Comparison of the Mercury Removal Efficiency using TiO2 Powder under Various Light Sources

다양한 광원하에서의 TiO2에 의한 수은제거 효율비교

  • Lee, Yong-Gyu (Department of Chemical Engineering, Yonsei University) ;
  • Lee, Tai-Gyu (Department of Chemical Engineering, Yonsei University) ;
  • Kim, Woo-Sik (Department of Chemical Engineering, Yonsei University)
  • 이용규 (연세대학교 화학공학과) ;
  • 이태규 (연세대학교 화학공학과) ;
  • 김우식 (연세대학교 화학공학과)
  • Received : 2004.11.02
  • Accepted : 2004.12.30
  • Published : 2005.02.28

Abstract

In this study, mercury was removed by $TiO_2$ using fluorescent light and sunlight, instead of UV lamps. A reactor was specially designed to increase the $TiO_2's$ exposure to the light source and to make the rotational speed constant. The contacting surface area between mercury and adsorbents was increased by packing the adsorption bed with mixture of $TiO_2$ and glass beads. The mercury removal efficiency was more than 99% under all light sources tested in this study. The mercury removal efficiency was more than 99% under the fluorescent light or sunlight which is harmless and cheap or free.

자외선을 대체하여 형광등이나 자연광(햇빛)을 이용하여 $TiO_2$로 수은제거 실험을 수행하였다. 반응기는 내부의 $TiO_2$가 광원에 최대한 노출되도록 디자인하였으며 회전할 수 있게 하였다. 반응기 내부에 $TiO_2$와 유리비드를 섞어 넣어 기상수은과 흡착제와의 접촉면적을 최대화하였다. 광촉매가 가장 활성을 잘 보이는 UV black light뿐 아니라 실험에 사용된 모든 광원에서 99% 이상의 수은제거효율을 보였다. 인체에 무해하고 경제성이 좋은 형광등이나 태양광하에서도 99% 이상의 수은제거효율을 얻었다.

Keywords

References

  1. U.S. Environmental Protection Agency, 'Mercury Study Report to Congress,' EPA Report; EPA-452/R-97-003, Office of Air Quality Planning and Standards and Office of Research and Development, Washington, DC(1998)
  2. Owens, T. M. and Biswas, P., 'Vapor Phase Sorbent Precursors for Toxic Metal Emissions Control from Combustors,' Ind. Eng. Chem. Res., 35(3), 792-798(1996) https://doi.org/10.1021/ie9502446
  3. Lee, T. G., Hedrick, E. and Biswas, P., 'Comparison of Hg0 Capture Efficiencies of Three in situ Generated Sorbents,' AlChE J., 47(4), 954-961(2001) https://doi.org/10.1002/aic.690470418
  4. Lengyel, Jr. J., DeVito, M. S. and Bilonick, R. A., 'Interlaboratory and Intralaboratory Variability in the Analysis of Mercury in Coal,' J. Air & Waste Mgmnt. Assocn., 46(4), 317-326(1996)
  5. Lee, T. G., Biswas, P. and Hedrick, E., 'Overall Kinetics of Heterogeneous Elemental Mercury Reactions on $TiO_2$ Sorbent Particles with UV Irradiation,' Ind. Eng. Chem. Res., 43(6), 1411-1417(2004) https://doi.org/10.1021/ie0303707
  6. U.S. EPA, The Ontario Hydro Method, Draft Manual, U.S. Government Printing Office, Washington, D.C.(1998)
  7. Wu, C. Y., Lee, T. G., Tyree, G., Arar, E. and Biswas, P., 'Capture of Mercury in Combustion Systems by In Situ Generated Titania Particles with UV Irradiation,' Environ. Eng. Sci., 15(2), 137-148(1998) https://doi.org/10.1089/ees.1998.15.137