An Overview of the Pretreatment Processes in Seawater Desalination Plants using Reverse Osmosis Membranes

역삼투막을 이용한 해수담수화 플랜트에서 전처리 공정 기술

  • 안창훈 (서울대학교 화학생물공학부) ;
  • 이원일 (서울대학교 화학생물공학부) ;
  • 윤제용 (서울대학교 화학생물공학부)
  • Received : 2009.08.26
  • Accepted : 2009.12.10
  • Published : 2009.12.15

Abstract

Seawater desalination process using a reverse osmosis (RO) membrane has been considered as one of the most promising technologies in solving the water scarcity problems in many arid regions around the world. To protect RO membrane in the process, a thorough understanding of the pretreatment process is particularly needed. Seawater organic matters (SWOMs) may form a gel layer on the membrane surface, which will increase a concentration polarization. As the SWOMs can be utilized as a substrate, membrane biofouling will be progressed on the RO membrane surface, resulting in the flux decline and increase of trans-membrane pressure drop and salt passage. In the middle of disinfection, an optimal chlorine dosage and neutralizer (sodium bisulfite, SBS) should be practiced to prevent oxidizing the surface of RO membranes. Additional fundamental research including novel non-susceptible biofouling membranes would be necessary to provide a guide line for the proper pretreatment process.

