Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Electrochemical Performance of Tricredyl Phosphate and Trispentafluorophenly Phosphine as Flame Retardant Additives for Lithium-ion Batteries

리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성

  • 안세영 (한국전기연구원 전지연구그룹) ;
  • 김기택 (한국전기연구원 전지연구그룹) ;
  • 김현수 (한국전기연구원 전지연구그룹) ;
  • 남상용 (경상대학교 고분자공학과 나노규브 사업단)
  • Published : 2007.09.01
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Abstract

Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.

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References

  1. J. S. Hong, H. Maleki, S. Al Hallaj, L. Reddy, and J. R. Selman, 'Electrochemical-calorimetric studies of lithium-ion cells', J. Electrochem. Soc., Vol. 145, p. 1469, 1998 https://doi.org/10.1149/1.1838506
  2. S. Tobishima and J. Yamaki, 'A consideration of lithium cell safety', J. Power Sources, Vol. 81-82, p. 882, 1999
  3. C. W. Lee, R. Venkatachalapathy, and J. Prakash, 'A novel flame-retardant additive for lithium batteries', Electrochem. Solid-State Letters, Vol. 3, No. 2, p. 63, 2000
  4. X. Wang, E. Yasukawa, and S. Kasuya, 'Nonflammable trimethul phosphate solvent-containing electrolytes for lithium-ion batteries', J. Electrochem. Soc., Vol. 148, No. 10, p. A1058, 2001 https://doi.org/10.1149/1.1397773
  5. Y. E. Hyung, D. R. Vissers, and K. Amine, 'Flame-retardant additives for lithium-ion batteries', J. Power Sources, Vol. 119-121, p. 383, 2003 https://doi.org/10.1016/S0378-7753(03)00225-8
  6. Q. Wang, J. Sun, X. Yao, and C. Chen, '4-isopropyl phenyl diphenyl phosphate as flame-retardant additive for lithium-ion battery electrolyte', Electrochem. and Solid-State Letters, Vol. 8, No. 9, p. A467, 2005 https://doi.org/10.1149/1.1993389
  7. K. Xu, M. S. Ding, S. Zhang, J. L. Allen, and T. R. Jow, 'Evaluation of fluorinated alkyl phosphates as flame retardants in electrolytes for Ii-ion batteries', J. Electrochem. Soc., Vol. 150, No. 2, p. A161, 2003 https://doi.org/10.1149/1.1533040
  8. D. D. MacNail and J. R. Dahn, 'The reaction of charged cathodes with nonaqueous solvents and electrolytes', J. Electrochem. Soc., Vol. 148, p. A1205, 2001 https://doi.org/10.1149/1.1407245
  9. D. D. MacNail and J. R. Dahn, 'The reactions of $Li_{0.5}CoO_{2}$ with nonaqueous solvents at elevated temperatures', J. Electrochem. Soc., Vol. 149, p. A912, 2002 https://doi.org/10.1149/1.1483865
  10. S. S. Zhang, K. Xu, and T. R. Jow, 'Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolyte in Li-ion batteries', J. Power Sources, Vol. 113, p. 166, 2003 https://doi.org/10.1016/S0378-7753(02)00537-2
  11. 공명철, 김현수, 김기택, 구할본, '리튬이온전지용 정극활물질 $LiNi_{0.4}Mn_{0.3)CO_{0.3}O_{2}$의 전기화학적 특성', 전기전자재료학회논문지, 19권, 7호, p. 650, 2006 https://doi.org/10.4313/JKEM.2006.19.7.650
  12. D. H. D., E. P. Roth, C. C. Crafts, G. Nagasubramamian, G. Henriksen, and K. Amine, 'Effects of additives in thermal stability of Li ion cells', J. Power Sources, Vol. 146, p. 116, 2005 https://doi.org/10.1016/j.jpowsour.2005.03.170
  13. E. P. Roth, 'Thermal characterization of Ii-ion cells using calorimetric techniques', Proceedings of the intersociety Energy Conversion Engineering Conference 2, p. 962, 2000
  14. T. Kashiwag, J. W. Gilman, K. M. Butler, R. H. Harrier, J. R. Shields, and A. Asano, 'Flame retardant mechanism of silica gel/silica', Fire Mater., Vol. 24, p. 277, 2000 https://doi.org/10.1002/1099-1018(200011/12)24:6<277::AID-FAM746>3.0.CO;2-A