The effect of ionic strength and hardness of trichloroethylene-contaminated synthetic groundwater on remediation using granular activated carbon

Heo, Joong-Hyeok;Lee, Dal-Heui;Koh, Dong-Chan;Chang, Ho-Wan

  • Published : 20070900

Abstract

The objective of this study is to evaluate the effect ofionic strength and hardness of trichloroethylene (TCE)-contami-nated synthetic groundwater on remediation using granular acti-vated carbon (GAC). The TCE sorption rate onto GAC in syntheticgroundwater was observed by batch experiments and rangedfrom 86.2% to 100%. As the ionic strength and hardness of thesynthetic groundwater increased, the TCE sorption rates decreased.The sorption kinetics of the GAC were also analyzed by kineticmodels. The Elovich model was more successfully applicable to thesorption kinetics than the Pseudo-first-order model. During thesorption, a greater amount of cations in groundwater were adsorbedthan anions. The sorption capacity of GAC was affected by cationsin groundwater. The GAC surface area was 958.98 m2/g and thecalculated TCE and ions sorption areas were 318.38 m2/g, whichcomprised 33.2% of the GAC surface area. Our experimentsshowed that TCE remediation was influenced by the ionic strengthand hardness of groundwater. The results of these experimentswere confirmed by two different models and sorption areas.Therefore, the ionic strength and hardness of groundwater mustbe considered in the remediation of TCE-contaminated ground-water using GAC. Key words : Ionic strength, Hardness, TCE, Remediation, GAC

