Journal of the Korean Electrochemical Society (전기화학회지)

The Korean Electrochemical Society (한국전기화학회)
권호 표지
DOI QR코드

DOI QR Code

Inhibition Effect of Amino Acids on the Corrosion of Aluminum in Artificial Sea Water

인공해수에서 알루미늄의 부식에 미치는 아미노산의 부식억제효과

  • Chon, Jung-Kyoo (Department of Chemistry, College of Natural Science, Hankuk University of Foreign Studies) ;
  • Kim, Youn-Kyoo (Department of Chemistry, College of Natural Science, Hankuk University of Foreign Studies)
  • 천정균 (한국외국어대학교 자연과학대학 화학과) ;
  • 김연규 (한국외국어대학교 자연과학대학 화학과)
  • Published : 2009.11.30
Download PDF
⟨ Previous Next ⟩

Abstract

Inhibition effects of alanine and methionine on the corrosion of aluminum were investigated in artificial sea water. Based on the low coverage of alanine and methionine we suggested that alanine and methionine adsorption process in aluminum surface is Langmuir isotherm and the carboxyl ion of amino acids seems to be adsorbed on Al.

인공해수에서 일어나는 Al의 부식에 대하여 alanine과 methionine의 부식억제 효과를 조사하였다. 이들 아미노산의 낮은 덮힘율로 보아 Al 표면에 alanine과 methionine는 Langmuir adsorption isotherm에 따른 흡착이 일어나며, 아미노산 안의 카르복시 이온만이 Al에 흡착하는 것으로 보인다.

