Effect of Water-back-flushing Time and Period in Advanced Water Treatment System by Ceramic Microfiltration

세라믹 정밀여과에 의한 고도정수처리 시스템에서 물 역세척 시간 및 주기의 영향

  • Park, Jin-Yong (Department of Environmental Sciences & Biotechnology, Hallym University) ;
  • Lee, Hyuk-Chan (Department of Environmental Sciences & Biotechnology, Hallym University) ;
  • Cho, Jae-Hyeong (Department of Environmental Sciences & Biotechnology, Hallym University)
  • 박진용 (한림대학교 환경생명공학과) ;
  • 이혁찬 (한림대학교 환경생명공학과) ;
  • 조재형 (한림대학교 환경생명공학과)
  • Published : 2008.03.30

Abstract

In this study, periodic water-back-flushing using permeate water was performed to minimize membrane fouling and to enhance permeate flux in advanced water treatment system by ceramic microfiltration. We investigated effect of water-back-flushing period (FT) and time (BT), and tried to find the optimal operating conditions. BT was fixed at 3 sec and FT was changed in $30{\sim}120$ sec to inspect effect of FT. Also, FT was fixed at 120 sec and BT was changed as $3{\sim}12$ sec at experiment of BT effect. At both two experiments, TMP was fixed at 1.52 bar, water-back-flushing pressure at 0.98 bar, feed flow rate at 0.5 L/min, and feed water temperature at $20^{\circ}C$. As the result, optimal FT was 30 sec at fixed BT 3 sec in our experimental range. It means that the more frequent back-flushing was the more effective to reduce membrane fouling. However, there were not large effects of FT due to a short BT. Then, increasing BT at fixed FT 120 sec could decrease resistance of membrane fouling ($R_f$) and increase permeate flux (J) and dimensionless permeate flux ($J/J_o$), and the most total permeate volume ($V_T$) could be produced at the maximum BT 12 sec.

본 연구에서 처리수를 이용한 주기적인 역세척은 세라믹 정밀여과에 의한 고도정수처리 시스템에서 막오염을 저감하고 투과선속을 향상시키고자 수행되었으며, 물 역세척 주기(FT) 및 시간(BT)의 영향과 최적 운전조건을 규명하고자 하였다. FT의 영향을 알아보기 위해 일정한 BT 3초에서 FT를 $30{\sim}120$초로 변화시켰고, BT 영향 실험에서 일정한 FT 120초에서 BT를 $3{\sim}12$초로 변화시켰다. 그리고 다른 운전변수인 막간압력차는 1.52 bar, 물 역세척 압력 0.98 bar, 유입유량 0.5 L/min, 공급액의 온도 $20^{\circ}C$로 일정하게 유지하였다. 그 결과, 일정한 BT 3초에서 본 실험 범위의 최적 FT는 30초로, 이것은 빈번한 역세척이 막오염의 저감에 더 효과적임을 의미한다. 그러나 너무 짧은 BT로 인하여 FT의 영향은 크지 않았다. 한편, 일정한 FT 120초에서 BT가 증가함에 따라 막오염에 의한 저항($R_f$)은 감소하고 투과선속(J)과 무차원화한 투과선속 ($J/J_o$)은 증가하는 경향을 나타내어, 최대 BT인 12초에서 가장 많은 총여과부피($V_T$)를 얻을 수 있었다.