Keywords

References

  1. Ahmedna, M., Marshall, W.E. and Rao, R.M., 2005, Surface properties of granular activated carbons from agricultural by-products and their effects on raw sugar decolorization, Bioresource Technology, 71, 103-112
  2. Barton, C.S., Stewart, D.I., Morris, K. and Bryant, D.E., 2004, Performance of three resin-based materials for treating uranium-contaminated groundwater within a PRB, Journal of Hazardous Matererials B, 116, 191-204 https://doi.org/10.1016/j.jhazmat.2004.08.028
  3. Bjelopavlic, M., Newcombe, G. and Hayst, R., 1999, Adsorption of NOM onto activated carbon: effect of surface charge, ionic strength, and pore volume distribution, Journal of Colloid and Interface Science, 210, 271-280 https://doi.org/10.1006/jcis.1998.5975
  4. Chen, P.H., Jenq, C.H. and Chen, K.M., 1996, Evaluation of granular activated carbon for removal of trace organic compounds in drinking water, Environment International, 22, 343-359 https://doi.org/10.1016/0160-4120(96)00021-9
  5. Cheung, C.W., Porter, J.F. and McKay, G., 2000, Sorption kinetics for the removal of copper and zinc form effluents using bone char, Separation and Purification Technology, 19, 55-94 https://doi.org/10.1016/S1383-5866(99)00073-8
  6. Cheung, C.W., Porter, J.F. and McKay, G., 2001, Sorption kinetic analysis for the removal of cadmium ions form effluents using bone char, Water Research, 35, 605-612 https://doi.org/10.1016/S0043-1354(00)00306-7
  7. Choi Y.S., Chung, M.K. and Kim, J.G., 2004, Effects of cyclic stress and insulation on the corrosion fatigue properties of thermally insulated pipeline, Materials Sciences Engineering A, 384, 47-56 https://doi.org/10.1016/j.msea.2004.05.068
  8. Dastgheib, S.A. and Karanfil, T., 2005, The effect of the physical and chemical characteristics of activated carbons on the adsorption energy and affinity coefficient of dubinin equation, Journal of Colloid and Interface Science, 292, 312-321 https://doi.org/10.1016/j.jcis.2005.06.017
  9. Ferris, F.G., Phoenix, V., Fujita, Y. and Smith, R.W., 2003, Kinetics of calcite precipitation induced by ureolytic bacteria at 10 to 20 $^{\circ}$C in artificial groundwater, Geochimca et Cosmochimica Acta, 67, 1701-1722
  10. Gullon, I.M., Lozar, J.P., Amoros, D.C. and Solano, A.L., 2004, Analysis of the microporosity shrinkage upon thermal post-treatment of $H_3PO_4$ activated carbon, Carbon, 42, 1339-1343 https://doi.org/10.1016/j.carbon.2004.01.018
  11. Ho, Y.S. and Mckay, G., 1999, The sorption of lead (Π) ions on peat, Water Research, 33, 578-584 https://doi.org/10.1016/S0043-1354(98)00207-3
  12. Jan, Y.L., Tsai, S.C., Cheng, H.P. and Hsu, C.N., 2004, Evaluation of buffer materials by associating engineering and sorption properties, Applied Radiation and Isotopes, 61, 1663-1172
  13. Kadirvelu, K., Kavipriya, M., Karthika, C., Radhika, M., Vennilamani, N. and Pattabhi, S., 2003, Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions, Bioresource Technology, 87, 129-132 https://doi.org/10.1016/S0960-8524(02)00201-8
  14. Kilduff, J.E. and Karanfil, T., 2002, Trichloroethylene adsorption by activated carbon preloaded with humic substance: effects of solution chemistry, Water Research, 36, 1685-1698 https://doi.org/10.1016/S0043-1354(01)00381-5
  15. Kim, E.S., Lee, D.H., Yum, B.W. and Chang, H.W., 2005, The effect of ionic strength and hardness of water on the non-ionic surfactant- enhanced remediation of perchloroethylene contamination, Journal of Hazardous Materials, 119, 195-203 https://doi.org/10.1016/j.jhazmat.2004.12.015
  16. Kock, F.P. and Deventer, J.S.J., 1995, Stochastic model for equilibrium adsorption onto activated carbon, Chemical Engineering Journal, 59, 205-220
  17. Korean Standards Association, 2003, Test method for activated carbon, KS M 1802, 1-18
  18. Korean Standards Association, 2004, Test method for activated carbon, KS M 1421, 1-3
  19. Kuran, P. and Sojak, L., 1996, Environmental analysis of volatile organic compounds in water and sediment by gas chromatography, Journal of Chromatography A 733, 119-141 https://doi.org/10.1016/0021-9673(95)01121-8
  20. Lagergren, S., 1898, About the theory of so-called adsorption of soluble substance, Kungliga Svenska Vetenskapsakademiens, 1-39
  21. Lee, J.W., Shin, W.G. and Moon, H., 2004, Adsorption equilibrium and kinetic for capillary condensation of trichloroethylene on MCM-41 and MCM-48, Microporous and Mesoporous Materials, 73, 109-119 https://doi.org/10.1016/j.micromeso.2004.04.020
