Bulletin of the Korean Chemical Society

  • 제27권4호
  • /
  • Pages.539-544
  • /
  • 2006
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Proton Transfer Reactions and Ion-Molecule Reactions of Ionized XCH2CH2Y (X and Y = OH or NH2)

  • 발행 : 2006.04.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Proton transfer reactions and ion-molecule reactions of bifunctional ethanes of $H_2NCH_2CH_2NH_2$, $H_2NCH_2CH_2OH$, and $HOCH_2CH_2OH$ were studied using Fourier transform mass spectrometry (FTMS). The rate constants for proton transfer reactions between the fragment ions and neutral molecules were obtained from the temporal variation of the ion abundances. The rate constants were consistent with the heats of reaction. The fastest proton transfer reactions were the reactions of $CH_2N^+$, $CHO^+$, and $CH_3O^+$ for $H_2NCH_2CH_2NH_2$, $H_2NCH_2CH_2OH$, and $HOCH_2CH_2OH$, respectively. The $[M+13]^+$ ion was formed by the ion-molecule reaction between $H_2C=NH_2 ^+$ or $H_2C=OH^+$ and the neutral molecule. The major product ions generated from the ion-molecule reactions between the protonated molecule and neutral molecule were $[2M+H]^+$, $[M+27]^+$, and $[M+15]^+$.

키워드

참고문헌

  1. Raczynska, E. D.; Maria, P.-C.; Gal, J.-F.; Decouzon, M. J. Mass Spectrom. 2000, 35, 1222 https://doi.org/10.1002/1096-9888(200010)35:10<1222::AID-JMS49>3.0.CO;2-Q
  2. Chen, X.; Zhong, D.; Liu, D.; Wang, Y.; Han, Y.; Gu, J. Raipd Commun. Mass Spectrom. 2003, 17, 2459 https://doi.org/10.1002/rcm.1189
  3. Paul, G.; Winnik, W.; Hughes, N.; Schweingruber, H.; Heller, R.; Schoen, A. Raipd Commun. Mass Spectrom. 2003, 17, 561 https://doi.org/10.1002/rcm.952
  4. El-Deen, I. M.; El-Fattah, M. E. Bull. Kor. Chem. Soc. 2003, 24, 559 https://doi.org/10.5012/bkcs.2003.24.5.559
  5. Nibbering, N. M. M. Acc. Chem. Res. 1990, 23, 279 https://doi.org/10.1021/ar00177a003
  6. Dearden, D. A.; Liang, Y.; Nicoll, J. B.; Kellersberger, K. A. J. Mass Spectrom. 2001, 36, 989 https://doi.org/10.1002/jms.215
  7. Choi, S. S.; So, H.-Y. Bull. Kor. Chem. Soc. 2004, 25, 1538 https://doi.org/10.5012/bkcs.2004.25.10.1538
  8. Choi, S. S.; So, H.-Y. Int. J. Mass. Spectrom. 2005, 243, 249 https://doi.org/10.1016/j.ijms.2005.03.009
  9. Choi, S. S.; So, H.-Y.; Kim, B.-T. Bull. Kor. Chem. Soc. 2005, 26, 609 https://doi.org/10.5012/bkcs.2005.26.4.609
  10. Harrison, A. G.; Keyes, B. G. J. Am. Chem. Soc. 1968, 90, 5046 https://doi.org/10.1021/ja01020a062
  11. Liou, C.-C.; Eichmann, E. S.; Brodbelt, J. S. Org. Mass Spectrom. 1992, 27, 1098 https://doi.org/10.1002/oms.1210271020
  12. Ahmed, M. S.; Hudson, C. E.; Giam, C. S.; McAdoo, D. J. Org. Mass Spectrom. 1991, 26, 1089 https://doi.org/10.1002/oms.1210261211
  13. Blanc, P. A.; Gülacar, F. O.; Buch, A. Org. Mass Spectrom. 1978, 13, 135 https://doi.org/10.1002/oms.1210130305
  14. Burgers, P. C.; Holmes, J. L.; Hop, C. E. C. A.; Postma, R.; Rutink, P. J. A.; Terlouw, J. K. J. Am. Chem. Soc. 1987, 109, 7315 https://doi.org/10.1021/ja00258a012
  15. Fujii, T.; Kitai, T. Int. J. Mass Spectrom. Ion Processes 1986, 71, 129 https://doi.org/10.1016/0168-1176(86)85051-0
  16. Audier, H. E.; Milliet, A.; Perret, C.; Tabet, J. C.; Varenne, P. Org. Mass Spectrom. 1978, 13, 315 https://doi.org/10.1002/oms.1210130604
  17. Lias, S. G.; Liebman, J. F.; Levin, R. D. J. Phys. Chem. Ref. Data 1984, 13, 695 https://doi.org/10.1063/1.555719
  18. Eichman, E. S.; Brodbelt, J. S. J. Am. Soc. Mass Spectrom. 1993, 4, 230 https://doi.org/10.1016/1044-0305(93)85086-D
  19. Weber, R.; Levsen, K. Org. Mass Spectrom. 1980, 15, 138 https://doi.org/10.1002/oms.1210150307

피인용 문헌

  1. Chemical Reactivity of Ti+ Ion within Ti+(CH2FCH2OH)n Clusters vol.29, pp.11, 2006, https://doi.org/10.5012/bkcs.2008.29.11.2183
  2. Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007 vol.29, pp.2, 2008, https://doi.org/10.5012/bkcs.2008.29.2.450
  3. Intracluster Ion-Molecule Reactions within Ti+(CH2FCH2OH)n Clusters vol.29, pp.4, 2006, https://doi.org/10.5012/bkcs.2008.29.4.725
  4. Competitive Ion-Molecule Reactions within V+(CH3COOCH3)n Clusters vol.31, pp.2, 2006, https://doi.org/10.5012/bkcs.2010.31.02.271
  5. Optoelectronic behavior of bischromophoric dyads exhibiting Zn2+/F- ions induced ''turn-On/Off'' fluorescence vol.169, pp.None, 2006, https://doi.org/10.1016/j.snb.2012.05.006