Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Electrochemical Characteristics of Si/Mo Multilayer Anode for Lithium-Ion Batteries

리튬 이온 전지용 Si/Mo 다층박막 음극의 전기화학적 특성

  • Park, Jong-Wan (Division of Materials Science and Engineering, Hanyang University) ;
  • Ascencio Jorge A. (Instituto Mexicano del Petroleo)
  • 박종완 (한양대학교, 박막재료 연구실) ;
  • Published : 2006.05.27
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Abstract

Si/Mo multilayer anode consisting of active/inactive material was prepared using rf/dc magnetron sputtering. Molybdenum acts as a buffer against the volume change of the Silicon. Multilayer deposited on RT (reversible treatment) copper foil current collector to enhance adhesion between Silicon and copper foil. Deposited Silicon was identified as an amorphous. Amorphous has a relatively open structure than crystal structure, thus prevents the lattice expansion and has many diffusion paths of Li ion. When deposited time of Silicon and Molybdenum is 30 second and 2 second respectably, electrode has more capacity and good cycle stability. A 3000 nm thick multilayer was maintained 99% of the initial capacity (1624 $mAhg^{-1}$) after 100 cycles. As the increase of the multilayer thickness (4500 nm, 6000 nm), Si/Mo mutilayer anodes show aggravation cycle stability.

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References

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