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Seasonal Variations of Chemical Composition and Optical Properties of Aerosols at Seoul and Gosan

서울과 고산의 에어로졸 화학성분과 광학특성의 계절변화

  • Lee, S. (School of Earth and Environmental Sciences, Seoul National University) ;
  • Ghim, Y.S. (Department of Environmental Science, Hankuk University of Foreign Studies) ;
  • Kim, S.W. (School of Earth and Environmental Sciences, Seoul National University) ;
  • Yoon, S.C. (School of Earth and Environmental Sciences, Seoul National University)
  • 이시혜 (서울대학교 지구환경과학부) ;
  • 김영성 (한국외국어대학교 환경학과) ;
  • 김상우 (서울대학교 지구환경과학부) ;
  • 윤순창 (서울대학교 지구환경과학부)
  • Published : 2008.08.31

Abstract

Seasonal variations of chemical composition and optical properties of aerosols at Seoul and Gosan were investigated using the ground-based aerosol measurements and an optical model calculation. The mass fraction of elemental carbon was $8{\sim}17%$, but its contribution on light absorption was high up to $29{\sim}48%$ in Seoul. In Gosan, the contribution of water soluble aerosols on aerosol extinction was $83{\sim}94%$ due to the high mass fraction of these particles in the range of $56{\sim}88%$. Model calculation showed that the water holding capacity of aerosols was larger in Gosan than in Seoul because of higher relative humidity and temperature along with abundant water soluble aerosols. Difference between measured and calculated aerosol optical depths was the highest in summer. This was because aerosol optical depth calculated from ground-based measurements could not consider aerosol loadings at high altitude in spite of high column-integrated aerosol loadings observed by Sun photometer. Although hygroscopic growth was expected to be dominant in summer, the mass concentration of water soluble aerosols was too low to permit this growth.

