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1-D photonic crystals of free-standing DBR PSi for sensing and drug delivery applications

비고정화 된 일차원 광결정의 DBR 다공성 실리콘을 이용한 센서와 Drug Delivery로의 응용

  • Published : 2006.11.30

Abstract

Free-standing multilayer distributed Bragg reflectors (DBR) porous silicon dielectric mirrors, prepared by electrochemical etching of crystalline silicon using square wave currents are treated with polystyrene to produce flexible, stable composite materials in which the porous silicon matrix is covered with caffeine-impregnated polystyrene. Optically encoded DBR PSi/polystyrene composite films retain the optical reflectivity. Optical characteristics of DBR PSi/polystyrene composite films are stable and robust for 2 hrs in a pH=7 aqueous buffer solution. The appearance of caffeine and change of DBR peak were simultaneously measured by UV-vis spectrometer and Ocean optics 2000 spectrometer, respectively.

Keywords

References

  1. A. Uhlir, 'Electronics shaping of germanium and silicon', Bell System Tech., vol. 35, pp. 333, 1956
  2. H. Sohn, S. Letant, M. J. Sailor, and W. C. Trogler, 'Detection of fluorophosphonate chemical warfare agent by catalytic hydrolysis with a porous silicon interferometer', J. Am. Chem. Soc., vol. 122, pp. 5399, 2000
  3. A. Bsiesy, J. C. Vial, F. Gaspard, R. Herino, M, Ligeon, F. Muller, R. Romestain, A. Wasiela, A. Halimaoui, and G Bomchil, 'Photoluminescence of high porosity and of electrochemically oxidized porous silicon layers', Surf Sci., vol. 254, pp. 195-200, 1991 https://doi.org/10.1016/0039-6028(91)90652-9
  4. L. T. Canham, 'Silicon quantum array fabrication by electrochemical and chemical dissolution as wafers', Appl. Phys. Lett., vol. 57, pp. 1046-1048, 1990 https://doi.org/10.1063/1.103561
  5. A. G. Cullis and L. T. Canham, 'Visible light emission due to quantum size effects in highly porous crystalline silicon', Nature, vol. 353, pp. 335-338, 1991 https://doi.org/10.1038/353335a0
  6. F. Gaspard, A. Bsiesy, M. Ligeon, F. Muller, and R. J. Herino, 'Exchange mechanism responsible for p-type silicon dissolution during porous silicon formation', Electrochem. Soc., vol. 136, pp. 3043-3046, 1989 https://doi.org/10.1149/1.2096399
  7. P. C. Searson, J. M. Macaulay, and F. M. Ross, 'Pore morphology and mechanism of pore formation in n-type silicon', J. Appl. Phys., vol. 72, pp. 253-258, 1992 https://doi.org/10.1063/1.352123
  8. C. Levy-Clement, A. Lagoubi, and M. J. Tomkiewucz, 'Morphology of porous n-type silicon obtained by photoelectrochemical etching', Electrochem. Soc., vol. 141, pp. 958-967, 1994 https://doi.org/10.1149/1.2054865
  9. V. S. Lin, K. Motesharei. K. S. Dancil, M. J. Sailor, and M. R. Ghadiri, 'A porous silicon-based optical interferometric biosensor', Science, vol. 278, pp. 840-843, 1997 https://doi.org/10.1126/science.278.5339.840
  10. V. V. Doan and M. J. Sailor, 'Luminescent color image generation on porous silicon', Science, vol. 256, pp. 1791-1792, 1992 https://doi.org/10.1126/science.256.5065.1791
  11. J. M. Lauerhaass and M. J. Sailor, 'Chemical modification of the photoluminescence quenching of porous silicon', Science, vol. 261, pp. 1567-1568, 1993 https://doi.org/10.1126/science.261.5128.1567
  12. A. Nakajima, T. Itakura, S. Watanabe, and N. Nakayama, 'Photoluminescence of porous Si, oxidized then deoxidized chemically', Appl. Phys. Lett., vol. 61, pp. 46-48, 1992 https://doi.org/10.1063/1.107663
  13. E. J. Lee, T. W. Bitner, J. S. Ha, M. J. S. Shane, and M. J. Sailor, 'Photoinduced surface reactions of reverse-biased n-type porous Si', J. Am. Chem. Soc., vol. 118, pp. 5375-5382, 1996 https://doi.org/10.1021/ja960777l
  14. E. J. Lee, J. S. Ha, and M. J. Sailor, 'Chemical modification of the porous silicon surface', J. Am. Chem. Soc., vol. 117, pp. 8295-8296, 1995 https://doi.org/10.1021/ja00136a038
  15. W. H. Green, E. J. Lee, J. M. Lauerhaas, T. W. Bitner, and M. J. Sailor, 'Electrochemiluminescence from porous silicon in formic acid liquid-junction cells', Appl. Phys. Lett., vol. 67, pp. 1468-1470, 1995 https://doi.org/10.1063/1.114497
  16. J.-H. Sim, D.-K. Kim, c.-S. Cho, H.-S. Tae, S.-H. Hahm, and J.-H. Lee, 'Fabrication of piezoresistive silicon acceleration sensor using selectively porous silicon etching method', J. of the Korean Sensors Society, vol. 5, no. 5, pp. 21-29, 1996
  17. S.-J. Kim, 'Study on the development of mesa-type humidity sensors using porous silicon layer', J. of the Korean Sensors Society, vol. 8, no. I, pp. 32-37, 1999
  18. D. T. McQuade, A. E. Pullen, and T. M. Swager, 'Conjugated polymer-based chemical sensors', Chem. Rev., vol. 100, pp. 2537-2574, 2000 https://doi.org/10.1021/cr9801014
  19. M. S. Yoon, K. H. Ahn, R. W. Cheung, H. Sohn, J. R. Link, F. Cunin, and M. J. Sailor, 'Covalent crosslinking of 1-D photonic crystals of microporous Si by hydrosilylation and ring-opening metathesis polymerization', Chem. Commun., pp. 680-681, 2003