Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Interfacial Electrical Effect of Particle Radius on Detergency of Particulate Soil -Particle Sizes and Dispersion Stability of Particle-

고형오구 입자크기가 고형오구의 세척성에 미치는 계면 전기적 효과 -고형오구의 입자크기와 입자의 분산안정성-

  • Mun, Mi-Hwa (Department of Clothing & Textiles, Changwon National University) ;
  • Kang, In-Sook (Department of Clothing & Textiles, Changwon National University)
  • 문미화 (창원대학교 자연과학대학 의류학과) ;
  • 강인숙 (창원대학교 자연과학대학 의류학과)
  • Received : 2009.09.25
  • Accepted : 2009.11.02
  • Published : 2009.12.31
⟨ Previous Next ⟩

Abstract

This study was a preliminary examination to investigate the effect of particle sizes on detergency of particulate soil. Monodispersed spherical $\alpha-Fe_2O_3$ particles were prepared by hydrothermal aging of an acidic $FeCl_3$ and HCl solution. The $\zeta$-potential of $\alpha-Fe_2O_3$ particles was measured by microelectrophoresis method, and the potential energy of interaction between particles was calculated by using the heterocoagulation theory. The particle size was reduced with decreasing concentration of $FeCl_3$ and with increasing concentration of HCl. The $\zeta$-potential of $\alpha-Fe_2O_3$ particles and energy of interaction between particles were increased with decreasing particle size and increasing concentration of surfactant. But the dispersion stability of particle increased with decreasing particle size and concentration of surfactant. The dispersion stability of particle was not related to interfacial electrical condition in high concentration of surfactant solution. Such phenomenon entails some sort of interaction between interfacial electrical effect and steric stability by adsorption of surfactant.

Keywords

Acknowledgement

Supported by : 한국학술진흥재단

References

  1. C. Tamura, M. Sato, and M. Minagawa, 'Studies on the Removal of Particulate Soil. II. Effect of Water Hardness on the Coagulation of Iron(III)-Oxide and the Deposition onto Fabric', J Jpn Oil Chem Sci, 1986, 35(7), 538-548 https://doi.org/10.5650/jos1956.35.538
  2. J. Hsu and Y. Chang, 'An Experimental Study of the Stability of TiO2 Particles in Water', Colloids Surf J, 2000, 161, 423-437 https://doi.org/10.1016/S0927-7757(99)00196-X
  3. N. Kallay and E. Matijevic, 'Particle Adhesion and Removal in Model Systems-Kinetics of Detachment of Hematite Particles from Steel', J Colloid Interf Sci, 1981, 83, 299-312
  4. E. Matijevic, R. J. Kuo, and H. Kolny, 'Stability and Deposition Phenomena of Monodispersed Hematite Sols', J Colloid Interf Sci, 1981, 80, 94-106 https://doi.org/10.1016/0021-9797(81)90163-6
  5. E. J. Verwey and J. T. G. Overbeek, 'Theory of the Stability of Lyophobic Colloids', Elsevier Publishing Co., Amsterdam, 1948, pp.66-67
  6. L. Zhigang, G. Deshun, Y. Xinsheng, L. Siren, and X. Yongping, 'Particle Size Correction of Suspended Sediment Concentration Measured by ADCP with in-situ Particle Size Analyzer', Oceanologia et Limnologia Sinica, 2004, 35(5), 385-392
  7. H. Sis and M. Birinci, 'Effect of Nonionic and Ionic Surfactants on Zeta Potential and Dispersion Properties of Carbon Black Powders', Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 2009, 341(1/3), 60-67 https://doi.org/10.1016/j.colsurfa.2009.03.039
  8. A. D. Nikolov and D. T. Wasan, 'Particle-particle Interactions in Concentrated Dispersions as Probed by the Capillary Force Balance with Application to Batch Sedimentation', Powder Technology, 1996, 88(3), 299-304 https://doi.org/10.1016/S0032-5910(96)03134-8
  9. S. Xiaolan, W. Haibo, W. Xuelan, Q. Peng, and Q. Guanzhou, 'Synthesis of $\gamma$-Al2O3 with CeO2 Nano Particles and Study on Dispersion and Stability for Its Suspension', Journal of the Chinese Rare Eatyh Society, 2004, 22(6), 800-805
  10. C. Ma and Y. Xia, 'Mixed Adsorption of Sodium Dodecylsulfate and Ethoxylated Nonylphenol on $TiO^{2}$ and the Stability of TiO2 Dispersions in Sodium Dodecylsulfareethoxylated Nonylphenol Mixed Solutions', Colloid Surf, 1992, 68(3), 171-177 https://doi.org/10.1016/0166-6622(92)80201-C
  11. C. R. Evanko, D. A. Dzombak, and J. W. Novak, 'Influence of Surfactant Addition on the Stability of Concentrated Alumina Dispersions in Water', Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 1996, 110(3), 219-233 https://doi.org/10.1016/0927-7757(95)03447-1
  12. A. D. Nikolov, D. T. Wasan, and S. E. Friberg, 'Effect of Surfactant Concentration on Dispersion Stability as Probed by the Film Thickness Stability Mechanism', Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 1996, 118(2), 221-243
  13. I. Fumoto, 'Interfacial Electrical Investigation of the Particle Deposition onto Fabrics in an Aqueous Soap Solution', Jpn Res Assn Text End Uses, 1983, 24(3), 33-45
  14. I. S. Kang, 'Effect of Dispersion Stability of Particles on Detergency of Particulate Soil(I)-The Dispersion Stability of $\alpha$-$Fe^{2}O^{3}$ Particles in the Nonionic Surfactants Solution-', J Korean Soc Cloth Ind, 2002, 4(1), 86-91