Keywords

References

  1. 강충민(2003) Characteristics of the fine particles and source apportionment using the CMB model in Seoul area, 건국대학교 박사학위논문
  2. 한진석, 김영성, 문광주, 안준영, 김정은, 류성윤, 김영준, 공부주, 이석조(2004) 2001년 11월 오염시기와 2002년 봄 황사시기 제주도 고산에서의 미량원소 농도 변화, 한국대기환경학회지, 20, 143-151
  3. Bates, T.S., T.L. Anderson, T. Baynard, T. Bond, O. Boucher, G. Carmichael, A. Clarke, C. Erlick, H. Guo, L. Horowitz, S. Howel, S. Kulkarni, H. Maring, A. McComiskey, A. Middlebrook, K. Noone, C.D. O'Dowd, J. Ogren, J. Penner, P.K. Quinn, A.R. Ravishankara, D.L. Savoie, S.E. Schwartz, Y. Shinozuka, Y. Tang, R.J. Weber, and Y. Wu (2006) Aerosol direct radiative effects over the northwest Atlantic, nothwest Pacific, and Indian Oceans: Estimates based on in situ chemical and optical measurements and chemical transport modeling, Atmospheric Chemistry and Physics, 6, 1657-1732 https://doi.org/10.5194/acp-6-1657-2006
  4. Carrico, C.M., M.H. Bergin, J. Xu, K. Baumann, and H. Maring (2003a) Urban aerosol radiative properties: Measurements during the 1999 Atlanta Supersite Experiment, J. Geophysical Research, 108, D7, 8422, doi:10.1029/2001JD001222
  5. Carrico, C.M., P. Kus, M.J. Rood, P.K. Quinn, and T.S. Bates (2003b) Mixtures of pollution, dust, sea salt, and volcanic aerosol during ACE-Asia: Radiative properties as a function of relative humidity, J. Geophysical Research, 108, D23, 8650, doi:10.1029/2003JD003405
  6. Charlson, R.J., S.E. Schwartz, J.M. Hales, R.D. Cess, J.A. Coakley, Jr., J.E. Hansen, and D.J. Hofmann (1992) Climate forcing by anthropogenic aerosols, Science, 255, 423-430 https://doi.org/10.1126/science.255.5043.423
  7. Cheng, Y.F., A. Wiedensohler, H. Eichler, H. Su, T. Gnauk, E. Bruggemann, H. Herrmann, J. Heintzenberg, J. Slanina, T. Tuch, M. Hu, and Y.H. Zhang (2008) Aerosol optical properties and related chemical apportionment at Xinken in Pearl River Delta of China, Atmospheric Environment, In Press
  8. Chow, J.C., J.G. Watson, L.-W. A. Chen, W.P. Arnott, and H. Moosmuller (2004) Equivalence of elemental carbon by thermal/optical reflectance and transmittance with different temperature protocols, Environmental Science and Technology, 38, 4414-4422 https://doi.org/10.1021/es034936u
  9. Day, D.E. and W.C. Malm (2001) Aerosol light scattering measurement as a function of relative humidity: A composition between measurement made at three different sites, Atmospheric Environment, 35, 5169-5176 https://doi.org/10.1016/S1352-2310(01)00320-X
  10. Fernald, F.G. (1984) Analysis of atmospheric lidar observations: Some comments, Applied Optics, 23, 653-659 https://doi.org/10.1364/AO.23.000653
  11. Fung, K. (1990) Particulate carbon speciation by $MnO_2$ oxidation, Aerosol Science and Technology, 12, 122-127 https://doi.org/10.1080/02786829008959332
  12. Hess, M., P. Koepke, and I. Schult (1998) Optical properties of aerosols and clouds: The software package OPAC, Bulletin of the American Meteorological Society, 79, 831-844 https://doi.org/10.1175/1520-0477(1998)079<0831:OPOAAC>2.0.CO;2
  13. Holben, B.N., T.F. Eck, I. Slutsker, D. Tanre, J.P. Buis, A. Setzer, E. Vermote, J.A. Reagan, Y. Kaufman, T. Nakajima, F. Lavenu, I. Jankowiak, and A. Smirnov (1998) AERONET-A federated instrument network and data archive for aerosol characterization, Remote Sensing of Environment, 66, 1-16 https://doi.org/10.1016/S0034-4257(98)00031-5
  14. Holland, H.D. (1978) The chemistry of the Atmosphere and Oceans, Wiley, Hoboken, NJ, 154pp.
  15. Huebert, B.J., T. Bates, P.B. Russell, G. Shi, Y.J. Kim, K. Kawamura, G. Carmichael, and T. Nakajima (2003) An overview of ACE-Asia: Strategies for quantifying the relationship between Asian aerosols and their climatic impacts, J. Geophysical Research, 108, D23, 8633, doi:10.1029/2003JD003550
