A Study on the Injection Characteristics of Urea Solution to Improve deNOx Performance of Urea-SCR Catalyst in a Heavy Duty Diesel Engine

대형 디젤 엔진용 요소분사 SCR촉매의 deNOx 성능향상을 위한 요소수용액의 분사특성 연구

  • Jeong, Soo-Jin (Advanced Power & IT Research Center, Korea Automotive Technology Institute) ;
  • Lee, Chun-Hwan (Environmental Parts R & D Center, Korea Automotive Technology Institute)
  • 정수진 (자동차부품연구원 첨단동력/IT 종합연구센터) ;
  • 이천환 (자동차부품연구원 환경부품연구센터)
  • Published : 2008.07.01

Abstract

Urea-SCR, the selective catalytic reduction using urea as reducing agent, has been investigated for about 10 years in detail and today is a well established technique for deNOx of stationary diesel engines. In the case of the SCR-catalyst a non-uniform velocity and $NH_3$ profile will cause an inhomogeneous conversion of the reducing agent $NH_3$, resulting in a local breakthrough of $NH_3$ or increasing NOx emissions. Therefore, this work investigates the effect of flow and $NH_3$ non-uniformities on the deNOx performance and $NH_3$ slip in a Urea-SCR exhaust system. From the results of this study, it is found that flow and $NH_3$ distribution within SCR monolith is strongly related with deNOx performance of SCR catalyst. It is also found that multi-hole injector shows better $NH_3$ uniformity at the face of SCR monolith face than one hole injector.

Keywords

References

  1. R. Shinozaki, Y. Takeda, H. Jyoutaki, S. Saito and A. Suzuki, "Development of Urea-SCR System for Commercial Vehicle-Basic Characteristics and Improvement of NOx Conversion at Low Load Operation," SAE 2003-01-3248, 2003
  2. M. D. Patil, P. Spurk, P. Floerchinger, J. Gieshoff, M. Pfeifer and C. Winkler, "Modeling of SCR deNOx Catalyst -Looking at the Impact of Substrate Attributes," SAE 2003-01-0845, 2003
  3. M. Ueda, A. Asano, T. Kondo, Y. Watanabe, T. Fukuma and Y. Harada, "A New Optimizing Technique of a Diesel Engine Aftertreatment System using HC deNOx Catalyst," JSAE Review, Vol.24, pp.47-51, 2003 https://doi.org/10.1016/S0389-4304(02)00249-7
  4. S.-J. Jeong, S.-J. Lee, W.-S. Kim and C. Lee, "Simulation on the Optimum Shape and Location of Urea Injector for Urea-SCR System of Heavy-Duty Diesel Engine to Prevent $NH_3$ Slip," SAE 2005-01-3886, 2005
  5. S.-J. Jeong, S.-J. Lee, W.-S. Kim and C. Lee, "Numerical Study on the Injector Shape and Location of Urea-SCR System of Heavy-duty Diesel Engine for Preventing $NH_3$ Slip," Transactions of KSAE, Vol.14, No.1, pp.68-78, 2006
  6. H. Weltens, H. Bressler, F. Terres, H. Neumaier and D. Rammoser, "Optimisation of Catalytic Converter Gas Flow Distribution by CFD Prediction," SAE 930708, 1993
  7. X. Zhang, M. Romzek and C. Morgan, "3-D Numerical Study of Mixing Characteristics of NH3 in front of SCR," SAE 2006-01-3444, 2006
  8. STAR-CD Ver.3.24 Manual, Computational Fluid Dynamics Ltd., 2005
  9. M. A. Cremer, E. Eddings, T. Martz, L. J. Muzio, Q. Quartucy, R. Hardman, J. Cox and J. Stallings, "Assessment of SNCR Performance on Large Cole-fired Utility Boilers," 1998 DOE Conference on SCR and SNCR for NOx Control, Pittsburg, PA, 1998
  10. M. Koebel, M. Elsener and M. Kleemann, "Urea-SCR: a promising technique to reduce NOx emissions from automotive diesel engines," Catalyst Today, Vol.59, pp.335-345, 2000 https://doi.org/10.1016/S0920-5861(00)00299-6
  11. H. L. Fang and H. F. M. DaCosta, "Urea thermolysis NOx reduction with and without SCR catalysts," Applied Catalysis B: Environmental, Vol.46, pp.17-34, 2003 https://doi.org/10.1016/S0926-3373(03)00177-2
  12. Y. Qiu and L. Gao, "Blue-emitting Syanuric Acid-melamine Complexes from Urea Thermolysis," Materials Research Bulletin, Vol.40, pp.794-799, 2005 https://doi.org/10.1016/j.materresbull.2005.02.003
  13. J. Oh, J. Seo, K. Lee, J. Park, Y. Choi and J. Lee, "Visualization of Urea Mixing Characteristics by Mixer and Diffuser in SCR System," Spring Conference Proceedings, KSAE, pp.326-332, 2007
  14. J. C. Wurzenberger and R. Wanker, "Multi- Scale SCR Modeling, 1D Kinetic Analysis and 3D System Simulation," SAE 2005-01-0948, 2005