Keywords

Acknowledgement

Supported by : 국토해양부

References

  1. Agus, E., Voutchkov, N., and Sedlak, D. L. (2009) Disinfection by-products and their potential impact on the quality of water produced by desalination systems: A literature review, Desalination, 237, pp.214-237 https://doi.org/10.1016/j.desal.2007.11.059
  2. Ali, M. Y., and Riley, P. (1989) The production of brominated methanes in desalination plants in Kuwait, Water Res., 23, 1099-1106, 1989 https://doi.org/10.1016/0043-1354(89)90153-X
  3. Al-Ahmad, M., Abdul Aleem, F. A., Mutiri, A., and Ubaisy, A (2000) ,Desalination, 132, 173- 179, 2000 https://doi.org/10.1016/S0011-9164(00)00146-6
  4. Alldredge, A. L., Passow, U., and Logan, B. E. (1993) The abundance and significance of a class of large, transparent organic particles in the ocean, Deep-Sea Res.,40, 131-1140, 1993 https://doi.org/10.1016/0967-0637(93)90129-Q
  5. Ang, W. S., and Elimelech, M. (2007) Protein (BSA) fouling of reverse osmosis membranes: Implications for wastewater reclamation, J. Membr. Sci., 296, 83-92 https://doi.org/10.1016/j.memsci.2007.03.018
  6. Applegate, L. E., Erkenbrecher, Jr., C. W., and Winters, H. (1989) New chloramines process to control aftergrowth and biofouling in PERMASEPRB-10 RO surfacesea waterplants, Desalination, 74, 51-67 https://doi.org/10.1016/0011-9164(89)85042-8
  7. Avolonitis, S., Hanbury, W. T., and Hodgekiess, T. (1992) Chlorine degradation of aromatic polyadmies, Desalination, 85, 321–334 https://doi.org/10.1016/0011-9164(92)80014-Z
  8. Belfer, S., Gilron, J., Daltrophe, N., and Oren, Y. (2005) Comparative study of biofouling of NF modified membrane at SHAFDAN, Desalination, 13–21 https://doi.org/10.1016/j.desal.2005.04.035
  9. Bj$\phi$rnsen, P. K., and Kuparinen, J. (1994) Determination of bacterioplanton biomass, net production, and growth efficiency in the Southern Ocean, Marine Ecology Progress Series, 71, 185–194 https://doi.org/10.3354/meps071185
  10. Bonnälye, V. Guey, L. and Del Castillo, J. (2008) UF/MF as RO pre-treatment: the real benefit, Desalination, 222, 59–65 https://doi.org/10.1016/j.desal.2007.01.129
  11. Brehant, A., Bonnelye, V., and Perez, M. (2003) Assessment of ultrafiltration as a pretreatment of reverse osmosis membranes for surface seawater desalination, WaterSci. Technol.:WaterSupply, 3(5/6), 437-445
  12. Cadotte, J. E., Petersen, R. J., Larson, R. E., and Erickson, E. E. (1980), Desalination, 32, 25-31 https://doi.org/10.1016/S0011-9164(00)86003-8
  13. Chen, K. L., Song, L., Ong, S. L., and Ng, W. J. (2004) The development of membrane fouling in full-scale RO processes, J. Membr. Sci., 63–72 https://doi.org/10.1016/j.memsci.2003.11.028
  14. Childress, A. E., and Elimelech, M. (2000), Environ. Sci. Technol., 34, 3710-3716 https://doi.org/10.1021/es0008620
  15. Chin, W. C., Orellana, M. V., and Verdugo, P. (1998) Spontaneous assembly of marine dissolved organic matter into polymer gels, Nature, 391, 568-572 https://doi.org/10.1038/35345
  16. Choi, J.S., Lee, S.H., Kim, W.J., Park, Y.G., Kim, H.S., Choi, K.H., Oh, Y.K. (2009) Experiments and modeling of boron removal by 2 pass RO system, IDA World Congress 2009, Atlantis-The Palm Jemeirah, Dubai-UAE, Nov. 8-10
  17. Collivignarelli, C., and Sorlini, S. (2004) Trihalomethane, chlorite and bromate formation in drinking water oxidation of Italian surface waters, J. Water Sup. Res. Tech. – Aqua, 53, 159-168
  18. Dalvi, A. G. I., Al-Rasheed, R., and Javeed, M. A. (2000) Haloacetic acid (HAAs) formation in desalination processes from disinfectants, Desalination, 129, 261-271 https://doi.org/10.1016/S0011-9164(00)00066-7
  19. Gabelich, C. J., Frankin, J. C., Gerringer, F. W., Ishida, K. P., and Suffet, I. H. (2005) Enhanced oxidation of polymide membrane using monochloramine and ferrous iron, J.Membr. Sci., 258, 64–70 https://doi.org/10.1016/j.memsci.2005.02.034
  20. Glater, J., Hong, S. K., and Elimelech, M. (1994) The search for a chlorine-resistant reverse osmosis membrane, Desalination, 95, 325–345 https://doi.org/10.1016/0011-9164(94)00068-9