  16. Kang, C.-M., H.S. Lee, B.-W. Kang, S.-W. Lee, and Y. Sunwoo (2004) Chemical characteristic of acidic gas pollutants and $PM_{2.5}$ species during hazy episodes in Seoul, South Korea, Atmospheric Environment, 38, 4749-4760 https://doi.org/10.1016/j.atmosenv.2004.05.007
  17. Kaskaoutis, D.G. and H.D. Kambezidis (2006) Investigation into the wavelength dependence of the aerosol optical depth in the Athens area, Q. J. R. Meteorological Society, 132, 2217-2234 https://doi.org/10.1256/qj.05.183
  18. Kim, J., S.-C. Yoon, S.-W. Kim, F. Brechtel, A. Jefferson, E.G. Dutton, K.N. Bower, S. Cliff, and J.J. Schauer (2006) Chemical apportionment of shortwave direct aerosol radiative forcing at the Gosan super-site, Korea during ACE-Asia, Atmospheric Environment, 40, 6718-6729 https://doi.org/10.1016/j.atmosenv.2006.06.007
  19. Kim, J.Y., Y.S. Ghim, C.H. Song, S.-C. Yoon, and J.S. Han (2007a) Seasonal characteristics of air masses arriving at Gosan, Korea, using fine particle measurements between November 2001 and August 2003, J. Geophysical Research, 112, D07202, doi:10.1029/2005JD006946
  20. Kim, S.-W., S.-C. Yoon, A. Jefferson, J.-G. Won, E.G. Dutton, J.A. Ogren, and T.L. Anderson (2004) Observation of enhanced water vapor in Asian dust layer and its effect on atmospheric radiative heating rate, Geophysical Research Letters, 31, L18113, doi:10.1029/2004GL020024
  21. Kim, S.-W., S.-C. Yoon, J. Kim, and S.-Y. Kim (2007b) Seasonal and monthly variations of columnar aerosol optical properties over east Asia determined from multi-year MODIS, LIDAR, and AERONET Sun/ Sky radiometer measurements, Atmospheric Environment, 41, 1634-1651 https://doi.org/10.1016/j.atmosenv.2006.10.044
  22. Kim, Y.P., J.H. Seinfeld, and P. Saxena (1993a) Atmospheric gas-aerosol equilibrium I. Thermodynamic model, Aerosol Science and Technology, 19, 157-181 https://doi.org/10.1080/02786829308959628
  23. Kim, Y.P., J.H. Seinfeld, and P. Saxena (1993b) Atmospheric gas-aerosol equilibrium II. Analysis of common approximations and activity coefficient calculation methods, Aerosol Science and Technology, 19, 182-198 https://doi.org/10.1080/02786829308959629
  24. Knapp, K.R. and L.L. Stowe (2002) Evaluating the potential for retrieving aerosol optical depth over land from AVHRR pathfinder atmosphere data, J. Atmospheric Sciences, 59, 279-293 https://doi.org/10.1175/1520-0469(2002)059<0279:ETPFRA>2.0.CO;2
  25. Latha, K.M. and K.V.S. Badarinath (2004) Characterization of aerosol and its radiation impacts over urban and rural environments-A case study from Hyderabad and Srisailam, Environmental Pollution, 132, 463-468 https://doi.org/10.1016/j.envpol.2004.05.010
  26. Lee, J.H., Y.P. Kim, K.-C. Moon, H.-K. Kim, and C.B. Lee (2001) Fine particle measurements at two background sites in Korea between 1996 and 1997, Atmospheric Environment, 35, 635-643 https://doi.org/10.1016/S1352-2310(00)00378-2
  27. Malm, W.C., J.F. Sisler, D. Huffman, R.A. Eldred, and T.A. Cahill (1994) Spatial and seasonal trends in particle concentration and optical extinction in the United States, J. Geophysical Research, 99, D1, 1347-1370 https://doi.org/10.1029/93JD02916
  28. Markowicz, K.M., P.J. Flatau, P.K. Quinn, C.M. Carrico, M.K. Flatau, A.M. Vogelmann, D. Bates, M. Liu, and M.J. Rood (2003) Influence of relative humidity on aerosol radiative forcing: An ACE-Asia experiment respective, J. Geophysical Research, 108, D23, 8662, doi:10.1029/2002JD003066
