Synthesis and Visible Light Photocatalytic Activity of Nanocrystalline $TiO_2$-SrO Composite Powders

나노 결정립 $TiO_2$-SrO 복합분체의 합성과 가시광 광촉매 활성 평가

Han, Jae-Kil;Choi, Sung-Min;Hong, Won-Seok;Lee, Byong-Taek
한재길;최성민;홍원석;이병택

  • Published : 20070800

Abstract

Abstract: Nano-sized and homogeneously distributed TiOs-ZO, -40, -60wt% SrO composite powders were successfullysynthesized by a sol-gel method. The as-received amorphous Ti02-20wt% SrO composite powders were crystallized withanatase TiO; at around 750"C. As calcination temperatures increased, the anatase TiO; crystalline phase was transformed torutile TiO; at about 900"C, whereas nano-sized, squarish SrTi03 Phase was detected. The peaks obtained after calcining at1,050"C mainly exhibited the mtile TiO; and SrTiO? Phases. However, a small number of SrO; Peaks were also detected. Forthe comparison of photocatalytic activity depending on light sources, TiOU-SrO composite powders were tested in phenoldegradation. Ti02-60wt%Sr0 composite powder showed good visible light photoactivity for the photo-oxidation of phenol.(Received january 25, 2007)

Keywords

References

  1. A. Fujishima, T.N. Rao and D.A. Tryk, J. Photochem. Photobiol. C1, 1 (2000)
  2. S. Ruan, F. Wu, T. Zhang, W. Gao, B. Xu and M. Zhao, Mater. Chem. Phy. 69, 7 (2001) https://doi.org/10.1016/S0254-0584(00)00301-1
  3. V. Loddo, G. Marci, C. Martin, L. Palmisano, V. Rives and A. Sclafani, Appl. Catal. B20, 29 (1999)
  4. M. Hirano, K. Ota, O. Tanaike and M. Inagaki, J. Solid State Chem. 170,39 (2003) https://doi.org/10.1016/S0022-4596(02)00013-0
  5. C. Belver, R. Bellod, A. Fuerte and M. Femandez-Garcia, Appl. Catal. B65 301 (2006)
  6. C. H. Chang, Y. H. Shen, Mater. Lett. 60, 129 (2006) https://doi.org/10.1016/j.matlet.2005.08.005
  7. B. T Lee, J. K. Han, A. K. Gain, K. H. Lee and F. Saito, Mater. Left. 60, 2101 (2006) https://doi.org/10.1016/j.matlet.2005.12.102