Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Solvent Effect on the Hydrosilylation Reactions for the Synthesis of Polydimethylsiloxane Grafted with Polyoxyethylene Catalyzed by Speier's Catalyst

Chung, Dae-Won;Kim, Tae-Gil

  • Published : 20071100
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Abstract

Polydimethylsiloxane grafted with polyoxyethylene was synthesized through hydrosilylation reactions in the presence of Speier’s catalyst and the solvent effect was investigated. Among the five solvents studied, acetonitrile (ACN) showed extremely low reactivity; the reactivities increased in the order ACN

Keywords

References

  1. R. M. Hill, Specialist Surfactants, I. D. Robb Ed., Blackie, London (1997)
  2. G. Riess, G. Hurterz, and P. Bahadur, Encyclopedia of Polymer Science and Engineering, 2nd Edn., p. 324, Wiley, New York (1985)
  3. H. F. Fink, Tenside Surf. Det., 28, 5 (1991)
  4. J. L. Speier, Adv. Organomet. Chem., 17, 407 (1979)
  5. L. Sacarescu, R. Ardeleanu, G. Sacarescu, and M. Simionescu, Eur. Polym. J., 40, 57 (2004)
  6. H. F. Lamoreaux and N. Y. Schenectady, U. S. Patent 3, 220, 972 (1965)
  7. L. N. Lewis and C. A. Sumpter, J. Mol. Catal. Chem., 104, 293 (1996)
  8. G. Cai and W. P. Weber, Polymer, 45, 2941 (2004)
  9. E. Louis, I. Jussofie, F. E. Kuhn, and W. A. Herrmann, J. Org. Chem., 691, 2031 (2006)
  10. D.-W. Chung and T. K. Kim, J. Ind. Eng. Chem., 13, 571 (2007)
  11. S. S. Hou, Y. P. Chung, C. K. Chan, and P. L. Kuo, Polymer, 41, 3263 (2000)
  12. M. L. Vadala, M. Rutnakornpituk, M. A. Zalich, T. G. St Pierre, and J. S. Riffle, Polymer, 45, 7449 (2004)
  13. D. W. Chung, J. P. Kim, D. Kim, and J. Lim, J. Ind. Eng. Chem., 13, 783 (2006)
  14. B. Marciniec, J. Gulinski, W. Urbaniak, and Z. W. Kornetka, Comprehensive handbook on hydrosilylation, B. Marciniec Ed., pp. 42-43, Pergamon, Oxford (1992)
  15. N. Nagatani, K. Fukuda, and T. Suzuki, J. Colloid Interface Sci., 234, 337 (2001) https://doi.org/10.1006/jcis.2000.7235
  16. K. Takeuchi, K. Yoshino, Y. Suzuki, and A. Kawamata, J.P. Patent 4108795 (1992)
  17. T. Ganicz, U. Mizerska, M. Moszner, M. O. Brien, R. Perry, and W. A. Stanczyk, Appl. Catal. Gen., 259, 49 (2004)
  18. S. Feng and M. Cui, React. Funct. Polym., 45, 79 (2000)
  19. C. Iojoiu, M. J. Abadie, V. Harabagiu, and M. Pinteala, Eur. Polym. J., 36, 2115 (2000)
  20. S. Meth and C. N. Sukenik, Thin Solid Films, 425, 49 (2003)
  21. T. H. Ho and C. S. Wang, Eur. Polym. J., 37, 267 (2001) https://doi.org/10.1016/S0014-3057(00)00100-2
  22. K. M. Choi, Mater. Chem. Phys., 103, 176 (2007)
  23. S. T. Phan, W. C. Lim, J. S. Han, I. N. Jung, and B. R. Yoo, J. Organomet. Chem., 691, 604 (2006)
  24. J. J. Pesek and M. T. Matyska, J. Chrom., 887, 31 (2000)
  25. S. A. Bulgakova, L. M. Mazanova, V. V. Semenov, and Y. D. Semchikov, Eur. Polym. J., 43, 644 (2007)
  26. U. Senthilkumar and B. S. R. Reddy, J. Membr. Sci., 232, 73 (2004)