  22. Lee, Y.W., Kim, H.J., Park, J.W., Choi, B.U., Choi, D.K. and Park, J.W., 2003, Adsorption and reaction behavior for the simultaneous adsorption of NO-$NO_2$ and $SO_2$ on activated carbon impregnated KOH, Carbon, 41, 1881-1888 https://doi.org/10.1016/S0008-6223(03)00105-2
  23. Li, L., Quinlivan, P.A. and Knappe, D.R.U., 2002, Effects of activated carbon surface and pore structure on the adsorption of organic contaminants from aqueous solution, Carbon, 40, 2085- 2100 https://doi.org/10.1016/S0008-6223(02)00069-6
  24. Lim, J.L. and Shin, H.S., 1995, Treatment of trichloroethylene using cometabolism of immobilized microorganism, Journal of Korean Society of Environmental Engineers, 17, 1079-1088
  25. Ministry of Environment Republic of Korea, 2005, 2005 Environmental statistic yearbook, 18, 314-315
  26. Mishra, S.P., Singh, V.K. and Tiwari, D., 1996, Radiotracer technique in adsorption study: part XIV. effective removal of mercury from aqueous solution by hydrous zirconium oxide, Applied Radiation and Isotopes, 47, 15-21 https://doi.org/10.1016/0969-8043(95)00260-X
  27. Miyake, Y., Sakoda, A., Yamanashi, H., Kaneda, H. and Suzuki, M., 2003, Activated carbon adsorption of trichloroethylene (TCE) vapor stripped from TCE-contaminated water, Water Research, 37, 1852-1858 https://doi.org/10.1016/S0043-1354(02)00564-X
  28. Moslemy, P., Neufeld, R.J., Millette, D. and Guiot, S.R., 2003, Transport of gellan gum microbeads through sand: an experimental evaluation for encapsulated cell bioaugmentation, Journal of Environmental Management, 69, 249-259 https://doi.org/10.1016/j.jenvman.2003.09.003
  29. Park, S.J. and Kim, Y.M., 2004, Influence of anodic treatment on heavy metal ion removal by activated carbon fibers, Journal of Colloid and Interface Science, 278, 276-281 https://doi.org/10.1016/j.jcis.2004.06.004
  30. Park, S.J., Shin, J.S., Shim, J.W. and Ryu, S.K., 2004, Effect of acidic treatment on metal adsorptions of pitch-based activated carbon fibers, Journal of Colloid and Interface Science, 275, 342-344 https://doi.org/10.1016/j.jcis.2004.01.010
  31. Peng, J. and Wan, A., 1997, Effect of ionic strength on Henry's constants of volatile organic compounds, Chemosphere, 36, 2731-2740 https://doi.org/10.1016/S0045-6535(97)10232-6
  32. Pelekani, C. and Snoeyink, V.L., 1999, Competitive adsorption in natural water: Role of activated carbon pore size, Water Research, 33, 1209-1219 https://doi.org/10.1016/S0043-1354(98)00329-7
  33. Quinlivan, P.A., Li, L. and Knappe D.R.U., 2005, Effects of activated carbon characteristics on the simultaneous adsorption of aqueous organic micropollutants and natural organic matter, Water Research, 39, 1663-1673 https://doi.org/10.1016/j.watres.2005.01.029
  34. Ramon, V.L., Castilla, C.M., Utrilla, J.R. and Radovic, L.R., 2002, Ionic strength effects in aqueous phase adsorption of metal ions on activated carbons, Letters to the editor/Carbon, 41, 2009-2025
  35. Sakoda, A., Kawazoe, K. and Suzuki, M., 1986, Adsorption of triand tetrachloroethylene from aqueous solution on activated carbon fibers, Water Research, 21, 717-722 https://doi.org/10.1016/0043-1354(87)90084-4
  36. Shih, T.C., Wangpaichitr, M. and Suffet, M., 2003, Evaluation on granular activated carbon technology for the methyl tertiary butyl ether (MTBE) from drinking water, Water Research, 37, 375-385 https://doi.org/10.1016/S0043-1354(02)00271-3
  37. Soeyink, V.L. and Jenkins, D., 1980, Water chemistry, Wiley, 58p.
  38. Tole C.A., Marshall W.E. and Johns M.M., 1997, Granular activated carbons from nutshells for the uptake of metals and organic compounds, Carbon, 35, 1407-1414 https://doi.org/10.1016/S0008-6223(97)00073-0
  39. Vejsada, J., Jelinnek, E., Randa, Z., Hradil, D. and Prikryl, R., 2005, Sorption of cesium on smectite-rich clays from the Bohemian massif and their mixtures with sand, Applied Radiation and Isotopes, 62, 91-96 https://doi.org/10.1016/j.apradiso.2004.05.075
  40. Wu, J., Claesson, O., Fangmark, I. and Hammarstrom, L.G., 2005, A systematic investigation of the overall rate coefficient in the wheeler-jonas equation for adsorption on dry activated carbons, Carbon, 43, 481-490 https://doi.org/10.1016/j.carbon.2004.09.024
  41. Wu, S.H. and Pendleton, P., 2001, Adsorption of anionic surfactant by activated carbon: Effect of surface chemistry, ionic strength, and hydrophobicity, Journal of Colloid and Interface Science, 243, 306-315 https://doi.org/10.1006/jcis.2001.7905