Keywords

References

  1. T. Leiknes, H. Odegaard, and H. Myklebust, 'Removal of natural organic matter (NOM) in drinking water treatment by coagulation-microfiltration using metal membranes', J. Membr. Sci., 242, 47 (2004) https://doi.org/10.1016/j.memsci.2004.05.010
  2. J. I. Oha and S. H. Lee, 'Influence of streaming potential on flux decline of microfiltration with in-line rapid pre-coagulation process for drinking water production', J. Membr. Sci., 254, 39 (2005) https://doi.org/10.1016/j.memsci.2004.12.030
  3. L. Fiksdal and T. O. Leiknes, 'The effect of coagulation with MF/UF membrane filtration for removal of virus in drinking water', J. Membr. Sci., 279, 364 (2006) https://doi.org/10.1016/j.memsci.2005.12.023
  4. A. R. Costa and M. N. Pinho, 'Performance and cost estimation of nanofiltration for surface water treatment in drinking water production', Desalination, 196, 55 (2006) https://doi.org/10.1016/j.desal.2005.08.030
  5. 이용택, 오중교, '분리막을 이용한 정수처리 System 에서 처리공정 및 운전조건의 최적화에 관한 연구', 멤브레인, 9(4), 193 (1999)
  6. 김미희, 박진용, '제지폐수 재활용을 위한 관형 탄소계 세라믹 한외여과장치에서 물 역세척의 막오염 제어 효과', 멤브레인, 11(4), 190 (2001)
  7. 이용택, 오중교, '분리막을 이용한 정수처리공정에서 유, 무기물질이 막오염에 끼치는 영향', 멤브레인, 13(4), 219 (2003)
  8. W. Yuan, A. Kocic, and A. L. Zydney, 'Analysis of humic acid fouling during microfiltration using a pore blockage-cake filtration model', J. Membr. Sci., 198, 51 (2002) https://doi.org/10.1016/S0376-7388(01)00622-6
  9. D. B. Mosqueda-Jimenez and P. M. Huck, 'Characterization of membrane foulants in drinking water treatment', Desalination, 198, 173 (2006) https://doi.org/10.1016/j.desal.2005.12.025
  10. M. Heran and S. Elmaleh, 'Microfiltration through an inorganic tubular membrane with high frequency retrofiltration', J. Membr. Sci., 188, 181 (2001) https://doi.org/10.1016/S0376-7388(01)00351-9
  11. S. K. Karode, 'Unsteady state flux response: a method to determine the nature of the solute and gel layer in mambrane filtration' J. Membr. Sci., 188, 9 (2001) https://doi.org/10.1016/S0376-7388(00)00644-X
  12. P. Rai, C. Rai, G. C. Majumdara, S. D. Gupta, and S. De, 'Resistance in series model for ultrafiltration of mosambi (Citrus sinensis (L.) Osbeck) juice in a stirred continuous mode' J. Membr. Sci., 283, 116 (2006) https://doi.org/10.1016/j.memsci.2006.06.018
  13. K. Katsoufidou, S. G. Yiantsios, and A. J. Karabelas, 'A study of ultrafiltration membrane fouling by humic acids and flux recovery by backwashing: Experiments and modeling', J. Membr. Sci., 266, 40 (2005) https://doi.org/10.1016/j.memsci.2005.05.009
  14. J. Y. Park, S. J. Choi, and B. R. Park, 'Effect of N2-back-flushing in multichannels ceramic microfiltration system for paper wastewater treatment', Desalination, 202, 207 (2007) https://doi.org/10.1016/j.desal.2005.12.056
  15. D. Chen, L. K. Weavers, and H. W. Walker, 'Ultrasonic control of ceramic membrane fouling: Effect of particle characteristics', Water research, 40, 840 (2006) https://doi.org/10.1016/j.watres.2005.12.031
  16. 육영재, 염경호, '초음파를 이용한 한외여과의 성능향상', 멤브레인, 13(4), 283 (2003)
  17. W. F. Jones, R. L. Valentine, and V. G. J. Rodgers, 'Removal of suspended clay from water using transmembrane pressure pulsed microfiltration', J. Membr. Sci., 157, 199 (1999) https://doi.org/10.1016/S0376-7388(98)00376-7
  18. F. Malek, J. L. Harris, and F. A. Roddick, 'Interrelationship of photooxidation and microfiltration in drinking water treatment', J. Membr. Sci., 281, 541 (2006) https://doi.org/10.1016/j.memsci.2006.04.045
  19. 박진용, '세라믹 여과 시스템으로 제지폐수 처리시 회수 효율에 대한 물 역세척 시간의 영향', 멤브레인, 14(4), 329 (2004)
  20. 김은옥, '세라믹 분리막의 응용', 멤브레인, 3(1), 12 (1993)
  21. 강상규, 김경호, 이호신, 배동식, '수처리용 세라믹 분리막의 기술개발 현황과 정보분석', 공업화학 전망, 7(3), 83 (2004)
  22. J. Y. Park, G. Y. Kyung, S. H. Han, H. W. Kim, and H. C. Lee, 'Lake Water Treatment using Ceramic Ultrafiltration Membrane System with Periodic Water-backflushing', Korean Membrane J., 8(1), 50 (2006)
  23. 동화기술편집부, '수질오염공정시험법', pp. 133-204, 동화기술 (2002)
  24. A. D. Eaton, L. S. Clesceri, and A. E. Greenberg, 'Standard Methods for the Examination of Water and Wastewater', 9th Ed., pp. 2-8, APHA, NW Washington, DC (1995)