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Ga doped ZnO Thin Films for Gas Sensor Application

Ga이 첨가된 ZnO 박막의 가스센서로의 응용 연구

  • 황현석 (요업기술원 융합기술본부) ;
  • 여동훈 (요업기술원 융합기술본부) ;
  • 김종희 (요업기술원 융합기술본부) ;
  • 송준태 (성균관대학교 정보통신공학부)
  • Published : 2008.06.01

Abstract

In this work, Ga-doped ZnO (GZO) thin films for gas sensor application were deposited on low temperature co-fired ceramics (LTCC) substrates, by RF magnetron sputtering method. The LTCC substrate is one of promising materials for this application since it has many advantages (e.g., low cost production, high manufacturing yields and easy realizing 3D structure etc.). The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The structural properties of the fabricated GZO thin film with thickness of 50 nm is analyzed by X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM). The film shows good adhesion to the substrate. The GZO gas sensors are tested by gas measurement system and show fast response and recovery characteristics to $NO_x$ gas that is 27.2 and 27.9 sec, recpectively.

Keywords

References

  1. Y. S. Lee, B. S. Joo, N. J. Choi, B. H. Kang, and Y. S. Chang, 'Pattern recognition of a gas sensor array using impedance', J. Korean Phys. Soc., Vol. 37, No. 6, p. 862, 2000 https://doi.org/10.3938/jkps.37.862
  2. T. Pisarkiewicz, A. Sutor, P. Potempa, W. Maziarz, H. Thust, and T. Thelemann, 'Microsensor based on low temperature cofired ceramics and gas-sensitive thin film', Thin Solid Films, Vol. 436, p. 84, 2003 https://doi.org/10.1016/S0040-6090(03)00514-5
  3. G. N. Chaudharil, D. R. Bambolel, A. B. Bodadel, and P. R. Padolel, 'Characterization of nanosized $TiO_2$ based $H_2S$ gas sensor', J. Mater. Sci., Vol. 41, p. 4860, 2006 https://doi.org/10.1007/s10853-006-0042-7
  4. Z. Topalian, J. M. Smulko, G. A. Niklasson, and C. G. Granqvist, 'Resistance noise in $TiO_2$-based thin film gas sensors under ultraviolet irradiation', Journal of Physics: Conference series, Vol. 76, p. 012056, 2007 https://doi.org/10.1088/1742-6596/76/1/012056
  5. A. Nemeth, E. Horvath, Z. Labadi, L. Fedak, and I. Barsony, 'Single step deposition of different morphology ZnO gas sensing films', Sens. Actuators B, Vol. 127, p. 157, 2007 https://doi.org/10.1016/j.snb.2007.07.091
  6. J. Xu, Q. Pan, Y. Shun, and Z. Tian, 'Grain size control and gas sensing properties of ZnO gas sensor', Sens. Actuators B, Vol. 66, p. 277, 2000 https://doi.org/10.1016/S0925-4005(00)00381-6
  7. F. Chaabouni, M. Abaab, and B. Rezig, 'Metrological characteristics of ZNO oxygen sensor at room temperature', Sens. Actuators B, Vol. 100, p. 200, 2004 https://doi.org/10.1016/j.snb.2003.12.059
  8. N. Koshizaki and T. Oyama, 'Sensing characteristics of ZnO-based Nox sensor', Sens. Actuators B, Vol. 66, p. 119, 2000 https://doi.org/10.1016/S0925-4005(00)00323-3
  9. S. C. Navale, V. Ravi, I. S. Mulla, S. W. Gosavi, and S. K. Kulkarni, 'Low temperature synthesis and Nox sensing properties of nanostructured Al-doped ZnO', Sens. Actuators B, Vol. 126, p. 382, 2007 https://doi.org/10.1016/j.snb.2007.03.019
  10. V. Khranovskyy, U. Grossner, O. Nilsen, V. Lazorenko, G. V. Lashkarev, B. G. Svensson, and R. Yakimova, 'Structural and morphological properties of ZnO:Ga thin films', Thin Solid Films, Vol. 515, p. 472, 2006 https://doi.org/10.1016/j.tsf.2005.12.269
  11. P. K. Song, M. Watanbe, M. Kon, A. Mitsui, and Y. Shigesato, 'Electrical and optical properties of gallium-doped zinc oxide films deposited by dc magnetron sputtering', Thin Solid Films, Vol. 411, p. 82, 2002 https://doi.org/10.1016/S0040-6090(02)00192-X
  12. J. F. Chang, H. K. Kuo, I. C. Leu, and M. H. Hon, 'The effects of thicknes and operation temperature on ZnO:Al thin film CO gas sensor', Sens. Actuators B, Vol. 24, p. 258, 2002
  13. C. M. Ghimbeu, J. Schoonman, M. Lumbreras, and M. Siadat, 'Electorstatic spary deposited zinc oxide films for gas sensor application', Appl. Surf. Sci., Vol. 253, p. 7483, 2007 https://doi.org/10.1016/j.apsusc.2007.03.039
  14. P. S. Cho, K. W. Kim, and J. H. Lee, '$NO_2$ sensing characteristics of ZnO nanorods prepared by hydrothermal methoed', J. Electroceram., Vol. 17, p. 975, 2006 https://doi.org/10.1007/s10832-006-8146-7
  15. 이우선, 최권우, 박진성, 서용진, '가스센서 적용을 위한 S$NO_2$ 박막의 CMP 특성 연구', 전기전자재료학회논문지, 17권, 12호, p. 1296, 2004