Journal of Korea Society of Waste Management (한국폐기물자원순환학회지)

Korea Society of Waste Management (한국폐기물자원순환학회)
권호 표지

Adsorption of Copper(II) by Ferric Hydroxide in Coal Mine Drainage Sludge: Equilibrium and Kinetics Modeling

탄광배수슬러지를 이용한 산성광산배수 중의 Cu(II) 흡착: 흡착평형 및 흡착속도 모델링

Kweon, Bo-Youn;Cui, Ming-Can;Lim, Jung-Hyun;Jang, Min;Shim, Yon-Sik;Khim, Jee-Hyeong
권보연;최명찬;임정현;장민;신연식;김지형

  • Published : 20081200
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Abstract

This study investigates low-cost sorbent as replacements for current costly methods of removing heavy metals from AMD (acid mine drainage).This investigation explores the coal mine drain sludge, which is a by-product of AMD of Na-Jeon Mine. The coal drain sludge, which contains 64.7% ferric oxide (Fe2O3) as mainly component, was utilized as an adsorption for Cu(II) removal from aqueous solution. The equilibrium and kinetics adsorption was investigated during series of batch adsorption experiments. Langmuir and Freundlich models were used to fit the equilibrium data and Langmuir isotherm was fitted better. The removal efficiency was affected by pH, temperature, initial ion concentration, quantity of adsorbent and contact time. Two simple kinetic model, pseudo-first - and second -order, were used to investigate the adsorption mechanism. The pseudo- first -order reaction kinetics provides the best correlation with the experimental data. As the activation energy was 51.0 kJ mol-1 at pH 5.9, the adsorption of Cu(II) onto coal mine drainage sludge was by chemisorption

Keywords

References

  1. 양재규, 이남희, 이승목 : pH를 달리하여 제조한 3가 철 첨착 활성탄에 의한 구리 제거특성 평가, 대한환경공학회지, Vol. 30, No. 6, pp. 345-351 (2008)
  2. Namasivayam, C., Ranganathan, K. : Removal of Cd(II) from wastewater by adsorption on "waste" Fe(III)/Cr(III) hydroxide, Water Research, Vol. 29, No. 7, pp. 1737-1744 (1995) https://doi.org/10.1016/0043-1354(94)00320-7
  3. 이재영, 박유리 : 산성광산배수 처리를 위한 폐철 박 편의 재활용 가능성에 관한 연구, 한국폐기물학회지, Vol. 23, No. 6, pp. 502-507 (2006)
  4. 도남영, 이승래 : 혼합흡착-연속추출법을 이용한 자 연 점토의 납, 구리,아연,카드뮴 흡착시 온도의 영향, 한국지반환경공학회, Vol. 2, No. 3, pp. 17-35 (2001)
  5. Nita, S., Lee, Y. J., Huifang, X., Mark, C. and Gaillard, J. F. : Role of Fe(II) and phosphate in arsenic uptake by coprecipitation, Geochimica et Cosmochimica Acta, Vol. 71, pp. 3193-3210 (2007) https://doi.org/10.1016/j.gca.2007.04.008
  6. Ozcan, A. S., Erdem, B. and Ozcan, A. : Adsorption of Acisd Blue 193 from aqueous solution onto Nabentonite and DTMA-bentonite, Journal of Colloid and Interface Science, Vol. 280, pp. 44-54 (2004) https://doi.org/10.1016/j.jcis.2004.07.035
  7. 최정찬 : 인회석 및 생선뼈를 이용한 일광광산 AMD 처리 현장 실험, 자원환경지질, Vol. 38, No. 5, pp. 563-570 (2005)
  8. Ho, Y. S. and McKay, G. : Sorption of dye from aqueous solution by pit, Chemical Engineering Journal, Vol. 70, pp. 115-124 (1998) https://doi.org/10.1016/S0923-0467(98)00076-1
  9. Rodda, D. P., Wells, J. D. and Johnson, B. B. : Anomalous adsorption of Copper(II) on goethite, Journal of Colloid and Interface Science, Vol. 184, pp. 564-569 (1996a) https://doi.org/10.1006/jcis.1996.0652
  10. Pimentel, P. M., Melo, M. A. F., Melo, D. M. A., Assunao, A. L. C., Henrique, D. M., Silva, C. N. and Gonzalez, G. : Kinetics and thermodynamics of Cu(II) adsorption on oil shale wastes, Fuel Processing Technalogy, Vol. 89, pp. 62-67 (2008) https://doi.org/10.1016/j.fuproc.2007.07.003
  11. Huang, Y. H., Hsueh, C. L., Cheng, H. P., Su, L. C. and Chen, C. Y. : Thermodynamics and kinetics of adsorption of Cu(II) onto waste iron oxide, Journal of Hazardous Materials, Vol. 144, pp. 406-411 (2007) https://doi.org/10.1016/j.jhazmat.2006.10.061
  12. Krishna, G. B. and Susmita, S. G. : Influence of acid activation on adsorption of Ni(II) and Cu(II) on kaolinite and montmorillonite, Chemical Engineering Journal, Vol. 136, pp. 1-13 (2008) https://doi.org/10.1016/j.cej.2007.03.005
  13. Wu, C. H. : Adsorption of reactive dye onto carbon nanotubes, Journal of Hazardous Materials, Vol. 144, pp. 93-100 (2007) https://doi.org/10.1016/j.jhazmat.2006.09.083
  14. Unuabonah, E. I., Adebowale, K. O. and Olu- Owolabi, B. I. : Kinetic and thermodynamic studies of the sorption of lead(II) ions onto phosphatemodified kaolinite clay, Journal of Hazardous Materials, ol. 144, pp. 386-395 (2007) https://doi.org/10.1016/j.jhazmat.2006.10.046