Preparation and characterization of Pt-supported porous graphite nanofibers

Kim, Byoung-Joo;Lee, Young-Seak;Park, Soo-Jin

  • Published : 20081100

Abstract

In this work, porous graphite nanofibers (PGNFs) were manufactured as promising catalyst supporter by a physical activation method for direct methanol fuel cells, and Pt nanoparticles were loaded on the PGNFs in order to prepare electrode materials by a chemical reduction method. The pore structures of the Pt/PGNFs were analyzed by N2 adsorption isotherms at 77 K. Electrocatalytic activities of final products were investigated by voltammetry and conductivity measurements in a 1.0 M CH3OH/0.5 M H2SO4. As a result, electrocatalytic activities of Pt/PGNFs were increased in the presence of Pt particles on the PGNFs and with increasing the specific surface area of the carbons.

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References

  1. R.C. Bansal, M. Goyal, Activated Carbon Adsorption, Taylor & Francis, Boca Raton, 2005
  2. D.D. Do, Adsorption Analysis: Equilibrium and Kinetics, Imperial College Press, London, 1998
  3. A. Oberlin, M. Endo, J. Cryst. Growth 32 (1976) 335 https://doi.org/10.1016/0022-0248(76)90115-9
  4. M.K. Seo, S.J. Park, S.K. Lee, J. Colloid Interf. Sci. 285 (2005) 306 https://doi.org/10.1016/j.jcis.2004.10.068
  5. B.J. Kim, S.J. Park, Nanotechnology 17 (2006) 4395 https://doi.org/10.1088/0957-4484/17/17/018
  6. S. Brunauer, P.H. Emmett, E. Teller, J. Am. Chem. Soc. 60 (1938) 309 https://doi.org/10.1021/ja01269a023
  7. M.M. Dubinin, G.M. Plavnik, Carbon 6 (1968) 183 https://doi.org/10.1016/0008-6223(68)90302-3
  8. E.P. Barret, P.B. Joyner, P. Halenda, J. Am. Chem. Soc. 73 (1951) 373 https://doi.org/10.1021/ja01145a126
  9. S. Kim, S.J. Park, J. Power Sources 159 (2006) 42 https://doi.org/10.1016/j.jpowsour.2006.04.041
  10. S.A. Lee, K.W. Park, B.K. Kwon, Y.E. Sung, J. Ind. Eng. Chem. 9 (2003) 63 https://doi.org/10.1021/ie50085a024