Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Experimental and Theoretical Studies of Cationic Gemini Surfactant and Anionic Sodium Lauryl Ether Sulfate

Cheon, Ho-Young;Kim, Myung-Soo;Jeong, Noh-Hee

  • Published : 20050100
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Abstract

Abstract: The mixed micellization of dimeric 1,2-bis(dodecyldimethyl ammonium)ethane dibromide (CGSI) and sodium lauryl ether sulfate (SLES) has been investigated. The surface tension was measured as a function of the concentration of the surfactants in aqueous solutions at 25 and $35^{\circ}C$ using a surface tensiometry and electrical conductometry apparatus. From these measurements, the critical micelle concentration (CMC), the thermodynamic parameters ($X_{i}$, $\gamma_{i}$, $a_{i}^{M}$, $\DeltaH_{mic}$), and the interfacial parameters ($\gamma_{CMC}$, $pC_{20}$, $\Gamma_{max}$, $-d_{\gamma}/dlogC$, $A_{min}$, $CMC/C_{20}$) were calculated and analyzed by means of equations derived from the nonideal mixed micelle model. Structural effects on the adsorption and micellization and the effectiveness of surface tension reduction are discussed in terms of these parameters. The kinds and degrees of interactions between the different surfactant molecules are explained on the basis of a regular solution model. The interaction parameter, $\beta$, was calculated to be -4.38 for the SLES/CGSI system at $25^{\circ}C$ and -4.72 at $35^{\circ}C$. These negative values indicate a reduction in the free energy of micellization over that predicted by the ideal solution theory, and reflect the synergistic behavior of the components (SLES and CGSI) in the mixed micelle. The behavior of this mixed surfactant system at interfaces and in dilute solution (viscosity, solubilization, and foaming power) is also reviewed.

