Performance of HCFC22 Alternatives R1270, R290, R1270/R290, R290/HFC152a, R1270/R290/RE170 Refrigerants for Air-conditioning and Heat Pump Applications

HCFC22 대체 R290, R1270 및 R1270/R290, R290/HFC152a, R1270/R290/RE170 혼합냉매의 공기조화기와 열펌프 작동범위에서의 성능 평가

  • 황지환 (인하대학교 대학원 기계공학과) ;
  • 백인철 (인하대학교 대학원 기계공학과) ;
  • 정동수 (인하대학교 기계공학과)
  • Published : 2006.04.01

Abstract

In this study, performance of 2 pure hydrocarbons and 7 mixtures was measured in an attempt to substitute HCFC22 used in air-conditioners and heat pumps. The mixtures were composed of R1270 (propylene), R290 (propane), HFC152a, and RE170 (Dimethyl ether, DME). The pure and mixed refrigerants tested have GWPs of $3{\sim}58$ as compared to that of $CO_2$ and the mixtures are all near-azeotropic showing the gliding temperature difference (GTD) of less than $0.6^{\circ}C$. Thermodynamic cycle analysis was carried out to determine the optimum compositions and actual tests were performed in a laboratory heat pump test bench at the evaporation and condensation temperatures of 7.5 and $45.1^{\circ}C$ respectively. Test results show that the coefficient of performance (COP) of these mixtures is up to 5.7% higher than that of HCFC22. While propane showed 11.5% reduction in capacity, most of the fluids tested had the similar capacity to that of HCFC22. Compressor discharge temperatures were reduced by $11{\sim}17^{\circ}C$ with these fluids. There was no problem with mineral oil since the mixtures were mainly composed of hydrocarbons. The amount of charge was reduced up to 55% as compared to HCFC22. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for. residential air-conditioning and heat pumping application.

Keywords

References

  1. Montreal Protocol on Substances That Deplete the Ozone Layer, 1989, Final Act, United Nations Environment Programme
  2. CFC Focus, 1998, March, Korea Specially Chemical Industry Association
  3. ARI, 1992-1997, R22 and RS02 Alternative Refrigerants Program, US Air-Conditioning and Refrigeration Institue
  4. Didion, D. A, 1994, Private Commuication, US National Institute of Standards and Technology, Gaithersburg, MD
  5. Global Environmental Change Report, 1997, A Brief Analysis of the Kyoto Protocol, Vol. IX, No. 24, December
  6. Cox, N., 2004, Energy comparison of a ground source heat pump using hydrocarbon refrigerants, Prod. of the 6th IIR Gustav Lorentzen Natural Working Fluids Conference, Glasgow, UK
  7. Private communication with N. Cox at Earthcare Products, London, UK, 2004. 8
  8. Kruse, H., 1996, The stats of the art of the hydrocarbon technology in household refrigeration, Proc, of the Int. Conferences on Ozone Protection Technologies, Washington, DC, pp. 179-188
  9. Jung, D., Song, Y. and Park, B., 2000, Testing of propane/isobutane mixture in domestic refrigerators, Int. J. Refrigeration, Vol. 23, pp.517-527 https://doi.org/10.1016/S0140-7007(99)00084-5
  10. Mulroy, W., Kauffeld, M., McLinden, M. O. and Didion, D. A., 1988., Experimental evaluation of two refrigerant mixtures in a bread-board air conditioner, Proc, of Int. Inst. Refrigeration, Purdue Conference on CFCs, . Commissions B1, B2, E1 & E2, pp. 27-34
  11. Didion, D. A. and Bivens, D. B., 1990, Role of refrigerant mixtures as alternatives to CFCs, Int. J. Refrigeration, Vol. B, pp. 163-175
  12. Radermacher, R. and lung, D., 1993, Theoretical anlysis of replacement refrigerants for R22 for residential uses, ASHRAE Trans., Vol. 99, Part 1, pp.333-343
  13. McLinden, M. O., Klein, S, A., Lemmon, E. W. and Peskin, A. P., 1998, NIST Thermodynamics and Transport Properties of Refrigerants and Refrigerant Mixtures, REFPROP Version 6.0
  14. Maclaine-cross, I. L. and Leonardi., E., 1997, Why hydrocarbons save energy?, Australian AIRAH Journal, Vol. 51, pp.33-37