DOI QR코드

DOI QR Code

Piezoelectric and Dielectric Properties of Low Temperature Sintering Pb(Zn1/2W1/2)O3-Pb(Mn1/2Nb2/3)O3-Pb(Zr0.48Ti0.52)O3 Ceramics Manufactured by Post-annealing Method

Post-annealing 방법으로 제작된 저온소결 Pb(Zn1/2W1/2)O3-Pb(Mn1/2Nb2/3)O3-Pb(Zr0.48Ti0.52)O3 세라믹의 압전 및 유전특성

  • Published : 2008.03.01

Abstract

In this study, in order to improve the electrical properties of low temperature sintering piezoelectric ceramics, $[0.05Pb(Zn_{1/2}W_{1/2})-0.07Pb(Mn_{1/3}Nb_{2/3})-0.088Pb(Zr_{0.48}Ti_{0.52})]O_3$(abbreviated as PZW-PMN-PZT) ceramic systems were fabricated using $Bi_2O_3$, CuO and $Li_2CO_3$ as sintering aids and then their piezoelectric and dielectric properties were investigated according to the amount of $Li_2CO_3$ and post-annealing process. Post-annealing process enhanced all physical properties except for mechanical quality factor (Qm). 0.2 wt% $Li_2CO_3$ added and post-annealed specimen showed the excellent values suitable for low loss piezoelectric actuator application as follow: the density = 7.86 $g/cm^3$ electromechanical coupling factor (kp) = 0.575, piezoelectric constant $d_{33}$ = 370 pC/N, dielectric constant ($\varepsilon_r$) = 1546, and mechanical quality factor (Qm) = 1161, respectively.

Keywords

References

  1. T. Sashida and T. Kenjo, "An Imtorduction to Ultrasonic Motors", Oxford, Clatendon Press, 1993
  2. S. Ueha, Y. Tomikawa, M. Kurosawa, and N. Nakamura, "Ultrasonic Motors ; Theory and Applications", Oxford, Clarendon Press, 1993
  3. 박창엽, "압전세라믹스", 김영사, p. 101, 1987
  4. 류주현, 이상호, 백동수, "$Pb(Ni_{1/3}Nb_{2/3})O_3$ 치환 에 따른 저온소결 $Pb(Mn_{1/3}Nb_{2/3})O_3-Pb(Ni_{1/3} Nb_{2/3})O_3-Pb(Zr_{1/2}Ti_{1/2})O_3$ 세라믹스의 압전 및 유전특성", 전기전자재료학회논문지, 19권, 1호, p. 35, 2006. https://doi.org/10.4313/JKEM.2006.19.1.035
  5. Y. Sato, L. Li, and Z. Gui, "Modified cofiring behaviors between PMN-PNN-PZT piezoelectric ceramics and PZT-doped 70Ag-30Pd alloy metallization", Mat. Sci. Eng., Vol. A326, p. 202, 2007
  6. 정광현, 이덕출, 류주현, "소결조제 변화에 따 른 PCW-PMN-PZT 세라믹스의 저온소결 및 압전특성", 전기전자재료학회논문지, 17권, 12 호, p. 1320, 2004
  7. 류주현, 이현석, 정광현, "$Pb(Mg_{1/2}W_{1/2})O_3$ 치환 에 따른 저온소결 $Pb(Mg_{1/2}W_{1/2})O_3-Pb(Mn_{1/3} Nb_{2/3})O_3-Pb(Zr_{1/2}Ti_{1/2})O_3$ 세라믹스의 압전 및 유전특성", 전기전자재료학회논문지, 19권, 5호, p. 417, 2006 https://doi.org/10.4313/JKEM.2006.19.5.417
  8. J. H. Yoo, K. H. Yoon, Y. W. Lee, S. S. Suh, J. S. Kim, and C. S. Yoo, "Electrical characteristics of the contour-mode piezoelectric transformer with ring/dot electrode area ratio", Jpn. J. Appl. Phys., Vol. 39A, No. 5A, p. 2680, 2000