Removal Characteristics of Ethyl Acetate and 2-Butanol by a Biofilter Packed with Jeju Scoria

  • KAM SANG-KYU (Division of Civil and Environmental Engineering, Cheju National University) ;
  • KANG KYUNG-HO (Division of Civil and Environmental Engineering, Cheju National University) ;
  • LEE MIN-GYU (Division of Applied Chemical Engineering, Pukyong National University)
  • Published : 2005.10.01

Abstract

The removal characteristics of ethyl acetate and 2-butanol were investigated in a bench-scale down-flow biofilter packed with Jeju scoria medium. Various inlet concentrations and gas flow rates were tested. The adaptation times of microorganisms to the change of the influent concentration of ethyl acetate and 2-butanol gas were found to be about 3 days. At the inlet concentration of 300 ppmv and empty bed contact time (EBCT) of 15 see, the removal efficiencies of the biofilter for ethyl acetate and 2-butanol were above $99.9\%$. The maximum removal capacity of the biofilter for ethyl acetate was $316-318\;g/m^3/h$ and that for 2-butanol was $245-251\;g/m^3/h$. Overall, the removal capacity of the biofilter for ethyl acetate was $50-70\;g/m^3/h$ larger than that for 2-butanol. During the operation of 65 days, the pressure drop through the biofilter column was maintained below $13\;mmH_{2}O/m$. Although the pH in the drain water decreased from 7.2 to 5.0, the pH drop did not affect the removal of the gases. From the above results, the biofilter using Jeju scoria as a packing material seemed to very effectively treat waste gases such as ethyl acetate and 2-butanol.

