Journal of Korean Society of Environmental Engineers (대한환경공학회지)

Korean Society of Environmental Engineers (대한환경공학회)
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Characteristics of PCDD/Fs Deposited on Regional Pine Needles and Soil

지역별 소나무잎과 토양에 침착된 PCDD/Fs 특성

  • Chun, Man-Young (Department of Environmental Engineering, Hankyong National University) ;
  • Kim, Tae-Wook (Department of Environmental Engineering, Hankyong National University)
  • Published : 2005.11.30
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Abstract

This study investigated on concentrations of PCDD/Fs and the homologue profiles deposited on pine needles and soil collected from different areas. As, in an area, the concentration of ${\sum}PCDD/Fs$ of pine needles decreased, the percentages of the higher chlorinated homologues of pine needles decreased, and those of lower chlorinated ones increased. However on the contrary the percentages of the higher chlorinated homologues of soil increased and those of lower chlorinated ones decreased. The concentrations of PCDD/Fs deposited on pine needles only depended upon those of PCDD/Fs in air, while the concentration of PCDD/Fs deposited on soil depended upon those of organic matter contents as well as those of PCDD/Fs in air. The results showed that pine needles rather than soil were adequate as a passive sampler.

서로 다른 장소에서 소나무잎과 토양을 채취하여 그 중에 침착된 PCDD/Fs의 농도와 homologue별 농도분포 특성에 대하여 연구하였다. 소나무잎중 PCDD/Fs homologue 농도분율은 소나무잎중 ${\sum}PCDD/Fs$ 농도가 낮은 지역일수록 염소치환수가 많은 homologue의 농도분율은 낮아지고 염소치환수가 적은 homologue의 농도분율은 높아지는 경향을 보였다. 그러나 토양중 PCDD/Fs homologue 농도분율은 소나무잎중 ${\sum}PCDD/Fs$ 농도가 낮은 지역일수록 염소치환수가 적은 homologue의 농도분율은 감소하였고 염소치환수가 많은 homologue의 농도분율은 증가하는 경향을 보였다. 그리고 소나무잎에 침착된 PCDD/Fs 농도는 대기중 PCDD/Fs 농도에 의존하지만 토양에 침착된 PCDD/Fs 농도는 대기중 PCDD/Fs 농도와 동시에 토양중 유기물의 농도에도 의존하였다. 그러므로 대기중 PCDD/Fs의 passive sampler로는 토양보다 소나무잎이 더 적합하였다.

Keywords

References

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