Keywords

References

  1. M. Pourbaix, "Atlas of Electrochemical Equilibria (English Ed. by J.A. Franklin)", Nat. Assoc. Corr. Eng., Houston, 168-176 (1974)
  2. O'M. Bockris and S. U. M. Khan, "Surface Electrochemistry, A Molecular level Approach", Plenum, New York, 771 (1993)
  3. C. Vargel, M. Jacques, and M. P. Schmidt, "Corrosion of Aluminum", Elsevier, 2004, Science-Direct Online Ed. 113 (2007)
  4. A.A. El-Shfei, S.A. Abd El-Maksoud, and A.S. Fouda, "The role of indole and its derivatives in the pitting corrosion of Al in neutral chloride solution", Corros. Sci.,46, 579 (2004) https://doi.org/10.1016/S0010-938X(03)00067-2
  5. R. C. Barik, J. A. Wharton, R. J. K. Wood, K. R. Stokes, and R. L. Jones, "Corrosion, erosion and erosion-corrosion performance of plasma electrolytic oxidation (PEO) depdsited $Al_{2}O_{3}$ coatings", Surf. & Coat. Tech., 199, 158 (2005) https://doi.org/10.1016/j.surfcoat.2004.09.038
  6. E. M. Sherif and S. -M. Park, "Effects of 1.4-naphthaquinone on aluminum corrosion in 0.5M sodium chloride solution", Electrochim. Acta, 51, 1313 (2006) https://doi.org/10.1016/j.electacta.2005.06.018
  7. W. Lee and S. Pyun, "Effects of sulphate ion additives on the pitting corrosion of pure aluminum in 0.01M NaCl solution", Electrochim. Acta, 45, 1901 (2000) https://doi.org/10.1016/S0013-4686(99)00418-1
  8. M. M. Osman, "Corrosion inhibition of aluminum-brass in 3.5% NaCl solution and sea water", Mater. Chem. and Phys., 71, 12 (2001) https://doi.org/10.1016/S0254-0584(00)00510-1
  9. D. Zhu and W. J. van Ooij, "Corrosion protection of AA 2024-T3 by bis-[3-(triethoxysilyl)propyl]tetrasulfide in neutral sodium chloride solution", Corros. Sci., 45, 2177 (2003) https://doi.org/10.1016/S0010-938X(03)00061-1
  10. A. M. Abdel-Garber, B. A. Abd-El-Nabey, I. M. Sidahmed, A. M. El-Zayady, and M. Saadawy, "Kinetics and thermodynamics of aluminum dissolution in 1.o M sulphuric acid and containing chloride ions", Mater. Chem. and Phys., 98, 291 (2006) https://doi.org/10.1016/j.matchemphys.2005.09.023
  11. I. L. Rozenfeld, "Corrosion Inhibitors (Translated by Ron and Hilary Hardin)", McGraw-Hill, New York, 1981
  12. O. Lunder, J. C. Walmsley, P. Mack, and K. Nisancioglu, "Formation and characterization of a chromate conversion coating on AA6060 aluminum", Corros. Sci., 47, 1604 (2005) https://doi.org/10.1016/j.corsci.2004.08.012
  13. M. Bethencourt, F. J. Botana, J. J. Calvino, M. J. Marcos, and M. A. Rodri$\acute{l}$guez-Chacon, "Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminum alloys: a review", Corros. Sci., 40, 1803 (1998) https://doi.org/10.1016/S0010-938X(98)00077-8
  14. M. Bethencourt, F. J. Botana, M. J. Cano, and M. J. Marcos, 'High protective, environmental friendly and short-time developed conversion coatins for aluminum alloys", Appl. Surf. Sci., 189. 162 (2002) https://doi.org/10.1016/S0169-4332(02)00129-0
  15. M. Bethencourt, F. J. Botana, M. J. Cano, and M. J. Marcos, "Advanced generation of green conversion coatings for aluminum alloys", Appl. Surf. Sci., 238. 278 (2004) https://doi.org/10.1016/j.apsusc.2004.05.268
  16. G. Moretti and F. Guidi, "Tyrophan as copper corrosion inhibitor in 0.5M sulfuric acid", Corr. Sci., 44 1995 (2002) https://doi.org/10.1016/S0010-938X(02)00020-3
  17. C. Liu, Q. Bi, A. Leyland, and A. Matthew, "An electrochemical impedance spectroscopy study of the corrosion behavior of PVD coated steels in 0.5 N NaCl aqueous solution", Corr. Sci., 45, 1257 (2003) https://doi.org/10.1016/S0010-938X(02)00214-7
  18. J. B. Matos, L. P. Pereira, S. M. L. Agostinho, O. E. Barcia, G. G. O. Cordeiro, and E. D'Elia, "Effect of cysteine on the anodic dissolution of copper in sulfuric acid medium", J. Electroanal. Chem., 570, 91 (2004) https://doi.org/10.1016/j.jelechem.2004.03.020
  19. D. Q. Zhang, L. Gao, and G. Zhou, "Inhibition of copper corrosion in aerated hydrochloric acid solution by aminoacid compounds", J. Appl. Electrochem., 35, 1081 (2005) https://doi.org/10.1007/s10800-005-9009-7
  20. W. A. Badawy, K. M. Ismail, and A. M. Fathi, "Corrosion control of Cu-Ni alloys in neutral chloride solutions by amino acids", Electrochim. Acta, 51, 4182 (2006) https://doi.org/10.1016/j.electacta.2005.11.037
  21. K. M. Ismail, "Evaluation of cysteine as environmentally friendly corrosion inhibitor for copper in neutral and acdic chloride solutions", Electrochim. Acta, 52, 7819 (2007) https://doi.org/10.1016/j.electacta.2007.02.053
  22. V. Shinde, A. B. Gaikwad, and P. P. Patil, "Synthesis and characterization of corrosion protective poly(2.5-dimthylaniline) coating on copper", App. Surf. Sci., 253, 1037 (2007) https://doi.org/10.1016/j.apsusc.2006.02.007
  23. M. I. Redondo and C. B. Breslin, "Polypyrrole electrodeposited on copper from an aqueous phosphate solution: Corrosion protection properties". Corr. Sci., 49, 1765 (2007) https://doi.org/10.1016/j.corsci.2006.10.014
  24. J. -K. Chon and Y. Kim, "Inhibitor effect of amino acids on the corrosion of copper in artificial sea water", J. Korean Chem. Soc., 52, 434 (2008) https://doi.org/10.5012/jkcs.2008.52.4.434
  25. G. Bereket and A. Yurt, "The inhibition effect of amino acids and hydroxyl carboxylic acids on pitting corrosion of aluminum alloy 7075", Corr. Sci., 43, 1179 (2001) https://doi.org/10.1016/S0010-938X(00)00135-9
  26. A. Yurt, G. Bereket, and C. Ogretir, "Quantum chemical studies on inhibition effect of amino acids and hydroxyl carboxylic acids on pitting corrosion of aluminum alloy 7075 in NaCl solution". J. Mol.Struct. THEOCHEM., 725, 215 (2005) https://doi.org/10.1016/j.theochem.2005.01.048
  27. J-K. Chon and Y. Kim, “Corrosion and passivation of copper in artificial sea water”, J. Korean Chem. Soc., 51, 305 (2007) https://doi.org/10.5012/jkcs.2007.51.4.305
  28. a)pp102-103 in Ref.3, b)pp173-178 in Ref.3. c)p320 in Ref.3
  29. B. B. Damaskin, O. A. Petrii, and Valeri$\check{i}$ V. Batrakov, "Adsorption of Organic Compounds on Electrodes (English Ed. by Uvarov. E.B.)", Plenum press, New York, 86 (1971)
  30. J. M. Bastidas, P. Pinilla, E. Cano, J. L. Polo, and S. Miguel, "Copper corrosion inhibition by triphenylmethane derivatives in sulphuric acid media", Corr. Sci., 45, 427 (2003) https://doi.org/10.1016/S0010-938X(02)00123-3
  31. E. Gileadi, "Electrode Kinetics for Chemists; Chemical Engineers and Material Scientist", VCH Publisher, New York, 267 (1993)
  32. p263 in Ref.2
  33. P. W. Atkins, "Physical chemistry", 4th Ed. Oxford University Press, Oxford, 885 (1993)
  34. O'M. Bockris and Y. Kang, "The protectivity ofaluminum and its alloys with transition metals", J. Solid State Electrochem. 1, 17 (1997) https://doi.org/10.1007/s100080050019

Cited by

  1. Inhibition Effects of Some Amino Acids on the Corrosion of Nickel in Hydrochloric Acid and Sulfuric Acid vol.59, pp.2, 2015, https://doi.org/10.5012/jkcs.2015.59.2.125
  2. Bonding characteristics and corrosion resistance of silane–cerium-treated aluminum adherend vol.27, pp.3, 2013, https://doi.org/10.1080/01694243.2012.705520
  3. Electrochemical Characterization of Stainless Steel in Ethanolamine Solution Containing an Alkyl Group using Cyclic Voltammetry vol.31, pp.1, 2014, https://doi.org/10.12925/jkocs.2014.31.1.66