Keywords

References

  1. Atlas, R. M. and R. Bartha, 1995. Handbook of Microbiological Media. CRC Press, Boca Raton, FL
  2. Baltzis, B. C. and H. Androutsopoulou. 1994. p. 14. In: Proceedings of the 87th Annual Meeting and Exhibition Air & Waste Management Association, 94-RP115B.02; Air & Waste Management Association; Pittsburgh, PA
  3. Bielefeldt, A. R. 1996. Biotreatment of contaminated gases in a sparged suspended-growth reactor: Mass transfer and biodegradation model. Ph.D. Dissertation, University of Washington, Washington, U.S.A., 4-55
  4. Cho, K. S., H. W Ryu, and N. Y. Lee. 2000. Biological deodorization of hydrogen sulfide using porous lava as a carrier of Thiobacillus thiooxidans. J. Biosci. Bioeng. 90: 25-31 https://doi.org/10.1016/S1389-1723(00)80029-8
  5. Christen, P., F. Domenech, G. Michelena, R. Auria, and S. Revah. 2002. Biofiltration of volatile ethanol using sugar cane bagasse inoculated with Candida utilis. J. Hazard. Mater. B89: 253-265
  6. Chung, Y. C., C. Huang, C. P. Tseng, and J. R. Pan. 2000. Biotreatment of H2S- and NH3-containing waste gases by co-immobilized cells biofilter. Chemosphere 41: 329-336 https://doi.org/10.1016/S0045-6535(99)00490-7
  7. Cox, H. H., R. E. Moerman, S. van Baalen, and W. N. M. Heiningen. 1997. Performance of a styrene degrading biotilter containing the yeast Exhophiala jeanselmei. Biotechnol. Bioeng. 3: 259-266
  8. Deshusses, M. A., C. T. Johnson, and G. J. Leson.1999. J. Air Waste Manage. Assoc. 49: 2383-2391
  9. Han, H. J. and O. S. Jo. 1996. Study on Evaluation of Emission and Reduction Technology on VOC Discharge Source. Korea Petroleum Association
  10. Jorio, H., L. Bibeau, G. Vie, and M. Heitz. 2000. Effects of gas flow rate and inlet concentration on xylene vapors biotiltration performance. Chem. Eng. J. 76: 209-221 https://doi.org/10.1016/S1385-8947(99)00160-6
  11. Kiared, K., B. Fundenberger, R. Brzezinski, G. Viel, and M. Heitz. 1997. Biofiltration of air polluted with toluene under steady-state conditions; experimental observations. Ind. Eng. Chem. Res. 36: 4719-4725 https://doi.org/10.1021/ie9701478
  12. Kim, C. W, J. S. Park, S. K. Cho, K. J. Oh, Y. S. Kim, and D. G. Kim. 2003. Removal of hydrogen sulfide, ammonia, and benzene by fluidized bed reactor and biofilter. J. Microbiol. Biotechnol. 13: 301-304
  13. Kwon, H. H., E. Y. Lee, K. S. Cho, and H. W. Ryu. 2003. Benzene biodegradation using the polyurethane biofilter immobilized with Stenotrophomonas maltophilia T3-c. J. Microbiol Biotechnol. 13: 70-76
  14. Lee, S. H., D. H. Lee, and M. G. Lee. 2003. Removal characteristics of benzene in the biofilter packed with scoria. Hwahak Konghak 41: 781-787
  15. Leson, G. and A. Winer. 1991. Biotiltration: An innovative air pollution control technology for VOC emissions. J. Air Waste Manage. Assoc. 41: 1045-1054 https://doi.org/10.1080/10473289.1991.10466898
  16. Leson, G., R. Chavira, A. Winer, and D. Hodge. 1995. Experiences with a full-scale biotilter for control of ethanol emissions, pp. 11. In: Proceedings of the 88th Annual Meeting of the Air and Waste Management Association. San Antonio, TX, U.S.A
  17. Liu, Y., X. Quan, Y. Sun, J. Chen, D. Xue, and J. S. Chung. 2002. Simultaneous removal of ethyl acetate and toluene in air streams using compost-based biotilters. J. Hazard. Mater. B95: 199-213
  18. Lu, C., M. R. Lin, J. Lin, and K. Chang. 2001. Removal of ethyl acetate vapor from waste gases by a trickle-bed air biotilter. J. Biotechnol. 87: 123-130 https://doi.org/10.1016/S0168-1656(01)00228-0
  19. Mallakin A. and O. P. Ward. 1996. Degradation of BTEX compounds in liquid media and in peat biofilters. J. Ind. Microbiol. 16: 309-318 https://doi.org/10.1007/BF01570040
  20. Martin, G. T. and R. C. Loehr. 1996. Effect of periods of non-use on biofilter performance. J. Air Waste Manage. Assoc. 46: 539-546 https://doi.org/10.1080/10473289.1996.10467489
  21. Morales M., R. Auria, F. Perez, and S. Revah. 1994. Toluene removal from air stream by biotiltration, pp. 405-411. In Galindo, E. and Ramirez, T. (eds.), Advances in Bioprocess Engineering. Dordrecht, The Netherlands: Kluwer Academic Press
  22. Ottengraf, S. P. P. 1986. Exhaust gas purification. In Rehm, H. J., Reed, G. (eds.). Biotechnology, pp. 425-452. Weinheim: VCH Verlagsgesellschaft
  23. Sabo, F. 1991. Behandlung von deponiegas im biotilter. Ph. D. Thesis, University of Stuttgart, Germany
  24. Smet, E., G. Chasaya, V. Langenhove, and W. Verstratete. 1996. The effect of inoculation and the type of carrier material used on the biofiltration of methyl sulfides. Appl. Microbiol. Biotechnol. 45: 293-298 https://doi.org/10.1007/s002530050686
  25. Tang, H. M. and S. J. Hwang. 1996. Waste gas treatment in biofilters. J. Air Waste Manage. Assoc. 46: 349-354
  26. Warren, J. S. and C. L. Raymond. 1997. Biofiltration: Fundamentals, design and operations principles, and applications. J. Environ. Eng. 123: 538-546 https://doi.org/10.1061/(ASCE)0733-9372(1997)123:6(538)
  27. Williams T. O. 1995. Odors and VOC emissions control method. Biocycle 36: 49-56
  28. Winer, M. 1991. Biofiltration: An innovative air pollution control technology for VOC emissions. J. Air Waste Manage. Assoc. 41: 1045 https://doi.org/10.1080/10473289.1991.10466898
  29. Wolstenholme, P. and R. Finger. 1995. Long-term odor and VOC pilot tests on biofilters, pp. 273-286. In: Proceedings of the 1995 Conference on Biojiltration. University of South California, Los Angeles, Tustin, C.A., The Reynolds Group