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Synthesis and Evaluation of N-(2,3-dihydroxypropyl)-N,N-dimethyldodecane-1-amine chloride

N-(2,3-dihydroxypropyl)-N,N-dimethyldodecane-1-amine chloride의 합성과 평가

  • 조완구 (전주대학교 대체의학대학 건강자원학부) ;
  • 최정진 (LG 생활건강 기술연구원)
  • Published : 2008.03.31

Abstract

In general, anionic and cationic surfactants are incompatible because their mixtures form insoluble complexes. There are, however, some complexes that are soluble and behave like regular surfactants, specifically like nonionic surfactants, thus named pseudo-nonionic surfactant complexes. Pseudo-nonionic complexes are more effective and efficient than their ionic surfactant components as shown by their equilibrium and dynamic surface tensions and interfacial tensions. They pack at the interface more than their ionic components. Since, pseudo-nonionic complexes show their own characteristics, they can be treated as separate classes of surfactants distinct from ionic and nonionic surfactants. Novel cationic surfactant was synthesized, having the polyhydroxyl group at the head group. We found that aqueous mixtures of our cationic surfactant and usual anionic surfactant(SDS) could form homogeneous solutions even at high concentration. The properties of mixed surfactant solutions were measured. Foam stability, CMC(critical micelle concentration), water hardness tolerance and thickening effect were tested. The foam stability of mixed surfactants was very good and various synergy effects were observed.

Keywords

References

  1. C. Chorro, M. Chorro, O. Dolladille, S. Partyka, and R. Zana, Adsorption of Dimeric(Gemini) Surfactants at the Aqueous Solution/Silica Interface, J. of Colloid and Interface Sci., 199(2), 169 (1998) https://doi.org/10.1006/jcis.1997.5341
  2. M. J. Rosen and L. D. Song, Dynamic Surface Tension of Aqueous Surfactant Solutions: Effect of Spacer on Dynamic Properties of Gemini Surfactant Solutions, J. of Colloid and Interface Sci., 179(1), 261 (1996) https://doi.org/10.1006/jcis.1996.0212
  3. L. Liu and M. J. Rosen, The Interaction of Some Novel Aiquaternary Gemini Surfactants with Anionic Surfactants, J. of Colloid and Interface Sci., 179(2), 454 (1996) https://doi.org/10.1006/jcis.1996.0237
  4. T. J. Taylor and A. F. Richter, Germicidal Liquid Laundry Detergent Compositions, U.S. Patent, 5,798,329(1998)
  5. A. M. Vogel, J. C. Severns, and E. H. Wahl, Fabric Softening Compositions Containing Mixtures of Softener Material and Highly Ethoxylated Curd Dispersant, U.S. Patent, 5,368,756(1993)
  6. L. E. Paszek and B. Gebbia, Liquid Disinfectant Laundry Detergents, U.S. Patent, 4,576,729(1986)
  7. K. A. Harrison and J. M. Weller, Stable, Isotropic Liquid Laundry Detergents, U.S. Patent, 4,810,409(1989)
  8. R. M. Wise and T. A. Cripe, Light-duty Liquid or Gel Dishwashing Detergent Composition Containing an Alkyl Ethoxy Carboxylate Surfactant, U.S. Patent, 5,230,823(1993)
  9. T. Sagoh, K. Toshima, K. Kawada and S. Matsumura, Enzymatic Synthesis of Surface Active and Biodegradable Glucosaminide Fatty Acid Esters, J. of Oleo. Sci., 52(11), 597 (2003) https://doi.org/10.5650/jos.52.597
  10. W. D. Harkins and H. F. Jordan, A Method for the Determination of Surface and Interfacial Tension from the Maximum Pull on a Ring, J. Am. Chem. Soc., 52(5), 1751 (1930) https://doi.org/10.1021/ja01368a004
  11. W. G. Cho, Measurement of Forces between Liquid Surfaces and Emulson Stability, PhD Thesis, University of Hull, UK (1997
  12. K. Ogino and M. Abe. "Mixed Surfactant Systems". Surfactant Science Series vol. 46, p. 55, Marcel Dekker, Inc. (1993)