Physical Properties of Hybrid Poplar Flakeboard Bonded with Alkaline Phenolic Soy Adhesives

  • Yang, In (Department of Forest Products, Seoul National University) ;
  • Kuo, Monlin (Department of Natural Resource Ecology and Management, Iowa State University) ;
  • Myers, Deland J. (Department of Food Science & Human Nutrition Iowa State University)
  • Received : 2005.06.20
  • Accepted : 2005.09.06
  • Published : 2005.09.25

Abstract

Soybean-based adhesives have recently been reconsidered as alternatives to petroleum-based adhesives due to the uncertainty of availability of petrochemical products and the increased demand for wood adhesives. This study was conducted to investigate the adhesive properties of alkaline phenolic soy (APS) resin for hybrid poplar flakeboard. The APS resin was formulated by crosslinking an alkaline soy flour hydrolyzate with lab-prepared PF resin in the soy hydrolyzate to PF resin weight ratios of 70/30, 60/40, and 50/50. The APS resins were used to fabricate homogeneous hybrid poplar flakeboards with different resin solid levels (5%, 7%, and 9%), press temperatures (175 and $200^{\circ}C$), and press times of 8 and 10 minutes. The IB, wet MOR, and dimensional stability properties of board improved with increasing press time, press temperature, and PF level in APS resins. Increasing press time can be used to offset poor IB strength associated with a 9% resin solid level and the excessive moisture content in the mat. The following conditions were concluded to meet the requirements of the CSA standard for exterior-grade flakeboard: a 50% PF level, a 5% resin content, a $200^{\circ}C$ press temperature, and an 8 minute press time.

Keywords

References

  1. Adams, D. 2000. U.S. structural panel consumption. [Online]. http://www.fs.fed.us/pnw/sev/rpa/adams files
  2. American Society for Testing and Materials. 1998. Standard test methods for evaluating properties of wood-based fiber and particle panel materials. ASTM D 1037-96a. ASTM, West Consshohocken, PA
  3. American Society for Testing and Materials. 1993. Standard test methods for determination of percent nonvolatile content of liquid phenolic resins used for wood laminating. ASTM 0 4426. ASTM, Philadelphia, PA
  4. Barbosa, A. P., E. B. Mano, and C. T. Andrade. 2000. Tannin-based resins modified to reduce wood adhesive brittleness. For. Prod. J. 50(9): 89-92
  5. Geimer, R. L. and J. B. Crist. 1980. Structural flakeboard from short-rotation, intensively cultured hybrid populus clones. For. Prod. J. 30(6): 42-48
  6. Hse, C. Y. 1975. Properties of flakeboards from hardwoods on southern pine sites. For. Prod. J. 25(3): 48 - 53
  7. Hse, C. Y., F. Fu, and B. S. Bryant. 2001. Development of formaldehyde-based wood adhesives with co-reacted phenol/soybean flour. In Wood Adhesives 2000, For. Prod. Soc. Madison, WI
  8. Johnson, R. S. 2001. An overview of North American wood adhesive resins. In Wood Adhesives 2000, For. Prod. Soc. Madison, WI
  9. Kelly, M. W. 1977. Critical literature review of relationships between processing parameters and physical properties of particleboard. General Technical Report FPL-IO. For. Prod. Lab., Madison, WI
  10. Koch, G. S., F. Klareich, and B. Exstrum. 1987. Adhesives for the Composite Wood Panel Industry. Noyes Data Corp. Park Ridge, NJ
  11. Kuo, M. L., Myers, D. J., Heemstra, H., Curry, D., Adams, D.O., and D. D. Stokke. 2001. Soybean-based adhesive resins and composite products utilizing such adhesives. U.S. Patent 6,306,997
  12. Kuo, M. L. and D. D. Stokke. 2001. Soybeanbased adhesive resins for composite products. In Wood Adhesives 2000, For. Prod. Soc. Madison, WI
  13. Liu, J. 1988. Influence of board construction on properties of flakeboard from six-year-old silver maple. M.S. thesis, Iowa State Univ., Ames, IA
  14. Pizzi, A. 1983. Tannin-based wood adhesives. In Wood Adhesive, Chemistry and Technology, A. Pizzi, ed. Marcel Dekker, Inc., New York, NY.
  15. Sellers, Jr., T., M. G. Kim, G. D. Miller, R. A. Haupt, and R. C. Strickland. 1994. Comparison of strands made with phenol-formaldehyde resin and resins modified with TVA acid-hydrolysis lignin. For. Prod. J. 44(4): 63-68
  16. Shupe, T. F., C. Y. Hse, and E. W. Price. 2001. Flake orientation effects on physical and mechanical properties of sweetgum flakeboard. For. Prod. J. 51(9): 38-43
  17. Structural Board Association. 2001. Canadian Standard Association (CSA) Standard O 437 [Online]. http://www.osbguide.com