  29. Mclnnes, L., M. Bergin, J. Ogren, and S. Schwartz (1998) Apportionment of light scattering and hygroscopic growth to aerosol composition, Geophysical Research Letters, 25, 513-516 https://doi.org/10.1029/98GL00127
  30. Meng, Z., J.H. Seinfeld, P. Saxena, and Y.P. Kim (1995) Contribution of water to particulate mass in the South coast air basin, Aerosol Science and Technology, 22, 111-123 https://doi.org/10.1080/02786829408959731
  31. Menzel, N., P. Schramel, and K. Wittmaack (2002) Elemental composition of aerosol particulate matter collected on membrane filters: A comparison of results by PIXE and ICP-AES, Nuclear Instruments and Methods in Physics Research, 189, 94-99 https://doi.org/10.1016/S0168-583X(01)01013-8
  32. Nakajima, T., S.-C. Yoon, V. Ramanathan, G.-Y. Shi, T. Takemura, A. Higurashi, T. Takemura, K. Aoki, B.-J. Sohn, S.-W. Kim, H. Tsuruta, N. Sugimoto, A. Shimizu, H. Tanimoto, Y. Sawa, N.-H. Lin, C.-T. Lee, D. Goto, and N. Schutgens (2007) Overview of the atmospheric brown cloud east Asian regional experiment 2005 and a study of the aerosol direct radiative forcing in east Asia, J. Geophysical Research, 112, D24S91, doi:10.1029/2007JD009009
  33. Quinn, P.K., D.J. Coffman, T.S. Bates, E.J. Welton, D.S. Covert, T.L. Miller, J.E. Johnson, S. Maria, L. Russell, R. Arimoto, C.M. Carrico, M.J. Rood, and J. Anderson (2004) Aerosol optical properties measured on board the Ronald H. Brown during ACE-Asia as a function of aerosol chemical composition and source region, J. Geophysical Research, 109, D19S01, doi: 10.1029/2003JD004010
  34. Quinn, P.K., D.J. Coffman, T.S. Bates, T.L. Miller, J.E. Johnson, E.J. Welton, C.C. Neususs, M. Miller, and P. J. Sheridan (2002) Aerosol optical properties during INDOEX 1999: Means, variability, and controlling factors, J. Geophysical Research, 107, D19, 8020, doi:10.1029/2000JD000037
  35. Tsai, Y.I. and S.-C. Kuo (2005) $PM_{2.5}$ aerosol water content and chemical composition in a metropolitan and a coastal area in southern Taiwan, Atmospheric Environment, 39, 4827-4839 https://doi.org/10.1016/j.atmosenv.2005.04.024
  36. Turpin, B.J. and H.-J. Lim (2001) Species contributions to $PM_{2.5}$mass concentrations: Revisiting common assumptions for estimating organic mass, Aerosol Science and Technology, 35, 602-610 https://doi.org/10.1080/02786820152051454
  37. Valkovic, V., R.B. Liebert, T. Zabel, H.T. Larson, D. Miljanic, R.M. Wheeler, and G.C. Phillips (1974) Trace element analysis using proton-induced X-ray emission spectroscopy, Nuclear Instruments and Methods, 114, 573-579 https://doi.org/10.1016/0029-554X(74)90182-7
  38. Yoon, S.-C. and J. Kim (2006) Influences of relative humidity on aerosol optical properties and aerosol radiative forcing during ACE-Asia, Atmospheric Environment, 40, 4328-4338 https://doi.org/10.1016/j.atmosenv.2006.03.036
  39. Yoon, S.-C., J.-G. Won, A.H. Omar, S.-W. Kim, and B.-J. Sohn (2005) Estimation of the radiative forcing by key aerosol types in worldwide locations using a column model and AERONET data, Atmospheric Environment, 39, 6620-6630 https://doi.org/10.1016/j.atmosenv.2005.07.058
  40. Yoon, S.-C., S.-W. Kim, J. Kim, B.-J. Sohn, A. Jefferson, S.- J. Choi, D.-H. Cha, D.-K. Lee, T.L. Anderson, S.J. Doherty, and R.J. Weber (2006) Enhanced water vapor in Asian dust layer: Entrainment processes and implication for aerosol optical properties, Atmospheric Environment, 40, 2409-2421 https://doi.org/10.1016/j.atmosenv.2005.12.018
  41. Yu, J.Z. (2002) Chemical characterization of water-soluble organic compounds in particulate matter in Hong Kong, report, Hong Kong Environ. Prot. Dep., Hong Kong

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