  21. Greenlee, L. F., Lawler, D. F., Freeman, B. D., Marrot, B., and Moulin, P. (2009) Reverse osmosis desalination: Water sources, technology, and today's challenges, Water Res., 43, 2317–2348 https://doi.org/10.1016/j.watres.2009.03.010
  22. Henmi, M., Fusaoka, Y., Tomioka, H., Kurihara, M., Uemura, T. (2009) Energy saving and high boron removal RO membrane for seawater desalination, IDA World Congress 2009, Atlantis-The Palm Jemeirah, Dubai-UAE, Nov. 8-10
  23. Herzberg, M., and Elimelech, M. (2007) Biofouling of reverse osmosis membranes: Role of biofilm-enhanced osmotic pressure, J. Membr. Sci., 295, 11–20 https://doi.org/10.1016/j.memsci.2007.02.024
  24. Hoek, E. M. V., and Elimelech, M. (2003) Cakeenhanced concentration polarization: A new fouling mechanism for salt-rejecting membranes, Environ. Sci. Technol, 37, 5581-5588 https://doi.org/10.1021/es0262636
  25. Hong, S.K., and Elimelech, M. (1997) ,J. Membr. Sci., 132, 159-181 https://doi.org/10.1016/S0376-7388(97)00060-4
  26. Hung, C. C., Guo, L., Santschi, P. H., Alvarado- Quiroz, N., and Haye, J. M. (2003) Distribution of carbohydrate species in the Gulf of Mexico, Marine Chemistry, 81, 119-135 https://doi.org/10.1016/S0304-4203(03)00012-4
  27. Hwang, J., Druffel, E. R. M., and Bauer, J. E. (2006) Incorporation of aged dissolved organic carbon (DOC) by oceanic particulate organic carbon (POC): An experimental approach using natural carbon isotopes, Marine Chemistry, 98, 315-322 https://doi.org/10.1016/j.marchem.2005.10.008
  28. International Desalination Association (2004) Desalting inventory 2004: Desalination business stabilized on a high level, International Desalination Water Reuse, 14(2), 14–17
  29. Kamp, P. C., Kruithof, J. C., and Folmer, H. C. (2000) UF/RO treatment plant Heemskerk: from challenge to full sacle application, Desalination, 131, 27-35 https://doi.org/10.1016/S0011-9164(00)90003-1
  30. Kawaguchi, T., and Tamura, H. (1984) Chlorineresistant membrane for reverse osmosis. I. Correlation between chemical structures and chlorine resistance of polyamides, J Appl. Polymer Sci., 29, 3359–3367 https://doi.org/10.1002/app.1984.070291113
  31. K$\ddot{}$hler, P., Bj$\phi$rnsen, P. K., Lochte, K., and Antia, A. (1997) Dissolved organic matter and its utilization by bacteria during spring in the Southern Ocean, Deep-Sea Res. II, 44(l/2), 341-353 https://doi.org/10.1016/S0967-0645(96)00071-9
  32. Kim, Y. M., Kim, S. J., Kim, Y. S., Lee, S. H., Kim, I. S., and Kim, J. H. (2009), Desalination, 238, 312-332 https://doi.org/10.1016/j.desal.2008.10.004
  33. Kwak, S. Y., Jung, S. G., and Kim, S. H. (2001) ,Environ. Sci. Technol., 35, 4334–4340 https://doi.org/10.1021/es010630g
  34. Kwon, Y. N., and Leckie, J. O. (2006a) Hypochlorite degradation of crosslinked polyamide membranes I. Changes in chemical/morphological properties, J. Membr. Sci., 283, 21–26 https://doi.org/10.1016/j.memsci.2004.03.018
  35. Kwon, Y. N., and Leckie, J. O., (2006b) Hypochlorite degradation of crosslinked polyamide membranes II. Changes in hydrogen bonding behavior and performance, J. Membr. Sci., 282, 456–464 https://doi.org/10.1016/j.memsci.2006.06.004
  36. Kwon, Y. N., Tang, C. Y., and Leckie, J. O. (2006) Change of membrane performance due to chlorination of crosslinked polyamide membranes, J. Appl. Polymer Sci., 102, 5895–5902 https://doi.org/10.1002/app.25071
  37. Lee, S., Kim, J., and Lee, C. H. (1999) Analysis of $CaSO_4$ scale formation mechanism in various nanofiltration modules, J. Membr. Sci., 163, 63-74 https://doi.org/10.1016/S0376-7388(99)00156-8
  38. Leparc, J., Rapenne, S., Courties, C., Lebaron, P., Croue, J. P., Jacquemet V., and Turner, G. (2007) Water quality and performance evaluation at seawater reverse osmosis plants through the use of advanced analytical tools, Desalination, 243–255 https://doi.org/10.1016/j.desal.2006.03.529
  39. Light, W.G., Chu, H. C., and Tran, C. N. (1987) Reverse osmosis TFC magnum elements for chlorinated/dechlorinated feedwater processing, Desalination, 64, 411–421 https://doi.org/10.1016/0011-9164(87)90113-5
  40. Magara, Y., Kawasaki, M., Sekino, M., and Yamamura, H. (2000) Development of reverse osmosis seawater desalination in Japan, Water Sci. Technol., 41(10/11), 1-8
