of Textile Conservation', Butterworth-Heinemann, pp.28-29(1998)
  6. Steven B. Warner, 'Fiber Science', Prentice Hall, Inc., United States of America, p.41(1995)
  7. E. Gumuskaya, M. Usta and H. Kirci, The Effects of Various Pulping Conditions on Crystalline Structure of Cellulose in Cotton Linters, Poly­mer Degradation and Stability, 81, 559-564(2003) https://doi.org/10.1016/S0141-3910(03)00157-5
  8. H. Nishimura and A. Sarka, Mercerization of Cellulose Ill-Changes in Crystallite sizes-, J. Appl Polym Sci., 33, 855-866(1987) https://doi.org/10.1002/app.1987.070330314
  9. A Wlochowics and E. Sarna, Evaluation of Turkish Cotton Versus its Maturity Degree, Fibers and Textiles, 86-89(1996)
  10. B. Focher, MT. Palma, M Canetti, G. Tom, C. Cosentino, and G. Gastaldi, Structure Differences between Non-wood Plant Cellulose : Evidence from Solid State NMR, Vibrational Spectroscopy and X-ray Diffractometry, Ind Crops Products, 28(7), 245-249(2002)
  11. M. S. Lee, A Study on Structure and Properties of Cellulose, Wool, and Nylon 6 Fibers Treated with Liquid ammonia, thesis, Pusan National University(2002)