Keywords

References

  1. D. Stoye, Paints, Coatings and Solvents, VCR, Weinheim (1993)
  2. M. M. Reiger, Surfactants in Cosmetics, Marcel Dekker, New Yark (1985)
  3. P. H. Elworthy, A. T. Florence, and C. B. Macfarlane, Solubilisation by surface Active Agent, Chapman and Hall, London (1968)
  4. P. Becher, Encyclopedia of Emulsion Technology, Vol. 2,Marcel Dekkerr, New Yark (1985)
  5. S. E. Friberg Food Emulsions, Vol. 5,Marcel Dekker, New York (1976)
  6. D. O. Shah and R. S. Schechter, Improved Oil Recovery by Surfactant and Polymer Flooding, Academic Press New York (1977)
  7. J. F. Scamehom,in Mixed Surfactant Systems, K. Ogino and M. Abe, Eds., Dekker, New York (1992)
  8. E. H. Lucassen-Reynders, J. Lucassen, and D. Giles, J. Colloid Interface Sci., 81, 150 (1981)
  9. F. M. Menger and J. S. Keiper, Angew. Chem. Int. Ed., 39, 1906 (2000)
  10. R. Zana, Adv. Colloid Interface Sci., in press (2002)
  11. V. Schmitt, F. Schosseler, and F. Lequeux, Europhys. Lett., 30, 31 (1995)
  12. R. Zana and H. Levy, Colloid Surf A,127,229 (1997) https://doi.org/10.1016/S0927-7757(97)00142-8
  13. M. Frindi, B. Michels, H. Levy, and R. Zana, Langmuir,10, 1140 (1994) https://doi.org/10.1021/la00016a005
  14. R. Zana, M. Benrraou, and R. Rueff, Langmuir,7, 1072 (1991)
  15. D. Danino, Y. Talmon, and R. Zana, Langmuir,11, 1448 (1995)
  16. A. Alami, H. Levy, R. Zana, and A. Skoulios, Langmuir,10, 2177 (1994) https://doi.org/10.1021/la00016a005
  17. E. Alami, G. Beinert, P. Marie, and R. Zana, Langmuir, 9, 1465 (1993) https://doi.org/10.1021/la00030a006
  18. T. A. Camesano and R. Nagarajan, Colloid Surf A, 167, 165 (2000)
  19. R. Zana and Y. Talmon, Nature, 362, 228 (1993)
  20. T.-S. Coi, G. Shimizu, M. Shirai, and K. Hamada, Dyes Pigments, 45, 145 (2000) https://doi.org/10.1016/S0143-7208(00)00015-2
  21. M. Benjelloum, M. Van der Voort, P. Cool, O. Collart, and E. F. Vansant, Phys. Chem., 3, 127 (2001) https://doi.org/10.1039/b008225m
  22. P. Camilleri, Chem. Commun.,1253 (2000)
  23. R. Zielinski, J. Colloid Interface Sci., 235, 201 (2001) https://doi.org/10.1006/jcis.2000.7305
  24. A. Kiraly and I. Dekany, J. Colloid Interface Sci., 242, 214 (2002)
  25. G. Sugihara and M. Hisatomi, J. Colloid Interface Sci., 219, 31 (1999)
  26. J. M. Ruso, P. Taboada, V. Mosquera, and F. Sarmiento J. Colloid Interface Sci., 214, 292 (1999)
  27. P. Taboada, D. Attwood, M. Garcia, M. N. Jones, J. M. Ruso, V. Mosquera, and F. Sarmiento, J. Colloid Interface Sci., 221, 242 (2000)
  28. D. Attwood, E. Boitard, J.-P. Dubes, and H. Tachoire, J Colloid Interface Sci., 227, 356 (2000)
  29. A.-M. Misselyn-Bauduin, A. Thibaut, J. Grandjean, G. Broze, and R. Jerome, J. Colloid Interface Sci., 238,1 (2001)
  30. H. Walderhaug and B. Nystrom, Colloids Surf A,149, 379 (1999)
  31. O. Annunziata, L. Costantino, G. D'Errico, L. Paduano, and V. Vitagliano, J. Colloid Interfce Sci., 216, 16 (1999)
  32. A. Caria, O. Regev, and A. Khan, J. Colloid Interface Sci., 200, 19 (1998)
  33. D. Grabner, T. Matsuo, E. Hoinkis, C. Thunig, and H. Hoffmann, J. Colloid Interface Sci., 236, 1 (2001) https://doi.org/10.1006/jcis.2000.7388
  34. T. Z. Wang, S. Z. Mao, X. J. Miao, S. Zhao, J. Y. Yu,and Y. R. Du, J. Colloid Interface Sci., 241, 465 (2001) https://doi.org/10.1006/jcis.2001.7740
  35. N. M. Correa, E. N. Durantini, and J. J. Silber, J. Colloid Interface Sci., 240, 573 (2001) https://doi.org/10.1006/jcis.2001.7616
  36. D. Shraboni, M. Subho, and M. Amarnath, J. Colloid Interface Sci., 230, 328 (2000)
  37. N. Yasuhiro, K. Takumi, N. Susumu, and T. Katsuroku, J. Membr. Sci., 195, 11 (2002)
  38. D. N. Rubingh, in Solution Chemistry of Surfactants, K. L. Mittal, Ed.,Vol. 1,pp. 337, Plenum, New Yark (1979)
  39. N. Nishikido,Y. Moroi, and R. Matuura, Bull. Chem. Soc., 5, 1387 (1975)
  40. B. H. Lee, S. D. Christian, E. E. Tucker,and J. F. Scamehorn, J. Phys. Chem., 95, 360 (1991)
  41. K. Esumi and M. Ogawa, Langmuir, 9, 358 (1993) https://doi.org/10.1021/la00028a019
  42. P. M. Holland and D. N. Rubingh, J. Phys. Chem., 87, 1984 (1983)
  43. P. M. Holland, in Mixed Surfactant Systems, P. M. Holland and D. N. Rubingh Ed., p. 31, ACS Symposium Series, American Chemical Society: Washington, DC (1992)
  44. B. H. Lee, J. Korean Chem. Soc., 37, 562 (1993)
  45. J. F. Rathman and S. D. Christian, Langmuir, 6, 391 (1990)
  46. M. J. Rosen, A. W. Cohen, M. Dahanayake, and X. Y. Hua, J. Phys. Chem., 86, 54 (1982) https://doi.org/10.1021/j100395a030
  47. Y. Muto, M. Asada, K. Esumi, K. Meguro, and A. Takasawa, J. Colloid Interface Sci., 124, 632 (1988)
  48. M. Takeuchi and Y. Moroi, J. Colloid Interface Sci., 197, 230 (1998)
  49. S. Sinha, A. Dogra, N. Jain, and P. Bahadur, Indian J. Chem., Sect. A, 37, 118 (1998)
  50. T. S. Choi, H. Ichikawa, J. Qian, Y. Shimizu, H. Shirai, and K. Hamada, Sen'i Gakkaishi, 55, 597 (1999)
  51. W. F. Patton, J. Chromatogr. B, 771, 3 (2002)
  52. J. P. Malone, M. R. Radabaugh, R. M. Leimgruber, and G. S. Gerstenecker, Electrophoresis, 22, 919 (2001)