  41. Majamaa, K.V., Bertheas U., Cortes, V.G., Mata, J.C., Arzu, A. (2009) Field trial to optimize the use of DBNPA in WRU application, IDA World Congress 2009, Atlantis-The Palm Jemeirah, Dubai-UAE, Nov. 8-10
  42. Mallevialle, J., Odendaal, P. E., and Wiesner, M. R. (1996) Water treatment membrane processes, NY, Mc Graw Hill, Inc., American Water Works Association
  43. Mehdizadeh, H. (2006) ,Desalination, 191, 200-209 https://doi.org/10.1016/j.desal.2005.06.037
  44. Passow U. (2002) Transparent exopolymer particles (TEP) in aquatic environments, Progress in Oceanography, 55, 287-333 https://doi.org/10.1016/S0079-6611(02)00138-6
  45. Reverter, J.A., Talo, S., and Alday, J. (2001) Las Palmas Ⅲ – the success story of brine staging, Desalination, 138, 207-217 https://doi.org/10.1016/S0011-9164(01)00266-1
  46. Shams El Din, A. M., Arain, R. A., and Hammoud, A. A. (1991) A contribution to the problem of trihalomethane formation from the Arabian Gulf water, Desalination, 85, 13-32 https://doi.org/10.1016/0011-9164(91)85143-I
  47. Sharp, J. H., Beauregard, A. Y., Burdige, D., Cauwet, G., Curless, S. E. Lauck, R., Nagel, K., Ogawa, H., Parker, A. E., Primm, O., Pujo-Pay, M., Savidge, W. B., Seitzinger, S., Spyres, G., and Styles, R. (2004) A direct instrument comparison for measurement of total dissolved nitrogen in seawater, Marine Chemistry, 84, 181–193 https://doi.org/10.1016/j.marchem.2003.07.003
  48. Sheikholeslami, R., Al-Mutaz, I. S., Koo, T., and Young, A. (2001) Pretreatment and the effect of cations and anions on prevention of silica fouling, Desalination, 83–95 https://doi.org/10.1016/S0011-9164(01)00297-1
  49. Singh, R. (1994) Polyamide polymer solution behavior under chlorination conditions, J. Membr. Sci., 88, 285-287 https://doi.org/10.1016/0376-7388(94)87015-2
  50. Shon, H. K., Vigneswaran, S., Zareie, M.H., Ben Aim, R., Lee, E., Lee, J., Cho, J., and Kim, I.S. (2009) Physico-chemical pretreatment to seawater reverse osmosis (SWRO): organic characterization and membrane autopsy, Desalination, 236, 282–290 https://doi.org/10.1016/j.desal.2007.10.078
  51. Schneider, R. P., Ferreira, L. M., Binder, P., Bejarano, E. M., Gäes, K. P., Slongo, E., Machado, C. R., and Rosa, G. M. Z. (2005) ,J. Membr. Sci., 266, 18-29 https://doi.org/10.1016/j.memsci.2005.05.006
  52. Soice, N. P., Maladono, A. C., Takigawa, D. Y., Norman, A. D., Krantz, W. B., Greenberg, A. R. (2003) Oxidative degradation of polyamide reverse osmosis membranes: Studies of molecular model compounds and selected membranes, J. Appl. Polymer Sci., 90, 1173–1184 https://doi.org/10.1002/app.12774
  53. Soice, N. P., Greenberg, A. R., Krantz, W. B., and Norman, A. D. (2004) Studies of oxidative degradation in polyamide RO membrane barrier layers using pendant drop mechanical analysis, J. Membr. Sci., 243, 345–355 https://doi.org/10.1016/j.memsci.2004.06.039
  54. Vedavyasan, C. V. (2007) Pretreatment trends – and overview, Desalination, 203, 296-299 https://doi.org/10.1016/j.desal.2006.04.012
  55. Verdugo, P., Alldredge, A. L., Azam, F., Kirchman, D. L., Passow, U., and Santschi, P. H. (2004) The oceanic gel phase: a bridge in the DOM-POM continuum, Marine Chemistry, 92, 67-85 https://doi.org/10.1016/j.marchem.2004.06.017
  56. Vrouwenvelder, J. S., Graf von der Schulenburg, D. A., Kruithofa, J. C., Johnsc, M. L., van Loosdrecht, M.C.M. (2009) Biofouling of spiralwound nanofiltration and reverse osmosis membranes: A feed spacer problem, Water Res., 43, 583–594 https://doi.org/10.1016/j.watres.2008.11.019
  57. Wu, S., Zheng, C., and Zheng, G. (1996) Truly chlorine-resistant polyamide reverse osmosis composite membrane, J. Appl. Polymer Sci., 61, 1147–1148 https://doi.org/10.1002/(SICI)1097-4628(19960815)61:7<1147::AID-APP10>3.0.CO;2-V
  58. Xu, P., Drewes, J. E., Kim, T. U., Bellona, C., and Amy, G. (2006) Effect of membrane fouling on transport of organic contaminants in NF/RO membrane applications, J. Membr. Sci., 165–175 https://doi.org/10.1016/j.memsci.2005.12.001
  59. 오상근, Hung, 오병수, 김인수 (2009) IC/MS를 활용한 HAAs 분석 및 막 중심 해수담수화 플랜트에서의 HAAs/HAAFP 거동 관찰, 대한 상하수도학회 . 한국물환경학회 2009년 공동 추계 학술발표회, 11월18-19일, 인천 송도 컨벤시아